Coupled and collaborative optimization model of impervious surfaces and drainage systems from the flooding mitigation perspective for urban renewal.

Urban pluvial flooding mitigation is a significant challenge in city development. Many mature methods have been used to reduce the risk of flood. The optimal design of impervious surfaces (ODIS) is an adaptive solution to urban flooding from the perspective of urban renewal planning. However, existing ODIS models are limited because they do not consider the drainage systems. To address this issue, this study proposes an elastic and controllable optimization model based on assumptions about rainstorm and drainage capacity, nondominated sorting genetic algorithm-II (NSGA-II), multivariate linear programming (MLP) and soil conservation service curve number model (SCS-CN) in a case study of the old town of Guangzhou city, China. The model not only coupled the drainage systems, but also collaboratively optimized the impervious surfaces and the drainage systems. The results show that the proposed model achieved an optimized efficiency of 5.70 %, which is more than a tenfold improvement compared to existing ODIS models. The study emphasizes that the optimization of the drainage system should be the focus and the optimization of impervious surfaces should be supplementary, and different flood risk areas require different optimization strategies. Furthermore, transforming impervious surfaces into a "high-low-high" spatial distribution of impervious surface densities is the optimal design solution for impervious surfaces. In general, this study offers a novel perspective and approach to urban flooding mitigation, enabling comprehensive control of flooding from a global perspective.

Correction: High performance blue quantum dot light-emitting diodes by attaching diffraction wrinkle patterns.

Correction for 'High performance blue quantum light-emitting diodes by attaching diffraction wrinkle patterns' by Hui Qi et al., Nanoscale, 2021, DOI: 10.1039/D1NR00082A.

High performance blue quantum light-emitting diodes by attaching diffraction wrinkle patterns.

Highly efficient blue quantum-dot light-emitting diodes (QLEDs) are still challenging to use in displays and solid-state lighting. Enhancing light outcoupling is one of the most effective methods to improve the performance of blue QLEDs. Here, a strategy for a spectrally independent boost in light outcoupling of blue QLEDs is demonstrated by quasi-periodic wrinkles, which are successfully used as a diffraction grating for extracting trapped light at the substrate/air interface. The quasi-periodic wrinkles can be adjusted from nano-scale to micron-scale under the condition of a constant aspect ratio, and the optimized wrinkle device shows a maximum luminance of 11 769 cd m-2 and a peak EQE of 15.41%. The enhancement of EQE is 49.5% higher compared to that of the reference device. Furthermore, simulation and calculation also indicate that external micron-scattering wrinkle patterns are an attractive option for boosting the performances of blue QLEDs.

Understanding the changes in spatial fairness of urban greenery using time-series remote sensing images: A case study of Guangdong-Hong Kong-Macao Greater Bay.

Urban greenery is essential to the living environment of humans. Objectively assessing the rationality of the spatial distribution of green space resources will contribute to regional greening plans, thereby reducing social injustice. However, it is difficult to propose a reasonable greening policy aimed at the coordinated development of an urban agglomeration due to a lack of baseline information. This study investigated the changes in spatial fairness of the greenery surrounding residents in Guangdong-Hong Kong-Macao Greater Bay by examining time-series remote sensing images from 1997 to 2017. With the substitution of impervious, artificial surfaces for universal areas of human activities, we quantified the amount of surrounding greenery from the perspective of human activities at the pixel level by utilizing a nested buffer. The Gini coefficient was further calculated for each city to quantify the spatial fairness of the surrounding greenery to people. The results indicated that areas with less greenery surrounding them decreased during 1997 and 2017 in Guangdong-Hong Kong-Macao Greater Bay. The spatial fairness did not tend to increase with the improvements in the overall greening level. The spatial fairness of 4 cities had an increasing trend, and the Gini coefficients of 5 cities were still over 0.6 in 2017. We further proposed different greening policy suggestions for different cities based on the amount of greenery surrounding people and the trend in fairness. The results and the conclusion of this research will help to improve future regional greening policies and to reduce environmental injustice.

Germanium quantum dot infrared photodetectors addressed by self-aligned silicon nanowire electrodes.

Germanium quantum dots (GeQDs), addressed by self-aligned and epitaxial silicon nanowires (SiNWs) as electrodes, represent the most fundamental and the smallest units that can be integrated into Si optoelectronics for 1550 nm wavelength detection. In this work, individual GeQD photodetectors have been fabricated based on a low temperature self-condensation of uniform amorphous Si (a-Si)/a-Ge bilayers at 300 °C, led by rolling indium (In) droplets. Remarkably, the diameter of the GeQD nodes can be independently controlled to achieve wider GeQDs for maximizing infrared absorption with narrower SiNW electrodes to ensure a high quality Ge/Si hetero-epitaxial connection. Importantly, these hetero GeQD/SiNW photodetectors can be deployed into predesigned locations for scalable device fabrication. The photodetectors demonstrate a responsivity of 1.5 mA W-1 and a photoconductive gain exceeding 102 to the communication wavelength signals, which are related to the beneficial type-II Ge/Si alignment, gradient Ge/Si epitaxial transition and a larger QD/NW diameter ratio. These results indicate a new approach to batch-fabricate and integrate GeQDs for ultra-compact Si-compatible photodetection and imaging applications.

Optimization of Impervious Surface Space Layout for Prevention of Urban Rainstorm Waterlogging: A Case Study of Guangzhou, China.

With the rapid expansion of impervious surfaces, urban waterlogging has become a typical "urban disease" in China, seriously hindering the sustainable development of cities. Therefore, reducing the impact of impervious surfaces on surface runoff is an effective approach to alleviate urban waterlogging. Presently, the development mode of many cities in China has shifted from an increase in urban scale to the improvement of urban quality through urban renewal, which is the current and future development path for most cities. Optimizing the design of impervious surfaces in urban renewal planning to reduce its impact on surface runoff is an important way to prevent and control urban waterlogging. The aim of this research is to construct an optimization model of impervious surface space layout under the framework of a geographic simulation technology-integrated ant colony optimization (ACO) and Soil Conservation Service curve number (SCS-CN) model (ACO-SCS) in a case study of Guangzhou in China. Urban runoff plots in the study area are divided according to the area of the urban planning unit. With the goal of minimizing the runoff coefficient, the optimal space layout of the impervious surfaces is obtained, which provides a technical method and reference for urban waterlogging prevention and control through urban renewal planning. The results reveal that the optimization of impervious surface space layout through ACO-SCS achieves a satisfactory effect with an average optimization rate of 9.52%, and a maximum optimization rate of 33.16%. The research also shows that the initial impervious surface layout is the key influencing factor in ACO-SCS. In the urban renewal planning stage, the space layout of the impervious surfaces with a high-low-high density discontinuous connection can be constructed by transforming medium-density impervious surfaces into low-density impervious surfaces to achieve the flat and long-type agglomeration of the low-density and high-density impervious surfaces, which can effectively reduce the influence of urban development on surface runoff. There is spatial heterogeneity of the optimal results in different urban runoff plots. Therefore, the policy of urban renewal planning for urban waterlogging prevention and control should be different. The optimized results of impervious surface space layout provide useful reference information for urban renewal planning.

Plasmon Excited Ultrahot Carriers and Negative Differential Photoresponse in a Vertical Graphene van der Waals Heterostructure.

Photogenerated nonequilibrium hot carriers play a key role in graphene's intriguing optoelectronic properties. Compared to conventional photoexcitation, plasmon excitation can be engineered to enhance and control the generation and dynamics of hot carriers. Here, we report an unusual negative differential photoresponse of plasmon-induced "ultrahot" electrons in a graphene-boron nitride-graphene tunneling junction. We demonstrate nanocrescent gold plasmonic nanostructures that substantially enhance the absorption of long-wavelength photons whose energy is greatly below the tunneling barrier and significantly boost the electron thermalization in graphene. We further analyze the generation and transfer of ultrahot electrons under different bias and power conditions. We find that the competition among thermionic emission, the carrier-cooling effect, and the field effect results in a hitherto unusual negative differential photoresponse in the photocurrent-bias plot. Our results not only exemplify a promising platform for detecting low-energy photons, enhancing the photoresponse, and reducing the dark current but also reveal the critically coupled pathways for harvesting ultrahot carriers.

Nanodroplet Hydrodynamic Transformation of Uniform Amorphous Bilayer into Highly Modulated Ge/Si Island-Chains.

Geometric and compositional modulations are the principal parameters of control to tailor the band profile in germanium/silicon (Ge/Si) heteronanowires (NWs). This has been achieved mainly by alternating the feeding precursors during a uniaxial growth of Ge/Si NWs. In this work, a self-automated growth of Ge/Si hetero island-chain nanowires (hiNWs), consisting of wider c-Ge islands connected by thinner c-Si chains, has been accomplished via an indium (In) droplet-mediated transformation of uniform amorphous a-Si/a-Ge bilayer thin films. The surface-running In droplet enforces a circulative hydrodynamics in the nanoscale droplet, which can modulate the absorption depth into the amorphous bilayer and enable a single-run growth of a superlattice-like hiNWs without the need for any external manipulation. Meanwhile, the separation and accumulation of electrons and holes in the phase-modulated Ge/Si superlattice leads to a modulated surface potential profile that can be directly resolved by Kelvin probe force microscopy. This simple self-assembly growth and modulation dynamics can help to establish a powerful new concept or strategy to tailor and program the geometric and compositional profiles of more complex hetero nanowire structures, as promising building blocks to develop advanced nanoelectronics or optoelectronics.

A spatial assessment of urban waterlogging risk based on a Weighted Naïve Bayes classifier.

Urban waterlogging occurs frequently and often causes considerable damage that seriously affects the natural environment, human life, and the social economy. The spatial evaluation of urban waterlogging risk represents an essential analytic step that can be used to prevent urban waterlogging and minimize related losses. The Weighted Naïve Bayes (WNB) classifier is a powerful method for knowledge discovery and probability inference under conditions of uncertainty; a WNB classifier can be applied to estimate the likelihood of hazards. Six spatial factors were considered to be added to the WNB, which may improve the efficiency in predicting urban waterlogging risk during analysis. As such, a spatial framework integrating WNB with GIS was developed to assess the risk of urban waterlogging using the primary urban area of Guangzhou in China as an example. The results show that 1) the rationality of six spatial factors was determined according to the Conditional Probability Tables and weights; 2) the Most Accurate Sampling Table has objectivity; and 3) the areas with a high likelihood of waterlogging risk were mainly located in the southwestern part of the study area. The northeastern zones are relatively free of waterlogging risk. The results reveal a more accurate spatial pattern of urban waterlogging risk that can be used to identify risk "hot spots". The resulting gridded estimates provide a realistic reference for decision making related to urban waterlogging.

The development of spontaneous trait inferences about the actor and spontaneous trait transferences about the informant: Evidence from children aged 8-13 years.

In social-cognitive research, little attention has been paid to the developmental course of spontaneous trait inferences about the actor (STIs about the actor) and spontaneous trait transferences about the informant (STTs about the informant). Using a false recognition paradigm, Study 1 investigated the developmental course of STIs and Study 2 investigated the developmental course of STTs, comparing 8-, 9-, 10-, 11-, 12- and 13-year olds. The results of Study 1 showed that 8-year olds could make STIs about the actor, and the magnitude of STIs increased from ages 8 to 10 years, stabilised at the age of 10, 11, 12 years, and decreased from ages 12 through 13 years. The results of Study 2 showed that 8-year olds could make STTs about the informant, and the magnitude of STTs did not vary with age. In all age groups, the magnitude of STIs about the actor was greater than that of STTs about the informant.

Deterministic Line-Shape Programming of Silicon Nanowires for Extremely Stretchable Springs and Electronics.

Line-shape engineering is a key strategy to endow extra stretchability to 1D silicon nanowires (SiNWs) grown with self-assembly processes. We here demonstrate a deterministic line-shape programming of in-plane SiNWs into extremely stretchable springs or arbitrary 2D patterns with the aid of indium droplets that absorb amorphous Si precursor thin film to produce ultralong c-Si NWs along programmed step edges. A reliable and faithful single run growth of c-SiNWs over turning tracks with different local curvatures has been established, while high resolution transmission electron microscopy analysis reveals a high quality monolike crystallinity in the line-shaped engineered SiNW springs. Excitingly, in situ scanning electron microscopy stretching and current-voltage characterizations also demonstrate a superelastic and robust electric transport carried by the SiNW springs even under large stretching of more than 200%. We suggest that this highly reliable line-shape programming approach holds a strong promise to extend the mature c-Si technology into the development of a new generation of high performance biofriendly and stretchable electronics.

Heteroepitaxial Writing of Silicon-on-Sapphire Nanowires.

The heteroepitaxial growth of crystal silicon thin films on sapphire, usually referred to as SoS, has been a key technology for high-speed mixed-signal integrated circuits and processors. Here, we report a novel nanoscale SoS heteroepitaxial growth that resembles the in-plane writing of self-aligned silicon nanowires (SiNWs) on R-plane sapphire. During a low-temperature growth at <350 °C, compared to that required for conventional SoS fabrication at >900 °C, the bottom heterointerface cultivates crystalline Si pyramid seeds within the catalyst droplet, while the vertical SiNW/catalyst interface subsequently threads the seeds into continuous nanowires, producing self-oriented in-plane SiNWs that follow a set of crystallographic directions of the sapphire substrate. Despite the low-temperature fabrication process, the field effect transistors built on the SoS-SiNWs demonstrate a high on/off ratio of >5 × 104 and a peak hole mobility of >50 cm2/V·s. These results indicate the novel potential of deploying in-plane SoS nanowire channels in places that require high-performance nanoelectronics and optoelectronics with a drastically reduced thermal budget and a simplified manufacturing procedure.

Engineering island-chain silicon nanowires via a droplet mediated Plateau-Rayleigh transformation.

The ability to program highly modulated morphology upon silicon nanowires (SiNWs) has been fundamental to explore new phononic and electronic functionalities. We here exploit a nanoscale locomotion of metal droplets to demonstrate a large and readily controllable morphology engineering of crystalline SiNWs, from straight ones into continuous or discrete island-chains, at temperature <350 °C. This has been accomplished via a tin (Sn) droplet mediated in-plane growth where amorphous Si thin film is consumed as precursor to produce crystalline SiNWs. Thanks to a significant interface-stretching effect, a periodic Plateau-Rayleigh instability oscillation can be stimulated in the liquid Sn droplet, and the temporal oscillation of the Sn droplets is translated faithfully, via the deformable liquid/solid deposition interface, into regular spatial modulation upon the SiNWs. Combined with a unique self-alignment and positioning capability, this new strategy could enable a rational design and single-run fabrication of a wide variety of nanowire-based optoelectronic devices.

Large-area, size-tunable Si nanopillar arrays with enhanced antireflective and plasmonic properties.

In this paper, a novel method using the modified Langmuir-Blodgett and float-transfer techniques was introduced to construct the perfect PS monolayer nanosphere template with large area up to cm(2). Based on such templates, the diameter, length, packing density, and the shape of Si nanopillar arrays (Si NPAs) could be precisely controlled and tuned through the modified nanosphere lithography combined with a metal-assisted chemical etching (NSL-MACE) method. Manipulation of the etching time can effectively avoid permanent deformation/clumping to generate size-tunable Si NPAs. The optical properties of the Si NPAs can be controlled by the Si NPA morphologies resulting from the different reactive ion etching (RIE) time and chemical etching time. The enhanced antireflective property and electromagnetic field effect of Au/Si NPAs were proved by the results. The new modified NSL-MACE technique with the capability of scale-up fabrication of Si NPAs would be helpful for potential applications in optoelectronic devices.

The effects of mood on spontaneous trait inferences about the actor: Evidence from Chinese undergraduates.

Prior research has indicated that positive moods increase but negative moods decrease the trait activation of spontaneous trait inferences (STIs). However, it is unknown whether this difference is also present in STIs about the actor. In Study 1, using a false recognition paradigm, we found that Chinese undergraduates made STIs about the actor. In Study 2, we found that the happy Chinese undergraduates were more likely to make STIs about the actor than the sad Chinese undergraduates. These findings showed that Chinese people made STIs about the actor and moods had an influence on their STIs about the actor.

Examining land-use/land-cover change in the Lake Dianchi watershed of the Yunnan-Guizhou Plateau of Southwest China with remote sensing and GIS techniques: 1974­2008.

Monitoring land-use/land-cover change (LULCC) and exploring its mechanisms are important processes in the environmental management of a lake watershed. The purpose of this study was to examine the spatiotemporal pattern of LULCC by using multi landscape metrics in the Lake Dianchi watershed, which is located in the Yunnan-Guizhou Plateau of Southwest China. Landsat images from the years 1974, 1988, 1998, and 2008 were analyzed using geographical information system (GIS) techniques. The results reveal that land-use/land-cover has changed greatly in the watershed since 1974. This change in land use structure was embodied in the rapid increase of developed areas with a relative change rate of up to 324.4%. The increase in developed areas mainly occurred in agricultural land, especially near the shores of Lake Dianchi. The spatial pattern and structure of the change was influenced by the urban sprawl of the city of Kunming. The urban sprawl took on the typical expansion mode of cyclic structures and a jigsaw pattern and expanded to the shore of Lake Dianchi. Agricultural land changed little with respect to the structure but changed greatly in the spatial pattern. The landscape in the watershed showed a trend of fragmentation with a complex boundary. The dynamics of land-use/land-cover in the watershed correlate with land-use policies and economic development in China.