Yield stress analysis of cellulose nanocrystals (CNCs) in hyaluronic acid suspensions.

Due to their biodegradability features, cellulose nanocrystals (CNCs) and hyaluronic acid (HA) have been simultaneously used in the matrix of hydrogels for biomedical applications, such as corneal transplantation, and skin regeneration. Although rheology of these hydrogels may provide useful information for their applications, little to no attention has been paid to rheological characterization. In this study, we analyzed the rheology of HA-CNC suspensions and more specifically their yielding behavior. Through different rheological experiments, known as stress ramp, shear rate ramp and amplitude sweep; it was observed that HA-CNC gels possessed two yield points. Reproducible magnitudes of yield stress were obtained by optimizing the experimental conditions. The rheo-optics characterizations confirmed that the first and second yield points could be attributed to the bond and cage breakage phenomena. Studying the effect of concentration, the second yield stress increased linearly by CNC concentration, whereas the first yield point manifested a power-law dependence on concentration (exponent of 0.5). This power-law relationship was further justified by the evolution of average distance between the CNC individual particles (d), calculated through SAXS analysis.

Effect of ultrasonic treatment on yield stress of highly concentrated cellulose nano-crystalline (CNC) aqueous suspensions.

The yield stress of highly concentrated cellulose nano-crystalline (CNC) suspensions is an important rheological property for different applications. The ultrasonic treatment is a common technique for dispersing CNCs in aqueous media. Although the effect of ultrasonic processing on rheology of CNC suspensions has been previously investigated, a systematic approach studying the sonication effect on yield stress is missing in the literature. In this study, we investigated the effect of sonication energy within the energy level of 0-5000 J/gCNC on static, dynamic and true yield points of a highly concentrated (8 wt%) aqueous CNC suspension, through a rheo-optics analysis. To better understand the yielding behaviour, the sonication effect on physicochemical properties of the CNCs was also investigated. The results revealed that yield stress decreases with sonication energy through a four-step mechanism governed by the microstructural transformations of the CNC agglomerates.

Effect of ultrasonication on lubrication performance of cellulose nano-crystalline (CNC) suspensions as green lubricants.

Industrial lubricants are widely introduced to the mechanical systems to reduce the wear and energy losses. With the increasing demand for environmental protection, developing eco-friendly lubricants becomes more crucial. Due to their abundance, biodegradability, non-toxicity, high thermal stability and low cost, cellulose nanocrystals (CNCs) may be an appropriate choice for formulating green lubricants. In this study, using different microstructural and tribological characterization methods, we systematically investigated the effect of ultrasonic treatment on lubrication performance of CNC aqueous suspensions. It was observed that within sonication energy of 4-50 kJ/gCNC, there exists an optimum condition for tribological measurements. In comparison to the unsonicated suspensions, sonicated CNC lubricants could decrease COF (coefficient of friction) and wear by almost 25 and 30% respectively. Results of this study suggest that ultrasonication processing can significantly improve lubrication performance of CNC aqueous suspensions.

Benchmarking Cellulose Nanocrystals Part II: New Industrially Produced Materials.

The demand for industrially produced cellulose nanocrystals (CNCs) has been growing since 2012, when CelluForce Inc. opened its inaugural demonstration plant with a production capacity of 1 tonne per day. Currently, there are 10 industrial CNC producers worldwide, each producing a unique material. Thus, academic researchers and commercial users alike must consider the properties of all available CNCs and carefully select the material which will optimize the performance of their desired application. To support these efforts, this article presents a thorough characterization of four new industrially produced CNCs including sulfated CNCs from NORAM Engineering and Constructors Ltd. (in cooperation with InnoTech Alberta and Alberta-Pacific Forest Industries Inc.) and Melodea Ltd., as well as carboxylated CNCs from Anomera Inc. and Blue Goose Biorefineries Inc. These materials were benchmarked against typical lab-made, sulfated CNCs. While all CNCs were similar in size, shape, crystallinity, and suspension quality, the sulfated CNCs had a higher surface charge density than their carboxylated counterparts, leading to higher colloidal stability. Additionally, significant differences in the rheological profiles of aqueous CNC suspensions, as well as CNC thermal stability and self-assembly behavior, were observed. As such, this article highlights both the subtle and significant differences between five CNC types and acts as a guide for end-users looking to optimize the performance of CNC-based materials.