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1.
Zhongguo Yi Liao Qi Xie Za Zhi ; 48(2): 160-166, 2024 Mar 30.
Artigo em Chinês | MEDLINE | ID: mdl-38605615

RESUMO

In response to the issues of insufficient stability and accuracy in dry chemical detection using reflectance photometry, caused by the divergence and multiple internal reflections of the reflected light signal from the sample and the multilayer dry film test strip, a dry chemical reflectance photometry detection system based on an integrating sphere is designed. Firstly, an integrating sphere device is incorporated to reduce signal divergence and loss, ensuring even detection of the sample's reflected light signal and improving detection stability. Secondly, Light Tools optical simulation analysis is performed, and an integrating sphere detection model is established. Thirdly, the Williams-Clapper equation is employed to correct the error in reflectance density caused by multiple internal reflections, enhancing detection accuracy. Experimental validation demonstrates that the developed integrating sphere-based dry chemical reflectance photometry detection system improves the stability and accuracy of the detection system.


Assuntos
Fotometria , Refração Ocular , Simulação por Computador
2.
Tetrahedron ; 67(52): 10105-10118, 2011 Dec 30.
Artigo em Inglês | MEDLINE | ID: mdl-23750054

RESUMO

Our efforts in constructing the ABD-ring of phomactin A through an intramolecular oxa-[3 + 3] annulation strategy is described. This struggle entailed finding a practical and efficient preparation of annulation precursor, and a realization of the unexpected competing regioisomeric pathway. The success entailed accessing the A-ring through Diels-Alder cycloaddition of Rawal's diene. Furthermore, the discovery that the regioisomers from the annulation existed as atropisomers with respect to the D-ring olefin and that they could be equilibrated to the desired ABD-tricycle, allowing large quantities of tricycle to be accessed.

3.
Adv Synth Catal ; 350(18): 2885-2891, 2008 Dec 18.
Artigo em Inglês | MEDLINE | ID: mdl-20351791

RESUMO

An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.

4.
Adv Synth Catal ; 350(18)2008 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-24273477

RESUMO

An enantioselective synthesis of the ABD-ring of (-)-phomactin A is described here. The sequence features Rawal's asymmetric Diels-Alder cycloaddition. The overall length is significantly reduced from our previous attempt.

5.
Org Biomol Chem ; 4(14): 2679-82, 2006 Jul 21.
Artigo em Inglês | MEDLINE | ID: mdl-16826290

RESUMO

Tandem azidination- and hydroazidination-Huisgen [3 + 2] cycloadditions of ynamides are described here. These processes are regioselective and chemoselective, leading to the synthesis of chiral amide-substituted triazoles.


Assuntos
Alcinos/química , Amidas/química , Azidas/química , Triazóis/síntese química , Ciclização , Estrutura Molecular , Estereoisomerismo
6.
J Am Chem Soc ; 124(51): 15186-7, 2002 Dec 25.
Artigo em Inglês | MEDLINE | ID: mdl-12487589

RESUMO

A rhodium(I)-catalyzed allenic Alder ene reaction to prepare cross-conjugated trienes has been discovered. The scope and limitations are currently being investigated, and the results obtained to date are reported on. This method shows enticing functional group compatibility by tolerating terminal and internal alkynes, hydroxyl, sulfonamide, ether, and diester groups. Progress has been made to increase the stereoselectivity of the olefinic side chain via an unprecendented iridium(I) catalyzed Alder-ene reaction.


Assuntos
Alcenos/síntese química , Hidrocarbonetos Cíclicos/síntese química , Ródio/química , Alcenos/química , Alcinos/química , Catálise , Ciclização , Compostos Organometálicos/química , Estereoisomerismo
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