Hydrophobic Polymeric Additives toward a Long-Term Robust Carbonaceous Mudstone Slope.

Slopes with carbonaceous mudstone (CM) are widely distributed in the southwest of China and have experienced numerous geological disasters in special climate, especially in rainfall conditions. Therefore, novel materials to stabilize CM slopes have attracted increasing interests. However, developing ultra-stable and cost-effective additives for CM slopes is still a great challenge. Herein, a hydrophobic polymeric material (polyvinylidene fluoride, PVDF) is investigated as an additive to enhance the mechanical strength and long-time stability of CM slopes. The PVDF is uniformly dispersed in CM matrix via interfacial interaction. The contact angle of the PVDF-modified carbonaceous mudstone (PVDF-MCM) can reach as high as 103.95°, indicating an excellent hydrophobicity. The unconfined compressive strength (UCS) and tensile strength (TS) of PVDF-MCM have been intensively enhanced to 4.07 MPa and 1.96 MPa, respectively, compared with ~0 MPa of pristine CM. Moreover, the UCS and TS of PVDF-MCM remain at 3.24 MPa and 1.03 MPa even after curing for 28 days in high humidity conditions. Our findings show that the PVDF can improve the hydrophobicity of CM significantly, which leads to super mechanical stability of PVDF-MCM. The excellent performance makes PVDF a promising additive for the development of ultra-stable, long-lifetime and cost-effective carbonaceous mudstone slopes.

Study of the Strength of Disintegrated Carbonaceous Mudstone Modified with Nano-Al2O3 and Cement.

Embankments filled with disintegrated carbonaceous mudstone (DCM) are prone to uneven settlements because of water-softening property and secondary disintegration of carbonaceous mudstone. To address this problem, nano-Al²O³ and cement were proposed in this study to improve the strength of DCM. Many nano-Al²O³- and cement-modified DCM (NACDCM) specimens with various nano-Al²O³ contents were prepared. Unconfined compression tests and triaxial compression tests were performed to examine the strengths of NACDCM under different conditions. Moreover, X-ray diffraction (XRD) analyses and scanning electron microscopy (SEM) observations were performed to reveal the microscopic mechanism for modification of the NACDCM. Macroscopic results showed that the unconfined compressive strength of NACDCM reached maximum when the nano-Al²O³ content was 0.2%. The cohesion showed positive correlation with nano-Al²O³ content while the angle of internal friction presented negative correlation with nano-Al²O³ content. Moreover, microscopic results indicated that nano-Al²O³ and cement improved the strength of NACDCM, mainly through cement hydration reaction, pozzolanic reaction, ion exchange, gel effect and filling effect.