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1.
Zookeys ; 1095: 43-74, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35836687

RESUMO

A list of 34 thomisid species belonging to 21 genera collected in Jangxi Province of China is provided. Five new species are described: Angaeusxieluae Liu, sp. nov. (♂♀), Lysitelessubspirellus Liu, sp. nov. (♀), Oxytatemucunica Liu, sp. nov. (♀), Phartalingxiufengica Liu, sp. nov. (♀), Stephanopisxiangzhouica Liu, sp. nov. (♀). A new combination is proposed: Ebelingiaforcipata (Song & Zhu, 1993) comb. nov. (ex. Ebrechtella Dahl, 1907). Previously unknown females of E.forcipata (Song & Zhu, 1993), Oxytatebicornis Liu, Liu & Xu, 2017, and Xysticuslesserti Schenkel, 1963 are described for the first time. Stephanopis O Pickard-Cambridge, 1869, a genus previously known from Australasia and South America, is recorded from the Asian mainland for the first time.

2.
Chemosphere ; 302: 134928, 2022 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-35561760

RESUMO

Polyaniline (PANI) is a useful conductive polymer material, and has good adsorption property, which makes it a good modification material. In this work, for the sake of highly enhancing the utilization of visible region in sunlight and accelerating photocatalytic degradation of tetrabromobisphenol A (TBBPA), a typical polybrominated flame retardant, titanium dioxide nanotube arrays (TiO2 NTAs) were modified with PANI by chemical and electrochemical polymerization. The coated amount of PANI was controlled via adjusting the polymerization time and the amount of aniline in the electrochemical method. The results demonstrate that the EC-PANI/TiO2 NTAs (synthesized electrochemically) exhibit higher catalytic activity than bare TiO2 NTAs and C-PANI/TiO2 NTAs (synthesized chemically) in photoelectrocatalytic degradation of TBBPA under visible light, and the degradation efficiency for TBBPA could reach 94.37% within 120 min. The improved performance was contributed to the synergetic effect of PANI modification which integrated the broad absorption of PANI in visible light region and high catalytic property of TiO2 NTAs. Interestingly, it was also found that the degradation efficiency of TBBPA by EC-PANI/TiO2 was further enhanced by up to 95.74% when the ethanol was present in the reaction system as the hole scavenger. Furthermore, the EC-PANI/TiO2 exhibited excellent stability after 10 cycling experiments. All the results indicated that this new modified material presented strong potential as a photoelectrocatalyst and had great practical applications in the future.

3.
Zookeys ; 1056: 1-15, 2021.
Artigo em Inglês | MEDLINE | ID: mdl-34466054

RESUMO

The male of Psechrusjinggangensis Wang & Yin, 2001 is described for the first time based on many specimens from its type locality, Jinggang Mountain National Nature Reserve, Ji'an City, Jiangxi province, China. Detailed illustrations, SEM images, and distribution map are given.

4.
Chemosphere ; 252: 126468, 2020 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-32197178

RESUMO

An ordered g-C3N4- and polyaniline-modified titanium oxide nanotube array (g-C3N4- and PANI-co-modified TiO2 NTAs) was successfully synthesized and used as a photocatalyst. Polyaniline (PANI) was coated onto TiO2 NTAs by electrochemical polycondensation, and g-C3N4 was deposited via the soaking adsorption method. The photocatalysts were examined by several technologies. The experiments demonstrated that the amount of g-C3N4 and PANI, as well as the initial pH value, had significant effects on the photocatalytic efficiency. The resulting photocatalysts exhibited high visible light photocatalytic ability for tetrabromobisphenol A (TBBPA) for two reasons. First, PANI expanded the light absorption into the visible region. Second, rapid and efficient separation of photoinduced charges from the photogenerated potential difference were produced at the contact interface of g-C3N4 and PANI-co-modified TiO2 NTAs. The •OH, [Formula: see text] and h+ were dominant components for the photocatalytic degradation of TBBPA. In addition, the g-C3N4 and PANI-co-modified TiO2 NTAs have excellent long-term stability.


Assuntos
Nanotubos/química , Bifenil Polibromatos/química , Titânio/química , Adsorção , Compostos de Anilina , Catálise , Luz , Processos Fotoquímicos
5.
Sensors (Basel) ; 19(7)2019 Apr 08.
Artigo em Inglês | MEDLINE | ID: mdl-30965611

RESUMO

Driving behavior is the main basis for evaluating the performance of an unmanned vehicle. In simulation tests of unmanned vehicles, in order for simulation results to be approximated to the actual results as much as possible, model of driving behaviors must be able to exhibit actual motion of unmanned vehicles. We propose an automatic approach of simulating dynamic driving behaviors of vehicles in traffic scene represented by image sequences. The spatial topological attributes and appearance attributes of virtual vehicles are computed separately according to the constraint of geometric consistency of sparse 3D space organized by image sequence. To achieve this goal, we need to solve three main problems: Registration of vehicle in a 3D space of road environment, vehicle's image observed from corresponding viewpoint in the road scene, and consistency of the vehicle and the road environment. After the proposed method was embedded in a scene browser, a typical traffic scene including the intersections was chosen for a virtual vehicle to execute the driving tasks of lane change, overtaking, slowing down and stop, right turn, and U-turn. The experimental results show that different driving behaviors of vehicles in typical traffic scene can be exhibited smoothly and realistically. Our method can also be used for generating simulation data of traffic scenes that are difficult to collect.

6.
Nanoscale Res Lett ; 14(1): 60, 2019 Feb 19.
Artigo em Inglês | MEDLINE | ID: mdl-30783795

RESUMO

In the present work, polyaniline and CeO2 co-decorated TiO2 nanotube arrays (PANI/CeO2/TiO2 NTAs) were facilely prepared by an electrochemical method. The as-prepared materials were characterized by scanning electron microscopy (SEM), an X-ray diffractometer (XRD), and energy-dispersive X-ray spectroscopy (EDS). The photoelectrocatalytic activity of as-prepared materials was investigated with tetrabromobisphenol A (TBBPA) as the target analyte, and the data showed that PANI/CeO2/TiO2 NTAs resulted in much higher photoelectrocatalytic efficiency than that of other materials. Under optimal conditions, the degradation rate of TBBPA reached a maximum value over 96% in 120 min under simulated solar irradiation. The results indicated that CeO2 and PANI co-modified TiO2 NTAs could narrow the band gap, expand the response from ultraviolet (UV) to visible region, increase the amount of active free radicals, inhibit the recombination rate of electron-hole pairs, and finally enhance the degradation efficiency towards TBBPA owing to the presence of Ce3+/Ce4+ and PANI. Moreover, the degradation reaction followed the first-order kinetics, and degradation rates of the repeated experiments were all over 92% for ten runs. All these results indicated that this novel catalyst earned great potential as a powerful photoelectrocatalyst for the removal of TBBPA and other pollutants.

7.
Sensors (Basel) ; 18(11)2018 Nov 05.
Artigo em Inglês | MEDLINE | ID: mdl-30400668

RESUMO

Road scene model construction is an important aspect of intelligent transportation system research. This paper proposes an intelligent framework that can automatically construct road scene models from image sequences. The road and foreground regions are detected at superpixel level via a new kind of random walk algorithm. The seeds for different regions are initialized by trapezoids that are propagated from adjacent frames using optical flow information. The superpixel level region detection is implemented by the random walk algorithm, which is then refined by a fast two-cycle level set method. After this, scene stages can be specified according to a graph model of traffic elements. These then form the basis of 3D road scene models. Each technical component of the framework was evaluated and the results confirmed the effectiveness of the proposed approach.

8.
Chemosphere ; 165: 268-276, 2016 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-27657819

RESUMO

Tetrabromobisphenol A, one of the most important brominated retardants, is an typical persistent organic pollutant and it is of great value to develop rapid and effective degradation method. Present study established a photoelectrodegradation method with CeO2 and reduced graphene oxide co-modified TiO2 nanotube arrays (RGO-CeO2-TiO2 NAs), which were successfully synthesized and characterized with scanning electron microscopy (SEM) and Energy Dispersive X Ray Spectrometry (EDX). The SEM Images revealed that the nanotubes had a diameter of about 100 nm and an obvious layer of CeO2 and RGO on the surface of TiO2 nanotube arrays. The EDX data exhibited the presence of Ce element. The results demonstrated that TBBPA was degraded at a high degradation rate constant of 0.0191 min-1, and photogenerated holes played a major role in the degradation reaction. Significant decrease of degradation efficiency was achieved with the presence of EDTA-2Na(hole scavenger), yet while the existence of t-BuOH(OH scavenger) resulted in less inhibition on the degradation. Besides, RGO-CeO2-TiO2 NAs exhibited good stability with rarely decline of degradation efficiency for ten reused runs. All these indicated that RGO-CeO2-TiO2 NAs were a good catalyst with extraordinary catalytic activity and stability for PEC degradation, and would have great potential in the control and removal of pollutants.


Assuntos
Cério/química , Poluentes Ambientais/análise , Grafite/química , Luz , Nanotubos/química , Bifenil Polibromatos/análise , Titânio/química , Catálise , Eletrodos , Poluentes Ambientais/química , Poluentes Ambientais/efeitos da radiação , Recuperação e Remediação Ambiental , Microscopia Eletrônica de Varredura , Modelos Teóricos , Óxidos/química , Processos Fotoquímicos , Bifenil Polibromatos/química , Bifenil Polibromatos/efeitos da radiação
9.
J Sep Sci ; 38(9): 1577-83, 2015 May.
Artigo em Inglês | MEDLINE | ID: mdl-25677605

RESUMO

Selenium is an important element for human health, and it is present in many natural drinks and foods. Present study described a new method using dispersive liquid-liquid microextraction prior to high-performance liquid chromatography with a UV variable wavelength detector for the determination of the total selenium, Se(IV), Se(VI), and total organoselenium in tea samples. In the procedure, 2,3-diaminonaphthalene was used as the chelating reagent, 400 µL acetonitrile was used as the disperser solvent and 60 µL chlorobenzene was used as the extraction solvent. The complex of Se(IV) and 2,3-diaminonaphthalene in the final extracted phase was analyzed by high-performance liquid chromatography. The factors influencing the derivatization and microextraction were investigated. Under the optimal conditions, the limit of detection was 0.11 µg/L for Se(IV) and the linearity range was in the range of 0.5-40 µg/L. This method was successfully applied to the determination of selenium in four tea samples with spiked recoveries ranging from 91.3 to 100%.


Assuntos
2-Naftilamina/análogos & derivados , Microextração em Fase Líquida , Compostos Organosselênicos/análise , Selênio/análise , Chá/química , 2-Naftilamina/química , Quelantes/química , Cromatografia Líquida de Alta Pressão
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