Recent advances in application of metal-organic frameworks (MOFs) as adsorbent and catalyst in removal of persistent organic pollutants (POPs).

The presence of persistent organic pollutants (POPs) in the aquatic environment is causing widespread concern due to their bioaccumulation, toxicity, and possible environmental risk. These contaminants are produced daily in large quantities and released into water bodies. Traditional wastewater treatment plants are ineffective at degrading these pollutants. As a result, the development of long-term and effective POP removal techniques is critical. In water, adsorption removal and photocatalytic degradation of POPs have been identified as energy and cost-efficient solutions. Both technologies have received a lot of attention for their efforts to treat the world's wastewater. Photocatalytic removal of POPs is a promising, effective, and long-lasting method, while adsorption removal of persistent POPs represents a simple, practical method, particularly in decentralized systems and isolated areas. It is critical to develop new adsorbents/photocatalysts with the desired structure, tunable chemistry, and maximum adsorption sites for highly efficient removal of POPs. As a class of recently created multifunctional porous materials, Metal-organic frameworks (MOFs) offer tremendous prospects in adsorptive removal and photocatalytic degradation of POPs for water remediation. This review defines POPs and discusses current research on adsorptive and photocatalytic POP removal using emerging MOFs for each type of POPs.

Nitrate in groundwater and agricultural products: intake and risk assessment in northeastern Iran.

The suitability of groundwater and agricultural products for human consumption requires determining levels and assessing the health risks associated with potential pollutants. Here, particularly pollution with nitrate still remains a challenge, especially for those urban areas suffering from insufficient sewage collection systems, resulting in contaminating soil, endangering food safety, and deteriorating drinking water quality. In the present study, nitrate concentrations in the commonly consumed fruit and vegetable species were determined, and the results, together with the groundwater nitrate levels, were used to assess the associated health risks for Mashhad city residents. For this assessment, 261 water samples and 16 produce types were used to compute the daily intake of nitrate. Nitrate in groundwater was analyzed using a spectrophotometer, and produce species were examined using High-Performance Liquid Chromatography. Ward's hierarchical cluster analysis was applied for categorizing produce samples with regard to their nitrate content. Additionally, to account for the sanitation hazards associated with groundwater quality for drinking purposes, total coliform and turbidity were also assessed using the membrane filter (MF) technique and a nephelometer, respectively. Nitrate concentrations exceeded the prescribed permissible limits in 42% of the groundwater wells. The outcomes also exhibit significantly higher nitrate accumulation levels in root-tuber vegetables and leafy vegetables compared to fruit vegetables and fruits. Using cluster analysis, the accumulation of nitrate in vegetables and fruits was categorized into four clusters, specifying that radish contributes to 65.8% of the total content of nitrate in all samples. The Estimated Daily Intake (EDI) of nitrate and Health Risk Index (HRI) associated with consumption of groundwater exceeded the prescribed limit for the children's target group in Mashhad's south and central parts. Likewise, EDI and HRI values for produce consumption, in most samples, were found to be in the tolerable range, except for radish, lettuce, and cabbage, potentially posing risks for both children and adult consumers. The total coliforms in groundwater were found to violate the prescribed limit at 78.93% of the sampling locations and were generally much higher over the city's central and southern areas. A relatively strong correlation (R2 = 0.6307) between total coliform and nitrate concentrations suggests the release of anthropogenic pollution (i.e., sewage and manure) in the central and southern Mashhad.

Small Hematite Nanoparticles from the Kiruna-Type Ore; Evaluation of Declined Balance Limit of the Attrition Process and Their Catalytic Properties.

Hematite nanoparticles possess unique properties which have motivated substantial attention for numerous applications, including environmental remediation and wastewater treatment as a promising novel technology. The magnetite-silicate raw material of Kiruna-type ore has been introduced as an innovative precursor, decreasing the attrition balance limit for large-scale production of the ball-mill-derived hematite nanoparticles below the critical size. In this study, the hypothesis and the postulated role of quartz in the effective size reduction process were further investigated. The prepared samples were characterized in detail via X-ray fluorescence (XRF) and powder X-ray diffractometry (pXRD) to be compared with the previous results. Furthermore, the catalytic and photocatalytic activities of the obtained nanoparticles were evaluated in the oxidation reaction of a common persistent sulfo-organic contaminant. The results exposed outstanding reactivity, particularly in their photocatalytic performance, suggesting them as a strong oxidizing agent and active photocatalyst, which greatly promises many possible applications including water and environmental remediation.