Measurement Methods for Droplet Adhesion Characteristics and Micrometer-Scale Quantification of Contact Angle on Superhydrophobic Surfaces: Challenges and Opportunities.

Inspired by nature, superhydrophobic surfaces have been widely studied. Usually the wettability of a superhydrophobic surface is quantified by the macroscopic contact angle. However, this method has various limitations, especially for precision micro devices with superhydrophobic surfaces, such as biomimetic artificial compound eyes and biomimetic water strider robots. These precision micro devices with superhydrophobic surfaces proposed a higher demand for the quantification of contact angles, requiring contact angle quantification technology to have micrometer-scale measurement capabilities. In this review, it is proposed to achieve micrometer-scale quantification of superhydrophobic surface contact angles through droplet adhesion characteristics (adhesion force and contact radius). Existing contact angle quantification techniques and droplet characteristics' measurement methods were described in detail. The advancement of micrometer-scale quantification technology for the contact angle of superhydrophobic surfaces will enhance our understanding of superhydrophobic surfaces.

Measuring the Adhesion Force and the Spreading Radius between Droplets and a Solid Surface during Short-Time Spreading.

When a droplet contacts a solid surface, the liquid spreads over the solid surface to minimize the total surface energy. This phenomenon is widespread in industrial production and nature, so research on droplet spreading is of great significance. Here, the adhesion force and the spreading radius during droplet spreading can be quantified using a highly sensitive photoelectric method. It is possible to study droplet spreading from two dimensions at the microscale. The adhesion force is measured by an optical lever, and the spreading radius is measured by an ultrafast electrical method. The measurement method allows the force resolution and the space-time resolution to reach the nanonewton lever and the nanosecond lever, respectively. We obtain the maximum spreading radius and the maximum adhesion force during short-time spreading through our technique. Moreover, we numerically simulate the droplet spreading process through the lattice Boltzmann solver and confirm the observed results. This study provides a new experimental technique for studying droplet spreading dynamics from multiple perspectives, which can deepen our understanding of droplet spreading and provide guidance for the development of new techniques.