A composite gel formed by konjac glucomannan together with Nano-CF obtained by FeCl3-citric acid hydrolysis as a potential fat substitute.

This study aims to fabricate composite gels using nano citrus fiber (Nano-CF) derived from the hydrolysis process of citric acid (CA) with FeCl3, with a simultaneous exploration of its potential as an substitute to fats. Investigation of varying FeCl3 concentrations (0.01 to 0.03 mmol/g of CA) revealed a significant enhancement in the water-holding and oil-retention capacity of the Nano-CF. The meticulous synthesis of the composite gels involved integrating nano citrus fibers with konjac glucomannan (KGM) through high-speed shearing, followed by a comprehensive evaluation of its microstructure and physicochemical attributes. Increasing the Nano-CF concentration within the gels led to a synergistic interaction with KGM, resulting in enhanced viscosity, improved thermal stability, and restricted water molecule mobility within the system. The gels initially displayed reduced firmness, resilience, and adhesive characteristics, followed by subsequent improvement. When the ratio of Nano-CF to KGM was 0.5:1, the composite gels exhibited texture parameters, viscosity, and viscoelastic stability comparable to whipped animal cream formulations. These findings provide a new idea for the application of Nano-CF/KGM composite gels in whipped cream.

Flue gas torrefaction of municipal solid waste: Fuel properties, combustion characterizations, and nitrogen /sulfur emissions.

Flue gas torrefaction (FGT) was proposed as the pretreatment of the municipal solid waste (MSW) combustion process to improve the fuel properties of MSW and achieve better combustion performance. The optimal FGT parameters were obtained at 300 ℃ and 30 min, with the energy-mass co-benefit index (EMCI) reaching the maximum of 23.38. FGT could significantly increase the heating value and energy density of MSW while reducing the H/C and O/C ratio. Then, the pyrolysis and combustion experiments were performed by tube furnace and TG-MS. The results proved the chemical compositions of MSW were altered, and the heat transfer was enhanced. With FGT, NOx and SO2 emissions could be reduced by 25.7 % and 52.4 %, respectively. This study provides an in-depth understanding of the mechanism of FGT and paves the way for the clean treatment and energy utilization of MSW.

Flue gas torrefaction of distilled spirit lees and the effects on the combustion and nitrogen oxide emission.

Flue gas torrefaction (FGT) integrated with combustion was introduced for the clean treatment of distilled spirit lees (DSL). The effects of temperature, residence time, and volumetric flow rate of FGTs were investigated. The improvement in the physicochemical and combustion characteristics of the torrefied DSL and the reaction mechanisms were clarified by a tube furnace and the TG-MS device. The results showed that FGT could effectively improve the properties of DSL. With increasing temperature, residence time, and volumetric flow rate, the mass and energy yields decreased. FGT showed positive effects on the removal of free and bonding water, as well as the enrichment of lignin. FGT effectively inhibited the release of NOx. The overall emission of NOx was reduced by 57.3%. Additionally, the cost of DSL drying and denitrification could be greatly reduced by FGT. This study provided a practical treatment for DSL and new insight into FGT.

Contamination, ecological and health risks of trace elements in soil of landfill and geothermal sites in Tibet.

Due to the utilization of landfill technology and geothermal energy production in Tibet, the contamination of the soils and underground water by trace element has currently become a serious problem, both ecologically and to the human health point of view. However, relevant studies concerning this critical problem, particularly in the Tibet area has not been found. Therefore, this study investigated the soil contamination and the spatial distribution of the trace elements in the areas surrounding the Tibetan landfill sites (LS) and geothermal sites (GS) through several pollution evaluation models. In addition, the possible sources of trace elements and their potential impact on public health were also investigated. Results showed that the trace elements in soils nearby LS and GS had moderate to high contamination risk. In soils surrounding LS, mercury had the highest concentration of 0.015 mg/kg and was 6 times higher than the background value of 0.008 mg/kg while in GS, arsenic had the highest concentration of 66.55 mg/kg, and exceeded the soil contamination risk value of 25 mg/kg. Maizhokunggar LS was the most polluted site with an average pollution load index value of 2.95 compared to Naqu, Nyingchi, Shigatse, and Lhasa. 42% of LS were with considerable ecological risk, and all GS had low ecological risk. Both carcinogenic and non-carcinogenic risk for children and adults (male, female) were within the acceptable range. According to the source analysis, unscientific anthropogenic activities including accumulated MSW, industrial discharges, and vehicle emissions significantly contributed 51.83% to soil trace element contamination. Considering that Tibet is an environment-ecologically vulnerable region with very weak self-adjustment ability, accumulated municipal solid waste in the landfill sites should be well disposed of, and even soil remediation should be well implemented.

Synthesis, characterization, and antibacterial activity of N,O-quaternary ammonium chitosan.

N,N,N-Trimethyl O-(2-hydroxy-3-trimethylammonium propyl) chitosans (TMHTMAPC) with different degrees of O-substitution were synthesized by reacting O-methyl-free N,N,N-trimethyl chitosan (TMC) with 3-chloro-2-hydroxy-propyl trimethyl ammonium chloride (CHPTMAC). The products were characterized by (1)H NMR, FTIR and TGA, and investigated for antibacterial activity against Staphylococcus aureus and Escherichia coli under weakly acidic (pH 5.5) and weakly basic (pH 7.2) conditions. TMHTMAPC exhibited enhanced antibacterial activity compared with TMC, and the activity of TMHTMAPC increased with an increase in the degree of substitution. Divalent cations (Ba(2+) and Ca(2+)) strongly reduced the antibacterial activity of chitosan, O-carboxymethyl chitosan and N,N,N-trimethyl-O-carboxymethyl chitosan, but the repression on the antibacterial activity of TMC and TMHTMAPC was weaker. This indicates that the free amino group on chitosan backbone is the main functional group interacting with divalent cations. The existence of 100 mM Na(+) slightly reduced the antibacterial activity of both chitosan and its derivatives.