Re-Entrant Honeycomb Auxetic Structure with Enhanced Directional Properties.

This paper presents a modified re-entrant honeycomb auxetic structure. The structure is constructed by adding an additional horizontal member between the vertical and re-entrant member of the semi-re-entrant honeycomb model to increase the overall compliance of the structure in order to obtain higher values of negative Poisson's ratio (NPR). An analytical model of the structure is presented, taking into account the bending, shear, and axial deformations. The model is verified using finite element analysis (FEA) and tensile testing. The results of FEA and tensile testing corroborate the results of the presented mathematical model. The structure is also compared to the existing re-entrant honeycomb structure. The newly added strut has shown a direct effect on the directional properties of the overall structure. With an increase in the newly added strut to re-entrant lengths, NPR was significantly enhanced in the x-direction and reduced in the y-direction loadings. The structure shows an improved Young's modulus compared to solid material in both loading directions, especially for the low values of the new strut and re-entrant lengths ratio. The structure also shows that high NPR can be achieved for low relative density compared to semi re-entrant honeycomb structure.

Nanomaterials for biogas augmentation towards renewable and sustainable energy production: A critical review.

Nanotechnology is considered one of the most significant advancements in science and technology over the last few decades. However, the contemporary use of nanomaterials in bioenergy production is very deficient. This study evaluates the application of nanomaterials for biogas production from different kinds of waste. A state-of-the-art comprehensive review is carried out to elaborate on the deployment of different categories of nano-additives (metal oxides, zero-valent metals, various compounds, carbon-based nanomaterials, nano-composites, and nano-ash) in several kinds of biodegradable waste, including cattle manure, wastewater sludge, municipal solid waste, lake sediments, and sanitary landfills. This study discusses the pros and cons of nano-additives on biogas production from the anaerobic digestion process. Several all-inclusive tables are presented to appraise the literature on different nanomaterials used for biogas production from biomass. Future perspectives to increase biogas production via nano-additives are presented, and the conclusion is drawn on the productivity of biogas based on various nanomaterials. A qualitative review of relevant literature published in the last 50 years is conducted using the bibliometric technique for the first time in literature. About 14,000 research articles are included in this analysis, indexed on the Web of Science. The analysis revealed that the last decade (2010-20) was the golden era for biogas literature, as 84.4% of total publications were published in this timeline. Moreover, it was observed that nanomaterials had revolutionized the field of anaerobic digestion, methane production, and waste activated sludge; and are currently the central pivot of the research community. The toxicity of nanomaterials adversely affects anaerobic bacteria; therefore, using bioactive nanomaterials is emerging as the best alternative. Conducting optimization studies by varying substrate and nanomaterials' size, concentration and shape is still a field. Furthermore, collecting and disposing nanomaterials at the end of the anaerobic process is a critical environmental challenge to technology implementation that needs to be addressed before the nanomaterials assisted anaerobic process could pave its path to the large-scale industrial sector.

Research Trends in the Use of Polyaniline Membrane for Water Treatment Applications: A Scientometric Analysis.

Polyaniline (PANI), which is a member of the family of electrically conducting polymers, has been widely discussed as a potential membrane for wastewater treatment. Although a steady growth in PANI literature was observed, analyzing PANI literature quantitatively is still a novelty. The main aim of this study is to unearth the current research status, global trends, and evolution of PANI membranes literature and their use in water treatment applications over time. For this purpose, a scientometric study was performed consisting of bibliometric and bibliographic analysis. A total of 613 entities were extracted from Web of Science published during the last 50 years and were analyzed to map trends based on leading peer-reviewed journals, publication records, leading research disciplines, countries, and organizations. The study shows that the number of annual publications increased exponentially from 2005 to 2020 and is expected to keep increasing in the current decade. The Journal of Membrane Science published the highest number of articles and was identified as the most-cited journal in the field. China, India, and the USA were observed as the top three research hubs. The top-ranked authors in the field were Wang, Jixiao, and Wang, Zhi. To find research trends, four different clusters of keywords were generated and analyzed. The top five most frequent keywords turn out to be polyaniline, water, performance, membranes, and nanoparticles. The analysis suggests that the application of nanotechnology for modifying PANI membranes (using nanoparticles, nanotubes, and graphene specifically) is the future of this field. This study elucidates the research streamline of the field that may serve as a quick reference for early career researchers and industries exploring this field.

Wastewater treatment for ships experiencing large temperature changes： the activated sludge/membrane-biofilm reactor.

A particular challenge to treatment systems for ship wastewater comes from low and variable temperatures. We evaluated the temperature response (35-15 °C) of a novel biological treatment system involving activated sludge followed by a membrane-biofilm reactor: the activated sludge/membrane-biofilm reactor (AS-ABfMemR). In this study, a pilot-scale AS-ABfMemR achieved over 96% chemical oxygen demand (COD) and 94% total nitrogen (TN) removal from a ship wastewater (550-960 mgCOD·L-1 and 52-77 mgTN·L-1) with a continuous operation with a hydraulic retention time of 12 h at 25 °C. The effluent COD and TN concentrations met IMO discharge standards at temperatures as low as 17 °C, which reduced the energy consumption for wastewater heating. The COD and TN removals of the biofilm stage became important (up to 34% and 35%, respectively) at low temperatures, and this compensated for the deterioration in performance of the aerobic sludge. The genus Azospira dominated in the biofilm's denitrification removal for TN at low temperature. In addition, the buildup of trans-membrane pressure was so slow that backwashing was not needed over the 90 days of continuous operation. These conclusions indicate that the pilot-scale AS-ABfMemR technology is an effective way for real ship sewage treatment under temperature variations.

Metal-Organic Frameworks for Wastewater Decontamination: Discovering Intellectual Structure and Research Trends.

Due to their simple synthesis method and excellent properties, such as superior adsorption and regeneration capabilities, with a large surface area and tunable pores, metal-organic frameworks (MOFs) have emerged as a suitable option for wastewater treatment. Although an exponential growth in MOF literature has been observed in recent years, conducting a quantitative literature analysis of MOF application in wastewater treatment is a novelty. To fill this gap, a total of 1187 relevant publications were extracted from the Web of Science, published during the last 50 years, and analyzed using bibliometric and content analysis techniques. A bibliometric analysis was conducted to reveal growing publication trends, leading journals, prolific countries, and organizations; whereas, a content analysis was used to highlight key research themes and hot topics in this field. The analyses revealed that there is a strong international collaboration among authors, countries, and organizations. Chemical Engineering Journal, Journal of Hazardous Materials, and Journal of Environmental Chemical Engineering are the most prolific journals in this field. Furthermore, the use of MOFs for removing antibiotics from wastewater was identified as a recent hot topic. In addition, performance enhancements of MOFs, in terms of a higher adsorption capacity and water stability, were identified as topics of great interest. To cater to these issues, the application of graphene, graphene oxides, nanoparticles, and quantum dots was also observed in the research fronts in this field.

Substrate degradation, biodiesel production, and microbial community of two electro-fermentation systems on treating oleaginous microalgae Nannochloropsis sp.

Electro-fermentation system (EFS) emerges its effectiveness on treating microalgae for biodiesel production, but much is unknown about biodegradation behaviors, biodiesel characteristics, and microbial community. Compared with conventional fermentation system (CFS), microbial electrolysis cell-based EFS (MEC-EFS) and microbial fuel cell-based EFS (MFC-EFS) were investigated for the performance while treating microalgae Nannochloropsis sp. Results indicated that MEC-EFS presented much higher first-order decomposition rate coefficients of carbohydrates and proteins (1.212/d and 0.951/d) than those of CFS (0.615/d and 0.794/d) and MFC-EFS (0.518/d and 0.415/d). Compared with MFC-EFS, MEC-EFS showed better electrochemical performance (2.17 A/m3vs. 0.95 A/m3). Moreover, MEC-EFS reached the highest extracted lipid to biomass ratio (43.3%), followed by MFC-EFS (32.3%) and CFS (27.7%). By strengthened microbial biohydrogenation, MEC-EFS and MFC-EFS had higher saturated fatty acids ratio (78.8% and 70.6%) than that of CFS (56.1%). For MEC-EFS, enriched Ruminococcus and Geobacter in anodic biofilm might contribute to favorable biohydrogenation and electrochemical performance.

Influence of salinity on the biological treatment of domestic ship sewage using an air-lift multilevel circulation membrane reactor.

Recently, strict standards for ship domestic sewage discharge have been implemented by the International Maritime Organization (IMO). The high salinity of ship sewage was considered a key factor influencing the removal efficiency of ship sewage treatment systems. In the present study, the salinity effect on the removal of chemical oxygen demand (COD) and ammonia nitrogen (NH4+-N) from ship domestic sewage was investigated by using a novel air-lift multilevel circulation membrane reactor (AMCMBR). Enzyme activity analysis and wavelet neural network (WNN) models were built to determine the mechanisms of the process. The experimental results indicate that high salinity levels (> 21 g/L) had a negative impact on COD and NH4+-N removal efficiencies, and low saline concentrations (≤ 21 g/L) caused a negligible effect. The COD and NH4-N removal efficiencies were 84% and 97%, respectively, at a salinity of 21 g/L, which were higher than those at low salinities (i.e., 7 g/L and 14 g/L). Invertase and nitrate reductase had a close relationship with removal performance, and they can be considered important indicators reflecting the operation effort under saline environments. With high predictive accuracies, the constructed WNN models simulated the complex COD and NH4+-N removal processes well under different saline concentrations, ensuring the long-term stable operation of the AMCMBR under different salinities.

Effects of sono-assisted modified precipitation on the crystallinity, size, morphology, and catalytic applications of hematite (α-Fe2O3) nanoparticles: A comparative study.

The present study reports a new approach to improve the adsorption and catalytic properties of hematite nanoparticles (HNPs) synthesized via the chemical precipitation technique as one of the most applicable and preferable synthesis methods. This could be performed through controlling the particles' crystallinity where a facile ultrasonic pathway (UP) modification was introduced as a hybrid replacement for the conventionally-used magnetic stirring pathway (MP) using different precursor concentrations. The X-ray diffraction and Raman spectra define the pristine phase of α-Fe2O3 crystal with lower crystallinity and higher degrees of structural disorder for UP products. UP also shows smaller nanosized particles with lower bundles of aggregations and lumps formation in addition to lesser values of polydispersity index compared to the MP products. The catalytic performance supported by the reaction kinetics for the degradation of hazardous Rose Bengal and Congo Red dyes in light and dark, respectively, were examined. It revealed superior efficiencies for all of the UP products within a short span against the conventional MP and previous studies. Moreover, it was confirmed that UP products could catalyze the biodegradation reactions of green algae (Enteromorpha) and induced higher rates of biogas production. In addition to this, decreasing the precursor concentrations was found to be another key factor reducing the produced particles' crystallinity, size, and lumps formation as well as affecting the morphology development. Thus, the synergetic effects of applying the UP at low precursor concentrations could show a practical pathway for the synthesis of low-crystalline HNPs with enhanced properties for green applications over the conventional MP products. Hence, the obtained findings are of vital importance to show the improved catalytic efficiency of HNPs by shedding new light on controlling the crystallinity and developing the surface features in the conventional precipitation process via the proposed modification.

Effect of hydraulic retention time on pollutants removal from real ship sewage treatment via a pilot-scale air-lift multilevel circulation membrane bioreactor.

Developing a real ship sewage treatment system that not only satisfies the requirement of small space onboard but also meets the latest emission standards of International Maritime Organization (IMO) is still a challenging task for ship industry. To overcome these problems, in this study, a novel pilot-scale air-lift multilevel circulation membrane bioreactor (AMCMBR) was used to explore the effect of hydraulic retention time (HRT) on effluent chemical oxygen demand (COD) and total nitrogen (TN) while treating real ship sewage. Results indicated that the satisfactory removal efficiencies of COD and TN was achieved in the former stages (Re(COD) = 91.57% and 87.82%; Re(TN) = 77.17% and 81.19%). When HRT decreased to 4 h, the removal efficiencies of COD and TN was 86.93% and 70.49% respectively, which still met the strict IMO discharge standards. This mainly because the biofilm-assistant membrane filtration lead to the increase of physical removal rate. The high ratio of mixed liquor volatile suspended solids (MLVSS)/mixed liquid suspended solids (MLSS) (i.e. 0.75) indicated a high biomass content in the attached sludge and resulted into perfect pollutants removal effort. The compliance rate of COD and TN was 100% and 89%, respectively, which indicated stable operation of the pilot-scale AMCMBR throughout the whole experiment. Fluorescence in situ Hybridization (FISH) analysis revealed that the abundance of ß-Proteobacteria was a key microbial reason for TN removal. In addition, wavelet neural network (WNN) model was proved to be suitable to simulate and predict the COD and TN removal. These conclusions indicated that the pilot-scale AMCMBR technology is an effective way for real ship sewage treatment.

Conceptual Design of Composite Sandwich Structure Submarine Radome.

Radomes are usually constructed from sandwich structures made of materials which usually have a low dielectric constant so that they do not interfere with electromagnetic waves. Performance of the antenna is increased by the appropriate assortment of materials enabling it to survive under marine applications, and it depends on composite strength-to-weight ratio, stiffness, and resistance to corrosion. The design of a sandwich core submarine radome greatly depends on the material system, number of layers, orientation angles, and thickness of the core material. In this paper, a conceptual design study for a sandwich core submarine radome is carried out with the help of finite element analysis (FEA) using two unidirectional composite materials-glass fiber reinforced polymer (GFRP) and carbon fiber reinforced polymer (CFRP)-as a skin material and six different core materials. Conceptual designs are obtained based on constraints on the composite materials' failure, buckling, and strength. The thickness of the core is reduced under constraints on material and buckling strength. Finite element analysis software ANSYS WORKBENCH is used to carry out all the simulations.