Footprints in compositions, PCDD/Fs and heavy metals in medical waste fly ash: Large-scale evidence from 17 medical waste thermochemical disposal facilities across China.

Chemical compositions, polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs) profiles and heavy metals (HMs) leachability of medical waste fly ash (MWFA) from 17 thermochemical treatment facilities in eight Chinese provinces were first investigated. Large-scale and extended monitoring revealed high chloride and Zn contents and similar PCDD/Fs congener profiles in MWFA. Particularly, the PCDD/Fs and HMs concentrations implied greater toxicity than that observed for municipal solid waste incinerator fly ash (MSWIFA). The maximum international toxic equivalent value of PCDD/Fs in MWFA was 40 times that of MSWIFA, and the leaching concentrations of Zn and Hg were 15 and 4 times those of MSWIFA, respectively. Notably, MWFA characteristics suggest the possibility of recycling and sustainable disposal solutions owing to the high Cl and Zn content with good recovery instead of landfill disposal. Similarities in chemical composition, PCDD/Fs homolog distribution, and water-solubility of chloride salts allows co-processing of MWFA and MSWIFA via water-washing detoxification and thermal treatment, such as that used in cement kilns. This study supplements existing literature on the characteristics and risk management of MWFA.

Greater phenological sensitivity on the higher Tibetan Plateau: new insights from weekly 5 km EVI2 datasets.

Plateau vegetation is considered to be highly sensitive to climate change, especially at higher altitudes. Although the Tibetan Plateau has experienced intensive warming over the past few decades, there is much contradictory evidence regarding its phenological variations and the impact of climatic change. In this study, we explored vegetation phenology through the inflexion point-based method with the weekly 0.05° EVI2 datasets from 1982 to 2010. We observed complex spatiotemporal variations in vegetation phenology on the higher Tibetan Plateau from three aspects. From a spatial aspect, the altitudinal gradients of phenological dates, as well as their directions, varied among different altitudes over the past three decades. Compared with delaying with elevation at altitudes below 5000 m, the phenological parameters at altitudes above 5000 m significantly advanced with increasing altitudes. At higher altitudes, much stronger altitudinal gradients (slope) of phenological dates were observed in the 2000s than in the 1980s and 1990s, i.e., 2.19, 3.47, and 3.68 days' advance for start, maximum, and end dates, respectively, compared to less than 1 day's change per 100 m increase in altitude. From a temporal dynamic aspect, when analyzed at different altitudinal bands, the dynamic trends in phenological dates were generally not significant except the advancing trends in the maximum dates at altitudes above 5000 m and the delaying trend in the end dates at altitudes of 4500-5000 m in the twenty-first century. Remarkable elevation dependency was also observed at the pixel level: increasing amplitudes of phenological dynamic trends were observed at higher altitudes when obtaining their minimum around 5000 m. These spatiotemporal variations of vegetation phenology were due to combined effects from both temperature and precipitation: more abundant rainfall and greater magnitudes of dynamic trends were observed in the average daily minimum temperature (slope = 0.08 °C/year) and annual precipitation (slope = 2.17 mm/year) at higher altitudes.

The effect of calcium on the treatment of fresh leachate in an expanded granular sludge bed bioreactor.

This research investigated the calcium effect on the anaerobic treatment of fresh leachate in an expanded granular sludge bed (EGSB) bioreactor under mesophilic conditions. The observations show that the bioreactor, inoculated with anaerobic granular sludge, can be started up only in about 40 days for the treatment of calcium-containing fresh leachate with chemical oxygen demand (COD) removal efficiency above 90% and organic loading rate up to 72.84 kg COD/m(3) day. The calcium accumulation onto the granules was monotonically related to the calcium concentration, accounting for 17-18 wt.% of Ca in the suspended solid in the form of calcium carbonate, phosphates/phosphonates and carboxylates. The mineral formation significantly increased the granule settling velocity (by ∼ 50%) and the suspended solid concentration (by ∼ 100%). However, the effect of calcium precipitation on the specific methanogenic activity and the CH(4) production rate was complex, first positive during the start-up but later on negative.

Effective bio-treatment of fresh leachate from pretreated municipal solid waste in an expanded granular sludge bed bioreactor.

This research investigated the anaerobic biodegradation of fresh leachate from pretreated municipal solid waste (MSW) in an expanded granular sludge bed (EGSB) bioreactor under mesophilic conditions. The observations showed that this bioreactor, inoculated with anaerobic granular sludge, could be readily activated. The chemical oxygen demand (COD) removal efficiency varied between 88% and 97% under normal operation conditions, and was kept at 94-96% under the proposed optimal conditions. We noted that 60-80% of the produced biogas was methane that was yielded at a rate depending on the organic loading rate (OLR) and the liquid up-flow velocity (Vup). Significantly, 80% of loaded COD or 83% of biodegraded COD was converted to methane under the proposed optimal conditions. These findings indicate that the fresh leachate from pretreated MSW can be efficiently treated in the EGSB bioreactor, and moreover, methane, a renewable energy, can be continuously generated.