Study on the Fractal Characteristics and Seepage Properties of Channels Filled by Coal Particles.

Studying the seepage process in fracture channels (where coal particles are deposited) is of great significance for improving the performance of both on-site coal seam water injection and dust reduction technology. Through a self-developed simulation experiment of water-borne coal particle migration and accumulation and computer graphics, we investigated the influencing factors of particle accumulation in water injection and their influence law on seepage, discussed the interaction relationship between the fractal structure of coal and the characteristics of accumulated coal particles, and established a new fractal model of fracture permeability based on different particle accumulation states. The results show that the seepage velocity and the particle size jointly affect the migration and accumulation process of water-borne coal particles. When the coal particle size is constant and the seepage velocity increases, then the output of the coal powder increases, the deposition decreases, and the structure fractal dimension D3 of fractures decreases. At the same seepage velocity, with the increase of the coal particle size, the output of coal powder decreases, the deposition increases, and the structure fractal dimension D3 of fractures increases. In addition, the amount of coal powder produced in the intermittent water injection process is smaller than that produced in the continuous water injection process, more easily leading to accumulation. The variation law of the theoretical permeability with porosity remains consistent for different particle accumulation states: with the increase of porosity, the structure fractal dimension D3 of fractures decreases, while the theoretical permeability increases. The above research results can provide a theoretical basis for reducing the seepage damage of coal under the particle blocking effect.

Three-Dimensional Nickel Cobalt Phosphide Nanocrosses with Well-Defined Axial Arms for Efficient Oxygen Evolution Reaction.

Concave nanostructure with highly branched architecture and abundant step atoms is one kind of desirable materials for energy conversion devices. However, current synthetic strategies for non-noble metal-based NiCoP concave nanostructure still remain challenging. Herein, we demonstrate a site-selective chemical etching and subsequent phosphorating strategy to fabricate highly branched NiCoP concave nanocrosses (HB-NiCoP CNCs). The HB-NiCoP CNCs are consisted of six axial arms in three-dimensional space and each protruding arm is equipped with high-density atomic steps, ledges and kinks. As an electrocatalyst towards oxygen evolution reaction, the HB-NiCoP CNCs exhibit remarkably enhanced activity and stability, with small overpotential of 289 mV to reach 10 mA cm-2 , surpassing the NiCoP nanocages and commercial RuO2 . The superior OER performance of HB-NiCoP CNCs is originated from the highly branched concave structure, the synergistic effect between bimetal Ni and Co atoms, as well as the electronic structure modulation from P.

A rapid electrochemical method to recycle carbon fiber composites using methyl radicals.

We introduce an electrochemical approach to recycle carbon fiber (CF) fabrics from amine-epoxy carbon fiber-reinforced polymers (CFRPs). Our novel method utilizes a Kolbe-like mechanism to generate methyl radicals from CH3COOH to cleave C-N bonds within epoxy matrices via hydrogen atom abstraction. Recovered CFs are then remanufactured into CFRPs without resizing.