1.
Chem Commun (Camb)
; 59(16): 2263-2266, 2023 Feb 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36728999
RESUMO
Fluorinated dicopper(II) metal-organic framework JXNU-16F with 1,3,5-tri(3,5-bifluoro-4-carboxyphenyl)benzene ligands and nonfluorinated JXNU-16 exhibit high propyne uptakes of 443 and 496 cm3 g-1 under ambient conditions, respectively. Their remarkable propyne uptakes result from suitable pore spaces and strong propyneâ¯propyne interactions amongst the adsorbed propyne molecules, as revealed by computational simulations.