1.
Gastroenterology
; 156(6): e1-e3, 2019 05.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30240664
2.
Dalton Trans
; 46(46): 16306-16314, 2017 Nov 28.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29140393
RESUMO
The magnetostructural correlation of the hexakis-dmso cobalt(ii) complex, [Co(dmso)6](BPh4)2 (dmso: dimethylsulfoxide), was investigated by single-crystal X-ray diffraction study and magnetic measurements. The magnetic analysis concluded the negative Δ value (H = Δ(L - 2/3) + E(L - L) - (3/2)κλL·S + ß[-(3/2)κLu + geSu]·Hu (u = x, y, z)), and this was explained by the tetragonal elongation of the octahedral geometry. The magnetostructural correlation was ascertained by both the angular overlap model calculation and the density functional theory calculation.