The loading of Fe ions on N-doped carbon nanosheets to boost photocatalytic cascade for water disinfection.

The pervasive presence of pathogenic bacteria in water environment poses a serious threat to public health. Here, a photocatalytic cascade was developed to reveal great water disinfection. Firstly, N-doped carbon nanosheets (N-CNSs) about 30-50 nm in size were synthesized by a hydrothermal strategy. It revealed wide-spectrum photocatalysis for H2O2 generation via a typical two-step single-electron process. A Fenton agent (Fe ion) was loaded, N-CNSs-Fe can in-situ convert photocatalytic H2O2 into ·OH with high oxidation potential. Moreover, its Fenton active is three times greater than pure Fe2+ owing to electron enrichment from N-CNSs to Fe for Fe3+/Fe2+ cycle. Further investigation displayed that Fe loading also could decrease bad gap and promote charge separation to boost photocatalysis. In addition, N-CNSs-Fe possesses positive surface potential to exhibit strong interaction with negative bacteria, facilitating the capture. Therefore, the nanocomposite can effectively inactivate E. coli with a lethality rate of 99.7 % under stimulated sunlight irradiation. In addition, it also was employed to treat a complex lake water sample, revealing great antibacterial (95.1 %) and dye-decolored (92.3 %) efficiency at the same time. With novel biocompatibility and antibacterial ability, N-CNSs-Fe possessed great potential for water disinfection.

Enhancing triethylamine sensing of ZIF-derived ZnO microspheres arising from cobalt doping and defect engineering.

Reasonable doping is beneficial to the generation of defects, which is a feasibility strategy to improve the ZnO sensing performance. Herein, we presented an in situ self-sacrificing template strategy for fabricating Co doped h-ZnO core-shell structures (h-ZnO/ZnCox) with different defect contents, pyrolyzing hierarchical porous ZnO (h-ZnO) sub-microspheres coated by zeolite imidazolate frameworks (h-ZnO/ZIF-ZnCox). The investigations of X-ray photoelectron (XPS), photoluminescence (PL) and Raman spectra indicate that donor defects include zinc interstitial (Zni) and oxygen vacancy (VO) in h-ZnO/ZnCox can be tuned by Co dopant (x = 0-30%). Resultantly, the h-ZnO/ZnCox exhibits a significantly enhanced response and selectivity towards triethylamine (TEA), beyond the undoped h-ZnO, and 15% Co-doped h-ZnO (h-ZnO/ZnCo15%) conducts the maximum responses of 1020 to 50 ppm TEA at 573 K, in the top set for the similar type of sensors. Further, the sensing mechanism of h-ZnO/ZnCox is elaborated, possibly resulting from abundant active oxygen species conversed from more oxygen adsorbed which corresponds to cobalt doping generating rich donor-related defects and additional electrons in h-ZnO/ZnCo15%.