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Environ Sci Pollut Res Int ; 24(7): 6002-6012, 2017 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-26676539

RESUMO

For this work, a phenol solution model was treated by an advanced oxidation process (AOPs), using the heterogeneous catalyst TiO2/BiPO4 and hydrogen peroxide combined with UVA for 240 min. An annular reactor containing a UVA lamp (80 W) was employed. A central composite rotacional design was developed employing a TiO2/BiPO4 concentration of 87 mg L-1 and a hydrogen peroxide concentration of 1800 mg L-1, being evaluated by the degradation percentage and phenol mineralization percentage as responses; 94.30 and 67.00 % were obtained for the phenol degradation and total organic carbon (TOC) conversion, respectively. The lumped kinetic model (LKM) was applied and a satisfactory profile of the residual fractions of the organic compounds present in the liquid phase as a time function with a determination coefficient (R 2 = 0.9945). The toxicity tests employing microbiological species indicated that the organisms tested for the evaluation of the toxic compounds present in the contaminated samples presented a practical low cost test, rapid execution, and high sensibility as an indicator of the presence of toxic substances in liquid effluents.


Assuntos
Bismuto , Fenol , Fotólise , Titânio , Poluentes da Água , Bismuto/química , Bismuto/toxicidade , Fenol/análise , Fenol/química , Titânio/química , Titânio/toxicidade , Poluentes da Água/análise , Poluentes da Água/química , Purificação da Água
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