A nimble strategy for enabling bioderived flame retardants with strikingly enhanced interfacial compatibility in poly (lactic acid) composites.

The utilization of bioderived flame retardants in biodegradable poly (lactic acid) (PLA) has profound practical implications for extending the widespread application of PLA composites and protecting the environment. Nevertheless, there are still certain challenges that require prompt attention, especially the ineffectiveness of bio-based flame retardants and their deterioration of the mechanical properties of PLA. This work introduced triglycidyl isocyanurate (TGIC), which has multiple epoxy functions, into the self-assembly process of phytic acid (PA) and chitosan (CS). The epoxy-modified bioderived flame retardant PA@CS-TGIC (PCT) was well dispersed in the PLA matrix and had a strong interfacial adhesion, while also TGIC had a synergistic char-forming effect. By compounding epoxy-modified ammonium polyphosphate (MAPP), 3%PCT/MAPP-PLA composites may reach a LOI value of 28.8 % and UL-94 V-0 rating. Simultaneously, the melting droplets had been considerably reduced. Tensile strength of the 3%PCT/MAPP-PLA composites was 67.0 MPa, 10.8 % higher than that of pure PLA. This work paves a new avenue for the development of PLA composites with robust mechanical and flame retardant properties.

Formation and prediction of heterocyclic amines and N-nitrosamines in smoked sausages using back propagation artificial neural network.

BACKGROUND: Heterocyclic amines (HAs) and N-nitrosamines (NAs) are formed easily during the thermal processing of food, and epidemiological studies have demonstrated that consuming HAs and NAs increases the risk of cancer. However, there are few studies on the application of back propagation artificial neural network (BP-ANN) models to simultaneously predict the content of HAs and NAs in sausages. This study aimed to investigate the effects of cooking time and temperature, smoking time and temperature, and fat-to-lean ratio on the formation of HAs and NAs in smoked sausages, and to predict their total content based on the BP-ANN model. RESULTS: With an increase in processing time, processing temperature and fat ratio, the content of HAs and NAs in smoked sausages increased significantly, while the content of HA precursors and nitrite residues decreased significantly. The optimal network topology of the BP-ANN model was 5-11-2, the correlation coefficient values for training, validation, testing and all datasets were 0.99228, 0.99785, 0.99520 and 0.99369, respectively, and the mean squared error value of the best validation performance was 0.11326. The bias factor and the accuracy factor were within acceptable limits, and the predicted values approximated the true values, indicating that the model has good predictive performance. CONCLUSION: The contents of HAs and NAs in smoked sausages were significantly influenced by the cooking conditions, smoking conditions and fat ratio. The BP-ANN model has high application value in predicting the contents of HAs and NAs in sausages, which provides a theoretical basis for the suppression of carcinogen formation. © 2024 Society of Chemical Industry.

Preparation of Biochar Composite Microspheres and Their Ability for Removal with Oil Agents in Dyed Wastewater.

Oil agents produced from the degreasing treatment of synthetic fibers are typical pollutants in wastewater from printing and dyeing, which may cause large-scale environmental pollution without proper treatment. Purifying oily dye wastewater (DTY) at a low cost is a key problem at present. In this study, biochar microspheres with oil removal ability were prepared and derived from waste bamboo chips using the hydrothermal method. The structure of the biochar microsphere was regulated by activation and modification processes. Biochar microspheres were characterized, and their adsorption behaviors for oily dye wastewater were explored. The results show that the adsorption efficiency of biochar microspheres for oily dye wastewater (DTY) was improved significantly after secondary pyrolysis and the lauric acid grafting reaction. The maximum COD removal quantity of biochar microspheres for DTY was 889 mg/g with a removal rate of 86.06% in 30 min. In addition, the kinetics showed that chemisorption was the main adsorption manner. Considering the low cost of raw materials, the application of biochar microspheres could decrease the cost of oily wastewater treatment and avoid environmental pollution.

Large-Scale Fabrication of Tunable Sandwich-Structured Silver Nanowires and Aramid Nanofiber Films for Exceptional Electromagnetic Interference (EMI) Shielding.

The recent advancements in communication technology have facilitated the widespread deployment of electronic communication equipment globally, resulting in the pervasive presence of electromagnetic pollution. Consequently, there is an urgent necessity to develop a thin, lightweight, efficient, and durable electromagnetic interference (EMI) shielding material capable of withstanding severe environmental conditions. In this paper, we propose an innovative and scalable method for preparing EMI shielding films with a tunable sandwich structure. The film possesses a nylon mesh (NM) backbone, with AgNWs serving as the shielding coating and aramid nanofibers (ANFs) acting as the cladding layer. The prepared film was thin and flexible, with a thickness of only 0.13 mm. AgNWs can easily form a conductive network structure, and when the minimum addition amount was 0.2 mg/cm2, the EMI SE value reached 28.7 dB, effectively shielding 99.884% of electromagnetic waves and thereby meeting the commercial shielding requirement of 20 dB. With an increase in dosage up to 1.0 mg/cm2, the EMI SE value further improved to reach 50.6 dB. The NAAANF film demonstrated remarkable robustness in the face of complex usage environments as a result of the outstanding thermal, acid, and alkali resistance properties of aramid fibers. Such a thin, efficient, and environmentally resistant EMI shielding film provided new ideas for the broad EMI shielding market.

Cost-effective resource utilization for waste biomass: A simple preparation method of photo-thermal biochar cakes (BCs) toward dye wastewater treatment with solar energy.

Waste biomass and dye wastewater pollution have been the serious environmental problems. The interfacial solar-steam generation technology is an effective and sustainable method for the water purification. However, the complex preparation process, high economic cost and probably secondary environmental pollution of traditional photo-thermal materials restricted their practical large-scale application. Herein, the biochar cakes (BCs) deriving from waste biomass were prepared, and the granular and schistose MgO coatings were dressed on the surface of carbonized fiber to improve their hydrophilicity. The BCs with high solar absorbance and super-hydrophilicity were applied in the photo-thermal purification of dye wastewater with solar energy. The highest evaporation rate of dye wastewater with BCs reached 2.27 kg m-2 h-1, and the corresponding conversion efficiency of solar to steam generation was 78.98% under the simulated solar irradiation (1846.0 w/m2). The collected clean water from the solar-steam evaporators reached the emission standards of EU Water Framework Directive (91/271/EEC). Considering the simple and economical preparation method, this process made the practical large-scale application of photo-thermal BCs on dye wastewater treatment a reality, and also provided a cost-effective management strategy for the waste biomass.

Dual resource utilization for tannery sludge: Effects of sludge biochars (BCs) on volatile fatty acids (VFAs) production from sludge anaerobic digestion.

Resource utilization of organic matters in tannery sludge has drawn great attention. In this paper, the influences of sludge biochars (BCs) on volatile fatty acids (VFAs) production from the anaerobic digestion of sludge supernatant (SST) were investigated. Experimental results demonstrated that the VFAs yields improved in the presence of BCs with rich functional groups. The maximum yield of VFAs was 1037.5 mg/g SCOD with the addition of BC-1 biochar (zeta potential -50.42 mV). BCs decreased ammonia nitrogen concentration, thus reducing inhibition for bacteria during the anaerobic digestion. Microbial community analysis indicated that the BCs affected microbial community structures and contributed to a favorable environment for bacteria. Especially, the BC-1 biochar with rich functional groups enhanced the relative abundance of acid-forming bacteria (Clostridiales). A dual strategy was proposed to improve the resource utilization efficiency for tannery sludge.

Roles of hydrothermal-alkaline treatment in tannery sludge reduction: rheological properties and sludge reduction mechanism analysis.

The hydrothermal-alkaline treatment (HAT) is an efficient sludge reduction method. However, the roles of HAT in tannery sludge reduction are not very clear. In this study, the sludge reduction mechanism of HAT was explored. The results showed that HAT had good performance for the organic dissolution of tannery sludge. The reduction of the sludge mass was calculated by the mass of the separated wet sludge solid (4000 rpm, 10 min) before and after HAT. The HAT parameters for sludge reduction (SR) were optimized by the Box-Behnken, and the sludge reduction was 62.5% under optimal conditions (198 °C, 87 min and 8.7 g L-1 NaOH). The soluble organics, especially a polysaccharide (PS) and ammonia nitrogen (NH3-N), showed a close correspondence with the SR ratio. The rheological properties of the sludge indicated that the reticular structures in the sludge were destroyed after HAT. The tannery sludge solid became more pyknotic than raw sludge after the hydrothermal-alkaline treatment. The tannery sludge reduction can be attributed to the damage of reticular structures, organic dissolution and release of bound water.

Fabry-Pérot cavity-coupled microbolometer terahertz detector with a continuously tunable air spacer gap.

This Letter demonstrates tunable Nb5N6 microbolometers operating in the terahertz frequency range. An asymmetric-coupled Fabry-Pérot cavity is constituted by simply placing a movable metallic planar mirror in the back of the silicon substrate. The incident THz radiation onto the Nb5N6 microbolometer is effectively manipulated by changing the air spacer gap to modulate the phase relation between the reflected wave and incident wave. The experimental measurements reveal that the detailed evolution of the resonance bands as a function of spacing is in excellent agreement with the analysis by using interference theory and simulation. The results detail the design of THz detectors wherein a wide degree of tunability or a variable number of detection bands is desirable.

Reflective grating-coupled structure improves the detection efficiency of THz array detectors.

A reflective grating-coupled structure on the silicon substrate was designed to improve the detection efficiency of terahertz detectors for the frequency ranging from 0.26 THz to 0.36 THz. By using finite difference time domain (FDTD) solutions, the simulation and optimized design of the grating-coupled structure were carried out. The results showed that the signal was effectively reflected and diffracted by the reflective grating-coupled structure which significantly enhanced the electric field in the place of the detector. The maximum electric field can be increased by 2.8 times than that of the Fabry-Perot resonator. To verify the design results, the reflective grating-coupled structure was applied in the preparation of the Nb5N6 array detector chip and compared with the Nb5N6 array detector chip with the F-P resonator. The results showed that the maximum voltage responsivity of the Nb5N6 detector with the reflective grating-coupled structure was 2 times larger than the Nb5N6 detector with the F-P resonator. It indicates that the reflective grating-coupled structure can efficiently improve the detection efficiency of THz detectors.

Investigation of antenna-coupled Nb5N6 microbolometer THz detector with substrate resonant cavity.

Fabricating resonant cavities with conventional methods to improve the coupling efficiency of a detector in the terahertz (THz) region is difficult for the wavelength is too long. Here, we propose a solution by using the substrate cavity effect given that the substrate wavelength and thickness of the preparation device are in the same order. The planar dipole antenna-coupled Nb5N6 microbolometers with different substrate thicknesses were fabricated. The interference effect of the substrate cavity on the optical voltage response of the detector is analyzed experimentally and theoretically. The experimental results show that the optical response of the detector is determined by the length of the substrate cavity. Thus, the THz devices with different detection frequencies can be designed by changing the substrate cavity length. Furthermore, on the basis of this substrate cavity effect, an asymmetric coupled Fabry-Pérot (FP) cavity is constituted by simply placing a movable metallic planar mirror at the backside of the Si substrate. The incident THz radiation on the Nb5N6 microbolometer can be effectively manipulated by changing the substrate-mirror distance to modulate the phase relation between the reflect wave and the incident wave. The distinct radiation control can be observed, and the experiments can be well explained by numerically analyzing the responsivity dynamics that highlights the role of the FP cavity effect during radiation. All of the results discussed here can be extended to a broad range of frequency and other type of THz detectors.

Effects of sludge thermal-alkaline pretreatment on cationic red X-GRL adsorption onto pyrolysis biochar of sewage sludge.

Thermal-alkaline pretreatment has traditionally been used to enhance anaerobic sludge digestion. In this study, after removing the supernatant, which could be used in anaerobic digestion, the Residual Solids of Thermal-Alkaline pretreated sewage Sludge (RSTAS) were used to prepare biochar via pyrolysis, which could then adsorb Cationic Red X-GRL(X-GRL). The experimental results showed that the RSTAS-biochar had a higher BET surface area and total pore volume than the biochar prepared from raw sludge (RS) (43.5% and 33.3%, respectively). The pretreatment enhanced the X-GRL adsorption capacity of the biochar by 1.5-49.2% at dosages between 12.5-100.0g/g, and the highest adsorption capacity increased from 39.1mg/g to 47.6mg/g. The biochar from RSTAS had a wider application pH range for X-GRL adsorption. The kinetics and isotherms for X-GRL adsorption onto the two biochars were well fitted to the pseudo-second-order and Langmuir isotherm models, respectively, which suggested that thermal-alkaline pretreatment had little effect on the adsorption mechanisms of X-GRL onto biochar.