Versatile Liquid Metal/Alginate Composite Fibers with Enhanced Flame Retardancy and Triboelectric Performance for Smart Wearable Textiles.

Liquid metal (LM) shows the superiority in smart wearable devices due to its biocompatibility and electromagnetic interference (EMI) shielding. However, LM based fibers that can achieve multifunctional integrated applications with biodegradability remain a daunting challenge. Herein, versatile LM based fibers are fabricated first by sonication in alginate solution to obtain LM micro/nano droplets and then wet-spinning into LM/alginate composite fibers. By mixing with high-concentration alginate solution (4-6 wt.%), the LM micro/nano droplets stability (colloidal stability for > 30 d and chemical stability for > 45 d) are not only improved, but also facilitate its spinning into fibers through bimetallic ions (e.g., Ga3+ and Ca2+ ) chelation strategy. These resultant fibers can be woven into smart textiles with excellent flexibility, air permeability, water/salt resistance, and high temperature tolerance (-196-150 °C). In addition, inhibition of smoldering result from the LM droplets and bimetallic ions is achieved to enhance flame retardancy. Furthermore, these fibers combine the exceptional properties of LM droplets (e.g., photo-thermal effect and EMI shielding) and alginate fibers (e.g., biocompatibility and biodegradability), applicable in wearable heating devices, wireless communication, and triboelectric nanogenerator, making it a promising candidate for flexible smart textiles.

3D Printing of Ionogels with Complementary Functionalities Enabled by Self-Regulating Ink.

Shaping soft and conductive materials into sophisticated architectures through 3D printing is driving innovation in myriad applications, such as robotic counterparts that emulate the synergic functions of biological systems. Although recently developed multi-material 3D printing has enabled on-demand creation of intricate artificial counterparts from a wide range of functional viscoelastic materials. However, directly achieving complementary functionalities in one ink design remains largely unexplored, given the issues of printability and synergy among ink components. In this study, an easily accessible and self-regulating tricomponent ionogel-based ink design to address these challenges is reported. The resultant 3D printed objects, based on the same component but with varying ratios of ink formulations, exhibit distinct yet complementary properties. For example, their Young's modulus can differ by three orders of magnitude, and some structures are rigid while others are ductile and viscous. A theoretical model is also employed for predicting and controlling the printing resolution. By integrating complementary functionalities, one further demonstrates a representative bioinspired prototype of spiderweb, which mimics the sophisticated structure and multiple functions of a natural spiderweb, even working and camouflaging underwater. This ink design strategy greatly extends the material choice and can provide valuable guidance in constructing diverse artificial systems by 3D printing.

A highly transparent ionogel with strength enhancement ability for robust bonding in an aquatic environment.

An underwater adhesive with strong, fast and stable adhesion ability has become an urgent requirement for various industrial applications. Herein, a highly transparent ionogel based on a fluorine-rich poly(ionic liquid) and the corresponding ionic liquid monomer has been developed and used as an underwater adhesive. Strong and stable underwater adhesion can be realized by taking advantage of the excellent interface adaptability and high mechanical strength of this ionogel. The underwater adhesion strength could reach as high as 5.18 ± 0.27 MPa. In addition, it can also realize robust bonding over a wide pH range (0-14). A waterproof transparent tape based on the ionogel has also been developed and it can carry out repair work in wet and aquatic environments.

Underwater Communication and Optical Camouflage Ionogels.

Marine animals, such as leptocephalus and jellyfish, can sense external stimuli and achieve optical camouflage in the aquatic environment. Fabricating an intelligent soft sensor that can mimic the capabilities of transparent marine animals and function underwater can enable transformative applications in various novel fields. However, previously reported soft sensors struggle to meet the requirements of adhesion, self-healing ability, optical transparency, and stable conductivity in the aquatic environment. Herein, high-performance ionogels by virtue of ion-dipole and ion-ion interactions between fluorine-rich poly(ionic liquid) and ionic liquid are designed. The hydrophobic dynamic viscoelastic networks provide excellent properties for ionogels, including optical transparency, adjustable mechanical properties, underwater self-healing ability, underwater adhesiveness, conductivity, and 3D printability. A mechanically compliant and visually invisible underwater soft sensor based on ionogel is developed. This sensor can achieve optical camouflage, human-body-motion detection, and barrier-free communication in the aquatic environment. A novel contactless sensing mechanism based on changing the electron transfer pathway is proposed. Several interesting functions, such as detection of water environment changes, recognition of objects, delivery of information, and even identification of human standing posture can be realized. Importantly, the ionogel sensor can avoid fatigue and physical damage in the sensing process.

Selective Adsorption and Separation of Organic Dyes with Spherical Polyelectrolyte Brushes and Compressed Carbon Dioxide.

Dye-containing wastewater has caused serious environmental pollution. Herein, rationally designed spherical polyelectrolyte brushes (SPBs) with cationic charges, polystyrene-poly(2-aminoethylmethacrylate hydrochloride) (PS-PAEMH) as the absorbent, and compressed carbon dioxide as the antisolvent are proposed for the separation of the anionic dye eosin Y (EY) from a solution of mixed dyes. The adsorption behavior of EY onto PS-PAEMH was highly dependent on CO2 pressure, contact time, and initial concentration. The maximum adsorption capacity of PS-PAEMH was 335.20 mg g-1 . FTIR and UV/Vis measurements proved that the electrostatic interactions between EY and PS-PAEMH played an important role in the absorbance process. The adsorption process fitted the pseudo-second-order kinetic model and Freundlich isotherm model very well. The combined dye and polymer brush could be easily separated through ion exchange by adding an aqueous solution of NaCl. Recovered PS-PAEMH retained a high adsorption capacity even after ten cycles of regeneration. This method provides a simple and effective way to separate ionic materials for environmental engineering.