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J Environ Sci (China) ; 19(11): 1387-92, 2007.
Artigo em Inglês | MEDLINE | ID: mdl-18232236

RESUMO

By dynamic method under UV irradiation, commercial melt-blown polypropylene (PPMB) filter element was modified with acrylamide (AAm) using benzophenone (BP) as initiator. Attenuated total reflection-Fourier transform infrared spectroscopy and scanning electron microscope verified that polyacrylamide chain was grafted on the fiber surface of PPMB filter element. Elemental content analysis with energy dispersive X-ray of fibers revealed that the polymerization content in the inner part of filter element was relatively higher than that in the outer. Degree of grafting changed with initiator concentration, monomer concentration, reaction temperature and reached 2.6% at the reaction condition: CBP=0.06 mol/L, CAAm=2.0 mol/L, irradiation time: 80 min, temperature: 600 degrees C. Relative water flux altered with the hydrophilicity and pore size of filter element. In the antifouling test, the modified filter gave greater flux recovery (approximately 70%) after filtration of the water extract of Liuweidihuang, suggesting that the fouling layer was more easily reversible due to the hydrophilic nature of the modified filter.


Assuntos
Acrilamida/química , Acrilamida/efeitos da radiação , Filtros Microporos , Polímeros/química , Polímeros/efeitos da radiação , Polipropilenos/química , Raios Ultravioleta , Filtração/instrumentação , Microscopia Eletrônica de Varredura , Solventes , Espectroscopia de Infravermelho com Transformada de Fourier , Temperatura
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