1.
Chem Commun (Camb)
; (39): 4979-81, 2005 Oct 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-16205820
RESUMO
A new Prussian-blue type molecular magnet containing a paramagnetic [Cr(CN)5(NO)]3- building block has been synthesized and characterized; the observed magnetic behavior displays the nature of a ferrimagnet.
2.
Inorg Chem
; 43(15): 4552-4, 2004 Jul 26.
Artigo
em Inglês
| MEDLINE
| ID: mdl-15257578
RESUMO
A novel complex, [[CoAu2(CN)4(NITpPy)2(H2O)2]]n, 1, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated.