RESUMO
In this study, two quaternary ammonium salts derived from l-lipoic acid were applied for self-assembled monolayers formation on rough structured gold surface. The derivatives differ in functionality since one possesses simple quaternary ammonium group whereas the other one is carboxybetaine ester containing quaternary ammonium group with pH hydrolysable ester group as a pendant. The response of surface wettability to ion exchange between Cl- and perfluorooctanoate, kinetics and gradient wettability were examined by water contact angle measurement and confirmed by X-ray photoelectron spectroscopy. Furthermore, adhesion forces related to applied counterion on the entire surface and after hydrolysis were investigated by atomic force microscopy measurement at nanometer scales. A dramatic change in wettability upon counterion exchange from superhydrophilic for Cl- to very or superhydrophobic for perfluorooctanoate in a repeatable manner was observed for both derivatives. Kinetics of counterion exchanges revealed faster hydration of simple quaternary derivate. The wettability gradient could be designed from superhydrophobic to superhydrophilic either in a reversible manner by simple immersion of the modified surface in a counterion solution modulated by ionic strength or in an irreversible manner for carboxybetaine ester derivate by time-controlled hydrolysis to charge balanced carboxybetaine.
RESUMO
Artificial enzyme mimetics is a current research area with much interest from scientific community. Some nanomaterials have been found to possess intrinsic enzyme-mimetic activity. In this study, VOx nanoflakes with mixed-phases are synthesized via a quick and facile one-pot synthetic process and their Fenton reaction and enzyme-mimetic activities have been studied. The results show that obtained VOx is not only highly effective Fenton reagent, completely decomposing Rhodamine B (RhB) within less than 1 min, but also exhibits excellent intrinsic peroxidase-like activity as well as H2O2 catalase-like activity. Our results suggest that this VOx nanomaterial can effectively mimic the enzyme cascade reaction of horseradish peroxidase (HRP). VOx nanoflakes have excellent affinity toward 3,3',5,5'-tetramethylbenzidine (TMB) for oxidation and henceforth, it can be used for the colorimetric assay of glucose and H2O2. Moreover, this study indicates that VOx nanoflakes can also be used for the efficient degradation of environmental pollutants.
RESUMO
Oxygen-sensitive photoreversible intelligent ink capable of assessment with the human eye is an ongoing demand in the modern era. In the food industry, redox-dye-based oxygen indicator films have been proposed, but the leaching of dyes from the film that contaminates the food is one unsolved issue. On the other hand, it is also highly desirable to develop rewritable paper that significantly reduces the pressure on modern society for the production and consumption of paper. Herein, we have developed an oxygen-deficient TiO2â¯-â¯x/methylene blue (MB) sol without relying on external sacrificial electron donors (SEDs) for photoreversible color switching. Oxygen vacancies in TiO2â¯-â¯x can work as electron donor to favor the adsorption of the substrate and improve the charge separation that is required for the redox-based color-switching system. The problems of rewriteable paper and food packaging are addressed as two sides of a single coin in this article. We have used hydroxyethyl cellulose (HEC) for rewritable paper that can significantly delay the oxidation of leuco-MB (LMB) through hydrogen bonding and retain the printed information for a long time. The dye leaching from oxygen indicator films is also significantly reduced (only 1.54%) by using furcelleran as the coating polymer that is extracted from edible red seaweed.
