Improved Short-Chain Fatty Acids Production and Protein Degradation During the Anaerobic Fermentation of Waste-Activated Sludge via Alumina Slag-Modified Biochar.

As the by-product in the biological sewage treatment, waste-activated sludge (WAS) always suffers from the difficulty of disposal. Anaerobic fermentation to achieve valuable carbon sources is a feasible way for resource utilization of WAS, whereas the process is always restricted by its biochemical efficiency. Hence, the WAS was used as the feedstock in this study. Alumina slag-modified biochar (Al@BioC) respectively from pine wood (PW) or fresh vinegar residue (FVR) was employed to stimulate the process of short-chain fatty acids (SCFAs) production during the anaerobic treatment of WAS. The results indicate that the addition of Al@BioC could facilitate the distinct increase in SCFAs yield (42.66 g/L) by 14.09% and acetate yield (33.30 g/L) by 18.77%, respectively, when compared with that in regular fermentation without Al@BioC addition. Furthermore, protein degradation was also improved. With the Al@BioCPW added, the maximum concentration of soluble protein reached 867.68 mg/L and was 24.39% higher than the initial level, while the enhancement in the group with Al@BioCFVR and without biochar addition was 12.49% and 7.44%, respectively. According to the results of 16S rDNA sequencing, the relative abundance of acid-producing bacteria (Bacteroidota and Firmicutes) was enriched, enhancing the pathways of protein metabolisms and the ability to resist the harsh environment, respectively. Moreover, Proteiniphilum under Bacteroidota and Fastidiosipila under Firmicutes were the main microorganisms to metabolize protein. The above results might provide a novel material for harvesting the SCFAs production, which is conducive to harmless disposal and carbon resource recovery.

Anti-fouling PVDF membranes incorporating photocatalytic biochar-TiO2 composite for lignin recycle.

In this study, a photocatalytic biochar-TiO2 (C-Ti) composite was prepared using lignin as carbon precursor, and blended with PVDF polymer to fabricate PVDF/C-Ti MMMs via non-solvent induced phase inversion. The prepared membrane demonstrates both 1.5 times higher initial and recovered fluxes than the similarly prepared PVDF/TiO2 membrane, suggesting the C-Ti composite can help maintain higher photodegradation efficiency and better anti-fouling performance. In addition, the comparison of PVDF/C-Ti membrane against pristine PVDF membrane show that the reversible fouling and photodegradation reversible fouling of BSA increased from 10.1% to 6.4%-35.1% and 26.6%, respectively. And the FRR of PVDF/C-Ti membrane was 62.12%, 1.8 times that of PVDF membrane. The PVDF/C-Ti membrane was also applied for lignin separation, where the rejection to sodium lignin sulfonate was maintained at about 75%, and the flux recovery ratio after UV irradiation reached 90%. The demonstrated the advantages of PVDF/C-Ti membrane in photocatalytic degradation and antifouling performance.

Roles and gains of coordination chemistry in nanofiltration membrane: A review.

The nanofiltration (NF) membranes with the specific separation accuracy for molecules with the size of 0.5-2 nm have been applied in various industries. However, the traditional polymeric NF membranes still face problems like the trade-off effect, organic solvent consumption, and weak durability in harsh conditions. The participation of coordination action or metal-organic coordination compounds (MOCs) brings the membrane with uniform pores, better antifouling properties, and high hydrophilicity. Some of the aqueous-phase reactions also help to introduce a green fabrication process to NF membranes. This review critically summarizes the recent research progress in coordination chemistry relevant NF membranes. The participation of coordination chemistry was classified by the various functions in NF membranes like additives, interlayers, selective layers, coating layers, and cross-linkers. Then, the effect and mechanism of the coordination chemistry on the performance of NF membranes are discussed in depth. Perspectives are given for the further promotion that coordination chemistry can make in NF processes. This review also provides comprehensive insight and constructive guidance on high-performance NF membranes with coordination chemistry.

Using Co-Design to Explore New Trends in Future Kitchen Designs: An Exploratory Workshop Study of College Students in China.

The current COVID-19 pandemic is exacerbating the challenges facing human society. The public is increasingly concerned about the health and well-being of individuals, families, and communities. To enhance human health and well-being, user expectations for the future need to be understood. The kitchen, a central area of a home, is closely related to healthy living. In this study, a series of seven exploratory workshops were held at a Chinese university using co-design to understand the expectations and thinking of Chinese college students about the future of kitchen design in terms of health and well-being. A methodological innovation was introduced in co-design workshops, where participants were asked to imagine, discuss, and sketch concepts together to stimulate creative design. A six-dimensional tentative model of future kitchen expectations, including 34 sub-themes, was constructed based on the data analysis to explore the expected characteristics of kitchens. These dimensions include intelligent technologies and interaction experiences, health and well-being, inclusivity and extensibility, ecosystem circulation and sustainability, emotional and meaningful experience, and spatial planning and aesthetic experience. The resulting model provides valuable insights into the expectations of future users, providing direction and systematic strategies for future kitchens along the six-dimensional characteristics. Future kitchens, if the younger generation is to adopt them, need to positively affect users' lives and meet their health and well-being standards.

Designing Multi-Stage 2 A/O-MBR Processes for a Higher Removal Rate of Pollution in Wastewater.

Multi-stage A/O-MBR processes were designed to improve wastewater treatment efficiency; three different designs were carried out and compared in this study. The 2(A/O)-MBR process, i.e., with two sets of anoxic/oxic tanks in series, showed better effluent quality than A/O-MBR and 3(A/O)-MBR processes. The removal rates of COD, NH4+-N, TP and TN were 95.29%, 89.47%, 83.55% and 78.58%, respectively, complying satisfactorily with China's urban sewage treatment plant pollutant discharge standards. In terms of membrane fouling, the 3(A/O)-MBR process demonstrated the lowest fouling propensity. The microbial community structure in each bioreaction tank was analyzed, the results from which matched with the process efficiency and fouling behavior.

Fabrication of Carbon-Alumina Composites via Catalytic Pyrolysis of Pine Sawdust on Aluminum Dross for Cr(VI) Removal.

Carbon-alumina composites are prepared for the efficient removal of Cr(VI) from wastewater. Pristine and acid-treated alumina dross (AD and AAD) are copyrolyzed with pine sawdust to form the respective composites, ADPC and AADPC. Excellent absorption properties with Cr(VI) removal efficiency of 95.08% are demonstrated at 60 °C for an initial concentration of 6 µg/mL. The composites combine the merits of char, which provides a high surface-to-volume ratio with abundant functional groups on the surface, and alumina, which provides metal ions for coprecipitation. Carbon structures of pine, char, and composite were analyzed semiquantitatively using 13C NMR by a curve-fitting method. Cr(VI) adsorption is accurately described with chemisorption by the Langmuir isotherm model and a pseudo-second-order kinetic model. The results show that AADPC has more alcohol hydroxyl groups substituted to glucosyl units in amorphous cellulose assigned to the peak at 80 ppm and hemicellulose assigned to peaks at 97 and 101 ppm. Also, it has more phenolic groups in lignin distributed at syringyl units assigned to peaks at 129 and 146 ppm. These oxygen-containing functional groups have a significant influence on Cr(VI) adsorption and reduction to Cr(III) governed by the mechanisms of diffusion, adsorption, complexation, reduction, and coprecipitation. The results of this work provide a new direction for the reuse of biomass and industrial solid wastes to fabricate higher value-added products, i.e., adsorption materials for Cr(VI) removal and stabilization.

An Effective Design of Electrically Conducting Thin-Film Composite (TFC) Membranes for Bio and Organic Fouling Control in Forward Osmosis (FO).

The organic foulants and bacteria in secondary wastewater treatment can seriously impair the membrane performance in a water treatment plant. The embedded electrode approach using an externally applied potential to repel organic foulants and inhibit bacterial adhesion can effectively reduce the frequency of membrane replacement. Electrode embedment in membranes is often carried out by dispensing a conductor (e.g., carbon nanotubes, or CNTs) in the membrane substrate, which gives rise to two problems: the leaching-out of the conductor and a percolation-limited membrane conductivity that results in an added energy cost. This study presents a facile method for the embedment of a continuous electrode in thin-film composite (TFC) forward osmosis (FO) membranes. Specifically, a conducting porous carbon paper is used as the understructure for the formation of a membrane substrate by the classical phase inversion process. The carbon paper and the membrane substrate polymer form an interpenetrating structure with good stability and low electrical resistance (only about 1Ω/□). The membrane-electrode assembly was deployed as the cathode of an electrochemical cell, and showed good resistance to organic and microbial fouling with the imposition of a 2.0 V DC voltage. The carbon paper-based FO TFC membranes also possess good mechanical stability for practical use.

Experiments and Modeling of Boric Acid Permeation through Double-Skinned Forward Osmosis Membranes.

Boron removal is one of the great challenges in modern wastewater treatment, owing to the unique small size and fast diffusion rate of neutral boric acid molecules. As forward osmosis (FO) membranes with a single selective layer are insufficient to reject boron, double-skinned FO membranes with boron rejection up to 83.9% were specially designed for boron permeation studies. The superior boron rejection properties of double-skinned FO membranes were demonstrated by theoretical calculations, and verified by experiments. The double-skinned FO membrane was fabricated using a sulfonated polyphenylenesulfone (sPPSU) polymer as the hydrophilic substrate and polyamide as the selective layer material via interfacial polymerization on top and bottom surfaces. A strong agreement between experimental data and modeling results validates the membrane design and confirms the success of model prediction. The effects of key parameters on boron rejection, such as boron permeability of both selective layers and structure parameter, were also investigated in-depth with the mathematical modeling. This study may provide insights not only for boron removal from wastewater, but also open up the design of next generation FO membranes to eliminate low-rejection molecules in wider applications.

Hydrophilic Mineral Coating of Membrane Substrate for Reducing Internal Concentration Polarization (ICP) in Forward Osmosis.

Internal concentration polarization (ICP) is a major issue in forward osmosis (FO) as it can significantly reduce the water flux in FO operations. It is known that a hydrophilic substrate and a smaller membrane structure parameter (S) are effective against ICP. This paper reports the development of a thin film composite (TFC) FO membrane with a hydrophilic mineral (CaCO3)-coated polyethersulfone (PES)-based substrate. The CaCO3 coating was applied continuously and uniformly on the membrane pore surfaces throughout the TFC substrate. Due to the intrinsic hydrophilicity of the CaCO3 coating, the substrate hydrophilicity was significantly increased and the membrane S parameter was reduced to as low as the current best of cellulose-based membranes but without the mechanical fragility of the latter. As a result, the ICP of the TFC-FO membrane could be significantly reduced to yield a remarkable increase in water flux without the loss of membrane selectivity.

Gallbladder-preserving cholelithotomy in laparoscopic and flexible choledochoscopic era: a report of 316 cases.

BACKGROUND: The gallbladder is an organ with accurate functions of concentrating and storing bile and regulating the bile flow. Cholecystectomy is associated with some severe complications in some patients. This study was to investigate the safety and effectiveness of gallbladder-preserving cholelithotomy (GPC) for patients with gallstones in laparoscopic and flexible choledochoscopic era. METHODS: From January 2006 to January 2007, a total of 316 patients with gallstone were assigned to GPC according to our inclusion criteria at Yunna Lithiasis Hospital. The procedures were performed by 1 surgical team under laparoscopic and flexible choledochoscopic guidance. The short-term clinical outcome and long-term gallstone recurrence rate were evaluated. RESULTS: The success rate of GPC was 95.25%. No severe postoperative complications such as bile leakage and hemorrhage occurred. Conversion to cholecystectomy was required in 15 patients. During 25 to 72 months of follow-up, the gallstone recurrence rate at 12, 36, and 60 months were 0%, 3.32%, and 5.64%, respectively. CONCLUSION: GPC using laparoscopy and flexible choledochoscopy is safe and effective in selected patients, the stone recurrence rate is acceptable.