1.
Org Biomol Chem
; 13(22): 6162-5, 2015 Jun 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25947551
RESUMO
The regiochemical outcome of Suzuki couplings of non-symmetric dibromobenzenes is investigated. Selectivities are dependent on the proximity of the bromine atom to alkene substituents, not on steric or electronic effects. Extension to a one-pot three-component Suzuki reaction leads to efficient terphenyl syntheses.