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1.
Heliyon ; 10(11): e31962, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38933979

RESUMO

This study conducted sterilization testing under different conditions using different strains for sterilization and crushing, the intermediate healthcare waste treatment phase, and proposed strategies for diversifying corresponding facilities in addition to promoting their installation. Five indicator microorganisms were selected to test the sterilization efficiency of steam, microwave, and chemical methods. Steam sterilization testing was conducted in accordance with legal and technological standards, microwave testing was carried out according to the legal standard, and chemical sterilization employed three typical compounds. Steam and microwave sterilization achieved 99.9999 % inactivation rates for all five strains under both conditions used; whereas under the chemical sterilization analyses, sodium hypochlorite (1000 ppm) failed to meet the inactivation requirement of the fungal strain Candida albicans, requiring further investigation. Based on these findings, this study presents strategies for diversifying sterilization·crushing facilities and promoting their installation.

2.
Environ Technol ; : 1-12, 2024 Jun 11.
Artigo em Inglês | MEDLINE | ID: mdl-38861474

RESUMO

ABSTRACTThe Ministry of Environment of Korea has proposed a ban on landfill disposal of municipal solid waste (MSW) from 2026. Thus, it is inferred that the amount of incineration ash will increase drastically. Against this backdrop, this study assessed the applicability of a plasma melting process to fly ash. Fly ash was collected from 14 incineration facilities to analyze its basic properties and perform melting experiments. Furthermore, scanning electron microscope (SEM) analysis and economic feasibility assessment were conducted. The molten fly ash slag exhibited a pH value of 9.9, and the ignition loss of fly ash was found to range from 14.5 to 25.7 wt.%. None of seven toxic elements (arsenic (As), cadmium (Cd), cyanide (CN), mercury (Hg), hexavalent chromium (Cr(VI)), copper, and lead (Pb)) was detected from the molten slag. In addition, 99.3 wt.% of chloride ion (Cl-), 97.9 wt.% of fluoride ion (F-), and 98.1 wt.% of sulphate ion (SO42-) were removed. The contents in the molten slag were found to be 0.19, 7.8, 27.8, 33.1, and 38 mg/kg for Cd, Pb, zinc, nickel, and F, respectively, and none of CN, Hg, and As was detected, thereby meeting the criteria for soil pollution. All of the environmental standards were met, and SEM analysis confirmed stable quality with high density and no surface pore. In the economic feasibility assessment, a profit of approximately 152.4 $/ton was also estimated compared to landfill disposal.

3.
Artigo em Inglês | MEDLINE | ID: mdl-38334008

RESUMO

To move away from linear system mining-manufacture-production-disposal, most countries have been trying to establish a circular economy, by reusing waste as resources. Responding to this paradigm change, the Ministry of Environment of Korea amended the Wastes Control Act in the 2010s. To increase the recycling rate in Korea, the environmental assessment of recycling (EAR) has been introduced to improve the Wastes Control Act. The whole process of new recycling technologies can be assessed in terms of environmental or technical aspects by assessment institutes of the EAR. Finally, the governmental research institute can approve of an application case, which proves environmental friendliness, even if the technology is not defined in the current act. Recently, 17 companies have been coassessed and approved to recycle steel codes in waste tires as resources for iron smelting via assessments of the whole process, such as environmental analysis and quality assessment. The EAR has been enforcing recycling materials for six years, and the total profit of the companies that were approved was estimated to be approximately 55 million USD. However, many amendments to the EAR continue to be requested by stakeholders. In this study, the effect of the EAR was evaluated, and additional tasks were found to enhance the EAR. Integr Environ Assess Manag 2024;00:1-13. © 2024 SETAC.

4.
Waste Manag ; 167: 141-149, 2023 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-37267877

RESUMO

The amount of incineration ash (IA) is expected to increase in South Korea from the rapidly rising numbers and operation capacities of incineration facilities; therefore, it remains necessary to establish measurements for the enhanced recycling and circularity of IA. This study established a database of hazardous substances in IA by compiling discharge data and survey results from domestic incineration facilities, along with literature survey values. The recycling potential of IA was assessed considering leaching reduction efficiency of various pretreatment methods. In particular, 98.2% of bottom ash and 49.0% of fly ash satisfied the IA recycling criteria after melting. Also, when mixed at a ratio of âˆ¼ 78:22 natural soil to IA, the resulting material was usable for media-contact recycling by meeting the heavy metal content criteria of the Soil Environment Conservation Act.


Assuntos
Incineração , Metais Pesados , Cinza de Carvão , Metais Pesados/análise , Reciclagem , República da Coreia , Resíduos Sólidos/análise
5.
Materials (Basel) ; 16(7)2023 Mar 27.
Artigo em Inglês | MEDLINE | ID: mdl-37048957

RESUMO

The quantity of waste from end-of-life vehicles is increasing with an increase in the number of scrapped internal combustion engine vehicles owing to international trends such as carbon neutrality and particulate matter reduction. The recycling rate must be ≥95%; however, the average recycling rate remains at approximately 89%. Therefore, the improvement of the recycling of automobile shredder residues (ASR) is gaining attention. In this study, four types of products (interlocking, clay, and lightweight swelled ceramic (LSC) bricks, and asphalt paving aggregate (APA)) were manufactured using ASR melting slag (ASRMS). Environmental performance, quality standards, and technology were evaluated to assess the recyclability of the manufactured bricks. The interlocking brick substituted melting slag for sand and stone powder as an aggregate. As melting slag content increased, absorption decreased and bending strength increased. Clay brick was manufactured by replacing kaolin and feldspar with melting slag that substituted for 20%. The quality of clay bricks mixed with over 15% melting slag was not better than standard. Asphalt paving aggregate was used to investigate the optimum condition of slag content in mixed asphalt; the mixture ratio showed that 61% broken stone of 13 mm, 6% screenings, 10% melting slag, 15% sand and 8% filler was most effective. A lightweight swelled ceramic brick was manufactured by using melting slag, front glass, and so on. Specific gravity and compressive strength ranged from 0.38 to 0.51 and from 339.7 to 373.6 N/cm2. ASRMS exhibited an environmental performance suitable for recycling and the manufactured bricks satisfied the quality standards. The recyclability of ASR was also assessed in terms of waste usage, conformance to quality standards, market size, and demand prediction. APA showed the best results followed by interlocking, clay, and LSC bricks.

6.
Environ Health Insights ; 16: 11786302221111872, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35864823

RESUMO

In South Korea, hazardous characteristics of wastes to be recycled are managed through the "Environmental Impact Assessment of Recycling" system. The ecotoxicity of medium-contact recyclable wastes, that is, those in contact with soil, groundwater, surface water, etc., is managed according to this system and is determined based on whether or not they exceed an ecotoxicity value (TU) of 2.0. The ecotoxicity of wastes is tested and determined by using pretreated eluate samples according to the Official Wastes Test Standard and applying the Official Water Pollution Process Test Standard. However, no ecotoxicity management limits are stipulated for medium-contact recycling using wastes in numerous other countries. This study aims to evaluate applicability and safety of the ecotoxicity test for wastes used in medium-contact recycling and establish an efficient management plan for hazardous characteristic wastes. Target wastes for the survey were selected based on the Wastes Control Act in South Korea. Nine types of waste were selected, which are representative types of wastes to which ecotoxicity is applied. In order to secure the representativeness of the target samples, a total of 45 samples were collected by selecting 5 cases each of the 9 waste types in consideration of the type of industry and amount of waste generated. Limit exceedance was calculated for each category of hazardous substances (leaching, total content), pH, and ecotoxicity of a total of 45 samples, and was found to increase in the order of leaching 2.22% < pH 9.09% < content 31.11% < ecotoxicity 37.21%. This indicates that the limit exceedance was maximum in the ecotoxicity category. Therefore, the application of ecotoxicity limit is efficient for identifying and comprehensively managing the environmental impacts of various types of hazardous substances contained in wastes from the perspective of comprehensive toxicity.

7.
Micromachines (Basel) ; 14(1)2022 Dec 26.
Artigo em Inglês | MEDLINE | ID: mdl-36677123

RESUMO

Over the years, several bare metal and crack-based strain sensors have been proposed for various fields of science and technology. However, due to their low gauge factor, metal-based strain sensors have limited practical applications. The crack-based strain sensor, on the other hand, demonstrated excellent sensitivity and a high gauge factor. However, the crack-based strain sensor exhibited non-linear behavior at low strains, severely limiting its real-time applications. Generally, the crack-based strain sensors are fabricated by generating cracks by bending a polymer film on which a metal layer has been deposited with a constant curvature. However, the random formation of cracks produces nonlinear behavior in the crack sensors. To overcome the limitations of the current state of the art, we propose a V-groove-based metal strain sensor for human motion monitoring and Morse code generation. The V-groove crack-based strain sensor is fabricated on polyurethane acrylate (PUA) using the modified photolithography technique. During the procedure, a V-groove pattern formed on the surface of the sensor, and a uniform crack formed over the entire surface by concentrating stress along the groove. To improve the sensitivity and selectivity of the sensor, we generated the cracks in a controlled direction. The proposed strain sensor exhibited high sensitivity and excellent fidelity compared to the other reported metal strain sensors. The gauge factor of the proposed V-groove-induced crack sensor is 10-fold higher than the gauge factor of the reported metal strain sensors. In addition, the fabricated V-groove-based strain sensor exhibited rapid response and recovery times. The practical feasibility of the proposed V-groove-induced crack-based strain sensor is demonstrated through human motion monitoring and the generation of Morse code. The proposed V-groove crack sensor can detect multiple motions in a variety of human activities and is anticipated to be utilized in several applications due to its high durability and reproducibility.

8.
Waste Manag Res ; 39(12): 1471-1479, 2021 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-33719778

RESUMO

The Ministry of Environment, South Korea, is involved in efforts to reduce safety-related accidents that could occur during hazardous waste disposal and minimise the environmental impacts of waste disposal. To reach such goals, new factors have been added that contribute to the hazardous characteristics of hazardous waste. The Ministry is also expanding regulations on inorganic and organic components present in hazardous waste for these factors and continues to correct the classification system to establish standards for waste components. Metallic dust, for example, is mostly generated during the operation of melting furnaces or precipitators and dangerous materials contained in this dust may cause accidents, such as explosions or fires. South Korean accident cases have confirmed that waste containing hazardous materials, such as Mg, Al and Mg-Al alloys, can cause such events. Therefore, this study analysed 28 dust samples collected from the dust accumulated in precipitators in 28 metal manufacturing facilities in South Korea. Nine samples were flammable and four samples were reactive to water. Two samples also exhibited leaching toxicities. The results applied to relevant laws in South Korea showed that the proportion of waste containing hazardous characteristics increased from 7.14% in the previous management category to 39.29% in the extended category, an overall increase of 32.15 percentage points.


Assuntos
Poeira , Eliminação de Resíduos , Poeira/análise , Resíduos Perigosos , Indústria Manufatureira , República da Coreia
9.
Sensors (Basel) ; 13(12): 16672-81, 2013 Dec 04.
Artigo em Inglês | MEDLINE | ID: mdl-24304643

RESUMO

We report fabrication of a microneedle-based three-electrode integrated electrochemical sensor and in-vitro characterization of this sensor for glucose sensing applications. A piece of silicon was sequentially dry and wet etched to form a 15 × 15 array of tall (approximately 380 µm) sharp silicon microneedles. Iron catalyst was deposited through a SU-8 shadow mask to form the working electrode and counter electrode. A multi-walled carbon nanotube forest was grown directly on the silicon microneedle array and platinum nano-particles were electrodeposited. Silver was deposited on the Si microneedle array through another shadow mask and chlorinated to form a Ag/AgCl reference electrode. The 3-electrode electrochemical sensor was tested for various glucose concentrations in the range of 3~20 mM in 0.01 M phosphate buffered saline (PBS) solution. The sensor's amperometric response to the glucose concentration is linear and its sensitivity was found to be 17.73 ± 3 µA/mM-cm2. This microneedle-based sensor has a potential to be used for painless diabetes testing applications.


Assuntos
Técnicas Biossensoriais/instrumentação , Técnicas Biossensoriais/métodos , Glucose/química , Eletrodos , Nanotubos de Carbono , Agulhas , Platina/química , Silício/química , Prata/química
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