Trace amounts of palladium catalysed the Suzuki-Miyaura reaction of deactivated and hindered aryl chlorides.

Electron-rich and hindered aryl chlorides are the most challenging substrates in Suzuki-Miyaura cross-coupling (SMC) reactions. Herein, we report a highly efficient catalytic system for the SMC reaction using trace amounts of commercially available catalysts [Pd(PPh3)4/(t-Bu)PCy2; Pd loading as low as 9.5 × 10-5 mol%]. This catalytic system can efficiently couple deactivated and sterically hindered aryl chlorides with various substituted phenylboronic acids, even in one-pot multiple coupling reactions (yield of products up to 92%). The impact of solvents on SMC reactions and the mechanisms of by-product formation in aryl boronic acid couplings are analyzed using density functional theory (DFT). Utilizing trace amounts of commercially available catalysts avoids complex synthesis, reduces costs, and minimizes metal residues.

Photochemical acridone-mediated direct arylation of (hetero)arenes with aryl diazonium salts.

A metal-free photochemical C-H direct arylation using acridone as a photoredox catalyst to facilitate the reaction is described. Diazonium salts as precursors for aryl radicals, demonstrated by a fluorescence quenching experiment and free radical trapping experiment, allow the functionalization of (hetero)arenes under mild conditions. A series of valuable substituted biaryl and aryl-heteroaryl compounds were prepared in moderate to good yields via the coupling. Moreover, this methodology is shown to be applicable to scale-up synthesis.

Integrated green mining technology of "coal mining-gangue washing-backfilling-strata control-system monitoring"-taking Tangshan Mine as a case study.

In Tangshan Mine, there are four engineering problems, including the layout of multiple seam mining system, serious environmental damages caused by gangue accumulation and surface collapse, nearly 100 million tons of three under coal (coal trapped under buildings, water bodies, and railways) to be released, and the control accuracy of stratum formations to be improved. The work developed the integrated green mining technology of coal mining, gangue washing-backfilling, strata control, and system monitoring. First, a production system was designed for surface-underground transportation of backfilling materials, underground gangue separation, multiple-seam combined backfilling, and mining. Second, key backfilling equipment was developed at mining heights of 2.2 and 3.5 m by backfilling system layout and precise stratum control methods in Tangshan Mine. After real-time monitoring of stope pressure, backfilling effect, and surface deformation, we evaluated the implementation effect of mining, washing, and backfilling technology. The integrated coal mining in seams 5, 8, and 9 of Tangshan Mine showed that the four backfilling surfaces of T3281, T3292, F5001, and F5002 recovered 946,000 t of raw coal and 1.18 million tons of filled gangue, with a net profit of 363.20 million yuan. The maximum land subsidence values (18, 119, 64, and 47mm) were far lower than the deformation extremes based on the requirements of surface building protection.