Morphology-dependent photoresponsive behaviors of a self-assembled system based on a single cyanostilbene derivative.

In recent years, photoresponsive supramolecular self-assemblies have shown great potential in various fields. However, it is still a great challenge to integrate and control multiple photoresponsive behaviors in a self-assembled system. Herein, we design a novel cyanostilbene-based molecule VOE. In the aggregated state, it has different photoresponsive behaviors under different morphologies. When VOE molecules are dispersed in a 70% H2O/THF mixture, two different assembly morphologies are obtained as the aging time changes. One is weakly emissive nanoparticles with amorphous packing arrangements, and the other is highly emissive microbelts with well-ordered stacking modes. When they are irradiated with blue light (420 nm), the disordered assembly structure of nanoparticles leads to a [2+2] cycloaddition reaction, while a Z/E isomerization reaction occurs in ordered packed microbelts. Therefore, we can use a self-assembled system to generate two different morphologies, enabling completely different emissions and photoresponsive behaviors.

White-light-emitting hydrogels with self-healing properties and adjustable emission colors.

White-light-emitting soft materials with self-healing properties show extensive applications in many fields. Herein, a novel self-healing hydrogel is successfully fabricated using oxidized dextran (Odex) and dithiodipropionate dihydrazide (TPH). Carbon dots (CDs), Riboflavin (Ri) and Rhodamine B (RhB) are incorporated into the gel matrix to produce white light emission through fluorescence resonance energy transfer (FRET) process, thus achieving excellent Commission Internationale de L'eclairage (CIE) coordinate value of (0.30, 0.33). The emission colors can be easily tuned via changing proportions of three emitters or the excitation wavelength. When the hydrogels are coated on an ultraviolet light-emitting diodes (UV LED), the hydrogel coating converts UV light to white light and repairs itself in 20 h while a hole is dug from it. Thanks to reversible exchanging reactions of acylhydrazone and disulfide bonds in hydrogel networks, the hydrogel coating exhibits perfect self-healing property in a wide range of pH (from 5 to 9 except for 7). The excellent emission and self-healing properties of hydrogels have great value in practical applications.