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1.
Entropy (Basel) ; 24(1)2021 Dec 24.
Artigo em Inglês | MEDLINE | ID: mdl-35052056

RESUMO

This paper aims to estimate an unknown density of the data with measurement errors as a linear combination of functions from a dictionary. The main novelty is the proposal and investigation of the corrected sparse density estimator (CSDE). Inspired by the penalization approach, we propose the weighted Elastic-net penalized minimal ℓ2-distance method for sparse coefficients estimation, where the adaptive weights come from sharp concentration inequalities. The first-order conditions holding a high probability obtain the optimal weighted tuning parameters. Under local coherence or minimal eigenvalue assumptions, non-asymptotic oracle inequalities are derived. These theoretical results are transposed to obtain the support recovery with a high probability. Some numerical experiments for discrete and continuous distributions confirm the significant improvement obtained by our procedure when compared with other conventional approaches. Finally, the application is performed in a meteorology dataset. It shows that our method has potency and superiority in detecting multi-mode density shapes compared with other conventional approaches.

2.
Nanomicro Lett ; 12(1): 112, 2020 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-34138112

RESUMO

The lithium-sulfur battery is the subject of much recent attention due to the high theoretical energy density, but practical applications are challenged by fast decay owing to polysulfide shuttle and electrode architecture degradation. A comprehensive study of the sulfur host microstructure design and the cell architecture construction based on the MXene phase (Ti3C2Tx nanosheets) is performed, aiming at realize stable cycling performance of Li-S battery with high sulfur areal loading. The interwoven KB@Ti3C2Tx composite formed by self-assembly of MXene and Ktejen black, not only provides superior conductivity and maintains the electrode integrality bearing the volume expansion/shrinkage when used as the sulfur host, but also functions as an interlayer on separator to further retard the polysulfide cross-diffusion that possibly escaped from the cathode. The KB@Ti3C2Tx interlayer is only 0.28 mg cm-2 in areal loading and 3 µm in thickness, which accounts a little contribution to the thick sulfur electrode; thus, the impacts on the energy density is minimal. By coupling the robust KB@Ti3C2Tx cathode and the effective KB@Ti3C2Tx modified separator, a stable Li-S battery with high sulfur areal loading (5.6 mg cm-2) and high areal capacity (6.4 mAh cm-2) at relatively lean electrolyte is achieved.

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