RESUMO
We report the first example of B(C6F5)3-catalyzed O-H insertion reaction of sulfoxonium ylides and carboxylic acids, achieving efficient construction of diester moieties under metal-free condition. This protocol is characterized by broad substrate tolerance, particularly for various phenylacetic acids, and good compatibility with water/air condition, which is superior to most other methods.
RESUMO
A novel Rh-catalyzed cascade reaction of pyridotriazoles with iodonium ylides is reported. This one-pot procedure involves a triazole-directed ortho-position C-H carbene insertion, followed by intramolecular denitrogenation annulation. It was noteworthy that this reaction provided straightforward access to 1H-isochromene frameworks with excellent yields (up to 94% yield).
Assuntos
TriazóisRESUMO
Rhizoctonia cerealis is a worldwide soil-borne pathogenic fungus that significantly infects wheat and causes sharp eyespot in China. However, the biocontrol strains used for the control of Rhizoctonia cerealis are insufficient. In the present study, antagonistic strain B1302 from the rhizosphere of wheat were isolated and identified as Bacillus mojovensis based on their morphological, physiological, and biochemical characteristics, and their 16S rDNA sequence. Culture filtrate of strain B1302 had a broad antifungal spectrum. In order to improve the antifungal activity of B1302, response surface methodology (RSM) was used to optimize the culture conditions. The final medium composition and culture conditions were 13.2 g/L of wheat bran, 14.1 g/L of soybean meal, 224 r/min of rotation speed, 7.50 of initial pH, and 1.5 × 108 CFU/mL of inoculation amount at 35 °C for a culture duration of 72 h. B. mojavensis B1302 inhibited the hyphae growth of R.cerealis and produced hydrolytic enzymes (protease, chitinase, and glucanase), IAA, and had N-fixing potentiality and P-solubilisation capacity. It can also promote wheat seedling growth in potted plants. The disease incidence and index of wheat seedlings were consistent with the effect of commercial pesticides under treatment with culture filtrate. The biocontrol efficacy of culture filtrate was significant-up to 65.25%. An animal toxicological safety analysis suggested that culture filtrate was safe for use and could be developed into an effective microbial fungicide to control wheat sharp eyespot.
RESUMO
The Experiences in Close Relationships-Relationship Structures (ECR-RS) scale is designed to capture attachment among diverse relational contexts (e.g., parents, friends). Although the ECR-RS has begun to be applied to children and adolescents, its psychometric properties among children and adolescents are not well-known, especially concerning second-order structural validity, measurement invariance, and longitudinal predictive validity. To fill this gap, the current research examined the ECR-RS among 3,184 Chinese students (9- to 18-year old) using cross-sectional and longitudinal (6 months) data. The results demonstrated generally acceptable composite and test-retest reliabilities, and acceptable second-order structural validity. In addition, the measurement invariance of the ECR-RS held across time, relational contexts, and school levels to varying degrees. Furthermore, using a partial invariance model, we depicted the cross-sectional trajectory of attachment scores across relational contexts and school levels. Finally, attachment was associated concurrently with the Big-Five personality traits in theoretically meaningful ways and longitudinally predicted depression, anxiety, stress, and self-esteem after controlling for age, gender, and pretest scores. In conclusion, the Chinese ECR-RS has proven to be a valuable instrument for future research among children and adolescents.
