Design and properties of graded polyamide12/hydroxyapatite scaffolds based on primitive lattices using selective laser sintering.

Scaffolds with favorable biological characteristics and controlled functional gradient architectures are preferable for the repair of damaged tissues in bone tissue engineering. In this study, the triply periodic minimal surfaces (TPMS) were introduced to design functional gradient porous scaffolds based on Primitive lattices which were then manufactured by selective laser sintering (SLS) using pure polyamide12 (PA12) material and PA12/hydroxyapatite (HA) composite material. The mechanical properties and permeability of the scaffolds were then evaluated by mechanical compression experiments and computational fluid dynamics (CFD) analysis. The radial-graded scaffold was found to have superior good mechanical properties and permeability and be favorable for the subsequent growth of bone tissue. Further, the optimal PA12/HA composition was determined by analyzing the effect of the addition of HA particles on the hydrophilicity and mechanical properties of the composite scaffold. Additionally, the cytotoxicity tests were performed to evaluate the effects of PA12/HA gradient scaffold on cell growth. The obtained results demonstrate that the radial gradient scaffold with 15% HA addition exhibits a feasible combination of comprehensive performance and biological activity, indicating a great application potential in the field of bone tissue engineering.

Antiferromagnetism Emerging in a Ferromagnet with Gain.

We present a theoretical mapping to show that a ferromagnet with gain (loss) is equivalent to an antiferromagnet with an equal amount of loss (gain). Our findings indicate a novel first-order ferromagnet-antiferromagnet phase transition by tuning the gain-loss parameter. As an appealing application, we demonstrate the realization as well as the manipulation of the antiferromagnetic Skyrmion, a stable topological quasiparticle not yet observed experimentally, in a chiral ferromagnetic thin film with gain. We also consider ferromagnetic bilayers with balanced gain and loss and show that the antiferromagnetic Skyrmion can be found only in cases with a broken parity-time symmetry phase. Our results pave the way for investigating the emerging antiferromagnetic spintronics and parity-time symmetric magnonics in ferromagnets.

Radiation synthesis and performance of novel cellulose-based microsphere adsorbents for efficient removal of boron (III).

A novel cellulose-based microsphere containing glucamine groups, referred as CVN, was successfully synthesized by radiation-induced graft polymerization of 4-vinylbenzyl chloride onto cellulose microspheres and subsequent functionalization with N-methyl-d-glucamine. The adsorption by CVN for boron (III) from aqueous solutions was evaluated systematically by batch adsorption technique. Langmuir models could fit well with the adsorption behavior of CVN. The CVN adsorbents exhibited a high adsorption capacity up to 12.4mgg-1 towards boron (III) over the wide pH range of 5-8. After the addition of chloride salts, the boron uptake of CVN was enhanced that was attributed to the compensation of the surface charge generated by boron (III) adsorption leading to favor the adsorption. At high concentrations of salts, the ionic strength and different salts have no effect on the adsorption of boron(III). This work provides a new sustainable, cost effective material as a promising specific adsorbent for the removal of boron (III) from saline solutions.

Wave manipulation with magnetically tunable metasurfaces.

Tunable metasurfaces have emerged as an efficient approach to manipulate the wave propagation. Different from previous work concentrating on electrically tunable mechanisms, here we demonstrate a magnetically tunable metasurface composed of ferrite rods and metallic foils. By tuning the thickness of ferrite rods, metasurfaces with different rod thickness gradients are obtained. The incident wave can propagate through the metasurfaces due to the extraordinary transmission. The deflection angle of the transmission wave is not only influenced by the rod thickness gradient, but also tuned by the applied magnetic field. This approach opens a way for the design of tunable metasurfaces.

Radiolysis of crown ether-ionic liquid systems: identification of radiolytic products and their effect on the removal of Sr(2+) from nitric acid.

The quantitative analysis and identification of the radiolytic products of dicyclohexano-18-crown-6 (DCH18C6), 4',4''(5'')-di-tert-butyldicyclohexano-18-crown-6 (DtBuCH18C6) and benzo-18-crown-6 (B18C6) in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([C4mim][NTf2]) ionic liquid after irradiation were performed for the first time. It was found that the yield for radiolytic destruction of DCH18C6 and DtBuCH18C6 was less than that for B18C6. The main radiolytic products were identified as substituted crown ethers formed between crown ether and active radicals such as methyl, trifluoromethyl, butyl, and [C4mim]˙ radicals generated during the irradiation of the crown ether-[C4mim][NTf2] system. The radiation effect on the Sr(2+) partitioning of the crown ether-[C4mim][NTf2] system shows further that DCH18C6-[C4mim][NTf2] and DtBuCH18C6-[C4mim][NTf2] still have good extractability for Sr(2+) after irradiation. The extraction ability of DCH18C6-[C4mim][NTf2] and DtBuCH18C6-[C4mim][NTf2] system for Sr(2+) decreased by 14.4% and 18.2% even at 500 kGy, respectively.