Cr release after Cr(III) and Cr(VI) enrichment from different layers of cast iron corrosion scales in drinking water distribution systems: the impact of pH, temperature, sulfate, and chloride.

Chromium accumulated from source water and pipeline lining materials in corrosion scales could potentially be released into bulk water in drinking water distribution systems (DWDS). This study examined the influence of pH (pH 4, pH 5.5, pH 7, pH 8.5, pH 10), temperature (5 °C, 15 °C, 25 °C), sulfate (50 mg/L, 150 mg/L, 250 mg/L), and chloride (50 mg/L, 150 mg/L, 250 mg/L) on chromium accumulation and release between iron corrosion scale phase and the surrounding water phase. For the first time, the accumulation and release behaviors of chromium were assessed and compared in two distinct layers of iron corrosion scales based on the speciation distributions of heavy metals. Results showed that in the outer and inner layers of corrosion scales, chromium exhibited an almost similar trend but significant differences in quantity, with the outer layer accumulating less and releasing more. In particular, the average difference of chromium released after Cr(VI) enrichment from the outer and inner layers was 50.53 µg/L under the same conditions. Further studies conclusively showed that in Cr(VI) accumulation process, a portion of Cr(VI) would be reduced to Cr(III) by Fe(II) in iron corrosion scales. The mechanisms of chromium retention based on different iron (oxyhydr)oxides were discussed.

Field study on the characteristics of scales in damaged multi-material water supply pipelines: Insights into heavy metal and biological stability.

Microbial corrosion and heavy metal accumulation in metal water supply pipelines aggravate scale formation and may result in pipeline leakage or bursting events. To better understand the corrosion and corrosion products in the damaged pipes, deposits excavated from three damaged pipes after 22-26 year service periods were analyzed. Using a combination of advanced micro-mineral techniques and 16S rRNA high-throughput sequencing, the micromorphology, chemical composition, and bacterial community were investigated systematically. Unlined pipe wall scales ruptured while lined pipes leaked due to joint scales. Dendrogram correlation results demonstrated that V/As, Al/Pb, and Cr/Mn clusters exhibited co-adsorption and co-precipitation characteristics. FTIR and XRD analysis detected the presence of γ-FeOOH, α-FeOOH in loose scales, and Fe3O4 in rigid scales. Scales were colonized by various corrosion bacteria, with sulfate reducing bacteria and ammonia producing bacteria being dominant in the scales of anticorrosive and non-corrosive pipe, respectively. Tl, Ca, Al, and Pb exhibited an extremely positive correlation with Rhodocyclaceae, Ferritrophicum, Thermodesulfovibrionia, and Clostridiaceae. Al and V presented a potential Hazard Quotient risk to consumers, while Cd was potentially bioavailable in all inner scales. Overall, this study provides valuable information for the effective management and avoidance of corrosion-induced pipeline damage and heavy metal release.