ZIFs-Derived Hollow Nanostructures via a Strong/Weak Coetching Strategy for Long-Life Rechargeable Zn-Air Batteries.

Recently, zeolitic imidazolate frameworks (ZIFs) composites have emerged as promising precursors for synthesizing hollow-structured N-doped carbon-based noble-metal materials with diverse structures and compositions. Here, a strong/weak competitive coordination strategy is presented for synthesizing high-performance electrocatalysts with hollow features. During the competitive coordination process, the cubic zeolitic-imidazole framework-8 (Cube-8)@ZIF-67 with core-shell structures are transformed into Cube-8@ZIF-67@PF/POM with yolk-shell nanostructures employing phosphomolybdic acid (POM) and potassium ferricyanide (PF) as the strong chelator and the weak chelator, respectively. After calcination, the hollow Mo/Fe/Co@NC catalyst exhibits superior performance in both oxygen evolution reaction (OER) and oxygen reduction reaction (ORR). Interestingly, the Mo/Fe/Co@NC catalyst exhibits efficient electrocatalytic performance for Zn-air batteries (ZABs), with a high power density (≈150 mW cm-2 ) and superior cycling life (≈500 h) compared to commercial platinum/carbon (Pt/C) and ruthenium dioxide (RuO2 ) mixture benchmarks catalysts. In addition, the density functional theory further proves that after the introduction of Mo and Fe atoms, the adsorption energy with the adsorption intermediates is weakened by adjusting the d-band center, thus weakening the reaction barrier and promoting the reaction kinetics of OER. Undoubtedly, this study presents novel insights into the fabrication of ZIFs-derived hollow structure bifunctional oxygen electrocatalysts for clean-energy diverse applications.

Biodegradation of benzo[a]pyrene by a marine Chlorella vulgaris LH-1 with heterotrophic ability.

In this study, a microalga, Chlorella vulgaris LH-1, with heterotrophic ability to degrade BaP was explored. The effect of BaP concentration on microalga growth was investigated, and the possible biodegradation mechanism of BaP was proposed. Results showed that low BaP concentration (<5 mg/L) had less negative influence on the growth of this microalga under mixotrophic condition, but high BaP concentration (>5 mg/L) had a significant inhibitory effect on its growth. During heterotrophic cultivation, low BaP concentration (<20 mg/L) promoted the growth of C. vulgaris LH-1, whereas high BaP concentration (>20 mg/L) inhibited its growth significantly. The degradation rates of mixotrophic and heterotrophic C. vulgaris LH-1 were 62.56 %-74.13 % and 52.07 %-71.67 %, respectively, when the BaP concentration ranged from 0.5 mg/L to 2 mg/L. The expression of functional enzyme genes of C. vulgaris LH-1 such as phenol 2-monooxygenase activity, protocatechuate 3,4-dioxygenase activity, catechol 1,2-dioxygenase activity, styrene degradation, and benzoate degradation were upregulated in the process of BaP degradation. C. vulgaris LH-1 may degrade BaP by monooxygenase and dioxygenase simultaneously. The degradation of BaP by this microalga under mixotrophic condition goes through the degradation pathway of phthalic acid, whereas it goes through the degradation pathway of benzoic acid under heterotrophic condition.

RNA-sequencing analysis reveals the co-biodegradation performance of crude oil by marine Chlorella vulgaris under norfloxacin stress.

In this study, the microalgal growth and crude oil (CRO) biodegradation by marine Chlorella vulgaris (C. vulgaris) were assessed under norfloxacin (NFX) stress. The presence of NFX negatively affected the bio-removal of CRO within 5 days, as the NFX concentration increased from 100 to 1600 µg/L, due to its toxicity as an antibiotic. However, its negative impact on the final degradation capabilities of C. vulgaris was less significant (P-value <0.05). After 9 days of cultivation, CRO bio-removal efficiencies still exceeded 90 %, while NFX bio-removal efficiencies maintained over 47 %. RNA-seq analysis revealed that the degradation of CRO and NFX was attributed to the combined action of functional genes involved in scavenging reactive oxygen species. The production of pigments and the bio-removal performance of C. vulgaris in CRO, NFX, and CRO & NFX coexistence media were consistent with the changes in the number of differentially expressed genes in these samples.

Effects of electron acceptors and donors on anaerobic biodegradation of PAHs in marine sediments.

Polycyclic aromatic hydrocarbons (PAHs) are typical organic pollutants accumulated in the environment. PAHs' bioremediation in sediments can be promoted by adding electron acceptor (EA) and electron donor (ED). Bicarbonate and sulfate were chosen as two EAs, and acetate and lactate were selected as two EDs. Six groups of amendments were added into the sediments to access their role in the anaerobic biodegradation of five PAHs, containing phenanthrene, anthracene, fluoranthene, pyrene, and benzo[a]pyrene. The concentrations of PAHs, EAs and EDs, electron transport system activity, and microbial diversity were analyzed during 126-day biodegradation in serum bottles. The HA group (bicarbonate and acetate) achieved the maximum PAH degradation efficiency of 89.67 %, followed by the SL group (sulfate and lactate) with 87.10 %. As the main PAHs degrading bacteria, the abundance of Marinobacter in H group was 8.62 %, and the addition of acetate significantly increased the abundance of Marinobacter in the HA group by 75.65 %.

Degradation of enrofloxacin by a novel Fe-N-C@ZnO material in freshwater and seawater: Performance and mechanism.

In this study, we investigated the doping of Fe-N-C with ZnO (Fe-N-C@ZnO) to enhance its performance in the reduction of biological toxicity and degradation of enrofloxacin (ENR) in seawater. The steady-state/transient fluorescence analysis and free radical quenching test indicated an extremely low electron-hole recombination rate and the generation of reactive oxygen species in Fe-N-C@ZnO, leading to an improvement in the energy efficiency. We compared the ENR degradation efficiencies of Fe-N-C@ZnO and ZnO using both freshwater and seawater. In freshwater, Fe-N-C@ZnO exhibited a slightly higher degradation efficiency (95.00%) than ZnO (90.30%). However, the performance of Fe-N-C@ZnO was significantly improved in seawater compared to that of ZnO. The ENR degradation efficiency of Fe-N-C@ZnO (58.87%) in seawater was 68.39% higher than that of ZnO (34.96%). Furthermore, the reaction rate constant for ENR degradation by Fe-N-C@ZnO in seawater (7.31 × 10-3 min-1) was more than twice that of ZnO (3.58 × 10-3 min-1). Response surface analysis showed that the optimal reaction conditions were a pH of 7.42, a photocatalyst amount of 1.26 g L-1, and an initial ENR concentration of 6.56 mg L-1. Fe-N-C@ZnO prepared at a hydrothermal temperature of 128 °C and heating temperature of 300 °C exhibited the optimal performance for the photocatalytic degradation of ENR. Based on liquid chromatography-mass spectrometry analysis, the degradation processes of ENR were proposed as three pathways: two piperazine routes and one quinolone route.

Using the meteorological early warning model to improve the prediction accuracy of water damage geological disasters around pipelines in mountainous areas.

This paper focuses on the threat of water damage geological disasters brought by the complex terrain along the long-distance natural gas pipeline. The role of rainfall factors in the occurrence of such disasters has been fully considered, a meteorological early warning model for water damage geological disasters in mountainous areas based on slope units has been constructed to improve the prediction accuracy of such disasters and timely early warning and forecasting. An actual natural gas pipeline in a typical mountainous area of Zhejiang Province is taken as an example. The hydrology-curvature combined analysis method is chosen to divide the slope units, and the SHALSTAB model is used to fit the slope soil environment to calculate the stability level. Finally, the stability level is coupled with rainfall data to calculate the early warning index for water damage geological disasters in the study area. The results show that compared with the separate SHALSTAB model, the early warning results coupled with rainfall are more effective in predicting water damage geological disasters. The early warning results are compared with the actual disaster points, among the nine actual disaster points, most of the slope units around seven disaster points are in the state of needing early warning, the early warning accuracy rate reaches 77.8 %. The proposed early warning model can carry out targeted deployment in advance according to the divided slope units, and the prediction accuracy of geological disasters induced by heavy rainfall weather is significantly higher and more suitable for the actual location of the disaster point, which can provide a basis for accurate disaster prevention in the research area and areas with similar geological environments.

Self-Assembly of Bi2Sn2O7/ß-Bi2O3 S-Scheme Heterostructures for Efficient Visible-Light-Driven Photocatalytic Degradation of Tetracycline.

Fabrication of S-scheme heterojunctions with enhanced redox capability offers an effective approach to address environmental remediation. In this study, high-performance Bi2Sn2O7/ß-Bi2O3 S-scheme heterojunction photocatalysts were fabricated via the in situ growth of Bi2Sn2O7 on ß-Bi2O3 microspheres. The optimized Bi2Sn2O7/ß-Bi2O3 (BSO/BO-0.4) degradation efficiency for tetracycline hydrochloride was 95.5%, which was 2.68-fold higher than that of ß-Bi2O3. This improvement originated from higher photoelectron-hole pair separation efficiency, more exposed active sites, excellent redox capacity, and efficient generation of ·O2 - and ·OH. Additionally, Bi2Sn2O7/ß-Bi2O3 exhibited good stability against photocatalytic degradation, and the degradation efficiency remained >89.7% after five cycles. The photocatalytic mechanism of Bi2Sn2O7/ß-Bi2O3 S-scheme heterojunctions was elucidated. In this study, we design and fabricate high-performance heterojunction photocatalysts for environmental remediation using S-scheme photocatalysts.

Visible-light driven p-n heterojunction formed between α-Bi2O3 and Bi2O2CO3 for efficient photocatalytic degradation of tetracycline.

To improve the efficiency of photocatalytic oxidative degradation of antibiotic pollutants, it is essential to develop an efficient and stable photocatalyst. In this study, a polymer-assisted facile synthesis strategy is proposed for the polymorph-controlled α-Bi2O3/Bi2O2CO3 heterojunction retained at elevated calcination temperatures. The p-n heterojunction can effectively separate and migrate electron-hole pairs, which improves visible-light-driven photocatalytic degradation from tetracycline (TC). The BO-400@PAN-140 photocatalyst achieves the highest pollutant removal efficiency of 98.21% for photocatalytic tetracycline degradation in 1 h (λ > 420 nm), and the degradation efficiency was maintained above 95% after 5 cycles. The morphology, crystal structure, and chemical state of the composites were analysed by scanning electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy. Ultraviolet-visible diffuse reflection, transient photocurrent response, and electrochemical impedance spectroscopy were adopted to identify the charge transfer and separation efficiency of photogenerated electron-hole pairs. The EPR results verified h+ and ˙OH radicals as the primary active species in the photocatalytic oxidation reactions. This observation was also consistent with the results of radical trapping experiments. In addition, the key intermediate products of the photocatalytic degradation of TC over BO-400@PAN-140 were identified via high-performance liquid chromatography-mass spectrometry, which is compatible with two possible photocatalytic reaction pathways. This work provides instructive guidelines for designing heterojunction photocatalysts via a polymer-assisted semiconductor crystallographic transition pathway for TC degradation into cleaner production.

Effect of terminal electron acceptors on the anaerobic biodegradation of PAHs in marine sediments.

The existing polycyclic aromatic hydrocarbons (PAHs) in marine sediment has become a critical threat to biological security. Terminal electron acceptor (TEA) amendment has been applied as a potential strategy to accelerate bioremediation in sediment. HCO3-, NO3-, and SO42- were separately added to anaerobic sediment system containing five kinds of PAH, namely, phenanthrene, anthracene, fluoranthene, pyrene and benzo(a)pyrene. PAH concentration, PAH metabolites, TEA concentration, and electron transport system (ETS) activity were investigated. The HCO3- amendment group achieved the max PAH degradation efficiency of 84.98 %. SO42- group led to the highest benzo(a)pyrene removal rate of 69.26 %. NO3- had the lowest PAH degradation rate of 76.16 %. ETS activity test showed that NO3- significantly inhibited electron transport activity in the sediment. The identified PAH metabolites were the same in each group, including 4,5-dimethylphenanthrene, 3-acetylphenanthrene, 9,10-anthracenedione, pyrene-7-hydroxy-8-carboxylic acid, anthrone, and dibenzothiophene. After 126 d's anaerobic degradation at 25 °C, the utilization of HCO3- and SO42- as selected TEAs promoted the PAH biodegradation performance better than the utilization of NO3-.

Effects of Chlorella vulgaris Enhancement on Endogenous Microbial Degradation of Marine Oil Spills and Community Diversity.

Biofortification could improve the bioremediation efficiency of microbes in the reparation of marine environmental damage caused by oil spills. In this paper, Chlorella vulgaris LH-1 was used as a fortifier to enhance the degradation of a marine oil spill by endogenous microorganisms. The addition of C. vulgaris LH-1 increased the degradation efficiency of crude oil by 11.09-42.41% and considerably accelerated oil degradation efficiency. Adding C. vulgaris LH-1 to a crude oil environment can improve the activity of endogenous seawater microorganisms. The results of high-throughput sequencing showed that the main bacterial genera were Oceanicola, Roseibacillus, and Rhodovulum when exotrophic C. vulgaris LH-1 and seawater endogenous microorganisms degraded low-concentration crude oil together. However, the addition of high-concentration nutrient salts changed the main bacterial genera in seawater to unclassified Microbacterium, Erythrobacter, and Phaeodactylibacter. The addition of C. vulgaris LH-1 increased the abundance of marine bacteria, Rhodococcus, and Methylophaga and decreased the abundance of Pseudomonas, Cladosporium, and Aspergillus. The functional prediction results of phylogenetic investigation of communities by reconstruction of unobserved states indicated that C. vulgaris LH-1 could improve the metabolic ability of seawater endogenous microorganisms to degrade endogenous bacteria and fungi in crude oil.

Facile Synthesis of Fe@C Loaded on g-C3N4 for CO2 Electrochemical Reduction to CO with Low Overpotential.

Electrochemical CO2 reduction has been acknowledged as a hopeful tactic to alleviate environmental and global energy crises. Herein, we designed an Fe@C/g-C3N4 heterogeneous nanocomposite material by a simple one-pot method, which we applied to the electrocatalytic CO2 reduction reaction (ECR). Our optimized 20 mg-Fe@C/g-C3N4-1100 catalyst displays excellent performance for the ECR and a maximum Faradaic efficiency (FE) of 88% with a low overpotential of -0.38 V vs. RHE. The Tafel slope reveals that the first electron transfer, which involves a surface-adsorbed *COOH intermediate, is the rate-determining step for 20 mg-Fe@C/C3N4-1100 during the ECR. More precisely, the coordinating capability of the g-C3N4 framework and Fe@C species as a highly active site promote the intermediate product transmission. These results indicate that the combination of temperature adjustment and precursor optimization is key to facilitating the ECR of an iron-based catalyst.

Optimization of photocatalytic degradation conditions and toxicity assessment of norfloxacin under visible light by new lamellar structure magnetic ZnO/g-C3N4.

Degradation of norfloxacin (NFX) by zinc oxide (ZnO)/g-C3N4, a magnetic sheet ZnO with g-C3N4 on its surface was studied. Through a new preparation system method, hydrothermal reaction provides a solid-layered magnetic ZnO material basis, and the simple thermal condensation method was used to transform the urea into g-C3N4 on the magnetic sheet ZnO in a uniform and orderly manner to increase the stability and photocatalytic performance of the material. Compared with previous studies, the pore volume and photocatalytic performance of the material are improved, and became more stable. By studying the degradation effect of basic and photocatalytic materials prepared in different proportions, the kinetic constant of ZGF is 0.01446 (min-1). The response surface methodology (RSM) was used to study the optimization and effect of solution pH (4-12), photocatalyst concentration (0.2-1.8 g/L), and NFX concentration (3-15 mg/L) on the degradation rate of NFX during photocatalytic degradation. The R2 value of the RSM model was 0.9656. The NFX removal rate is higher than 90% when the amount of catalyst is 1.43 g/L, the solution pH is 7.12, and the NFX concentration is less than 8.61 mg/L. After 5 cycles, the degradation rate of magnetic materials decreased to 92.8% of the first time. The capture experiment showed that the photocatalytic machine Toxicities was mainly hole action. The TOC removal rate within 2 h was 30%, a special intermediate toxicity analysis method was adopted according to the characteristics of NFX's inhibitory effect on Escherichia coli community. The toxicity of degraded NFX solution disappeared, and the possibility of non-toxic harm of by-products was verified. LC-Q-TOF method was used to detect and analyze various intermediate products converted from NFX after photocatalytic degradation, and the photocatalytic degradation pathway of NFX was proposed.

Efficient Fenton-Like Catalysis Boosting the Antifouling Performance of the Heterostructured Membranes Fabricated via Vapor-Induced Phase Separation and In Situ Mineralization.

A photocatalytic membrane with significant degradation and antifouling performance has become an important part in wastewater treatment. However, the low catalyst loading on the polymer membrane limits its performance improvement. Herein, we fabricated poly(vinylidene fluoride) (PVDF) and poly(acrylic acid) (PAA) blend membranes with a rough surface via a vapor-induced phase separation (VIPS) process. Then Fe3+ was cross-linked with the carboxyl groups on the membrane surface and further in situ mineralized into ß-FeOOH nanorods. The resultant membranes exhibit not only hydrophilicity and underwater superoleophobicity but also favorable separation efficiency and high water flux in oil-in-water emulsions separation. Under visible light irradiation, the membrane can degrade methylene blue (MB) to 95.2% in 180 min. More importantly, the membrane has a significant photocatalytic self-cleaning ability for crude oil with a flux recovery ratio (FRR) as high as 94.1%. This work brings a new strategy to fabricate the rough and porous surface for high loading of the hydrophilic photo-Fenton catalyst, improving the oil/water emulsion separation and antifouling performance of the membranes.

Anaerobic degradation of high-concentration polycyclic aromatic hydrocarbons (PAHs) in seawater sediments.

Recurring oil spill accidents have been a global challenge and contribute to PAHs' heavy accumulation in marine sediments. The rapid bioremediation of PAHs with high concentrations in marine sediments has rarely been studied. In this study, four representative PAHs in crude oil were tested for fast anaerobic biodegradation. An efficient system for the anaerobic degradation of high-concentration PAHs was obtained using petroleum-acclimated marine sediments as inoculants in the treatment system. The degradation efficiencies of benzo[b]fluoranthene, benzo[a]pyrene, pyrene, and phenanthrene reached 0.21, 1.71, 3.89, and 4.10 mg/(L·d), respectively, which are 16, 2.8, 1.8, and 1.0 times higher than the reported values. Nitrate was preferred to sulfate as an electron acceptor. The acclimated sediment contains a high abundance of hydrocarbon-degrading bacteria. The number and diversity of species in the treatment system supplemented with PAHs decreased, but the abundance of some hydrocarbon-degrading bacteria and hydrocarbon-intermediate utilising bacteria increased, and ecological succession was observed.

Effective Visible Light-Driven Photocatalytic Degradation of Ciprofloxacin over Flower-like Fe3O4/Bi2WO6 Composites.

Photocatalytic degradation of organic pollution is a vital path to deal with environmental problems. Here, a direct Z-scheme 2D/2D heterojunction of a Fe3O4/Bi2WO6 photocatalyst is fabricated for the degradation of ciprofloxacin by a self-assembly strategy. Furthermore, to characterize the morphology of the obtained composite photocatalysts, various kinds of characterization methods were employed like XRD, XPS, SEM, and TEM. It is indicated that the flower-like photocatalyst is composed of nanosheets. Comparable photocatalysts were prepared by controlling the hydrothermal temperature and the iron content. In the photocatalytic degradation of ciprofloxacin (CIP) in water, under visible light irradiation, FB-180 (synthesized at 180 °C with 4% iron content) presents approximately 99.7% degradation efficiency in only 15 min. Meanwhile, during photocatalytic degradation reactions, the Fe3O4/Bi2WO6 heterojunction also displayed excellent stability, which still kept above 90% degradation efficiency after five consecutive cycles. UV-Vis DRS and M-S analyses showed that the Fe3O4/Bi2WO6 catalyst has a strong visible light absorption capacity and the transfer pathway of photo-induced charge carriers. PL, EIS, and TPR showed that Fe3O4/Bi2WO6 has an efficient separation and transfer rate of the photo-generated carriers. ESR analysis proved that the superoxide radical (•O2 -) and hydroxyl radical (•OH) play a major role in the Fe3O4/Bi2WO6 photocatalytic system. This special 2D/2D heterojunction we proposed may have huge potential for marine pollution treatment by photocatalysis degradation with dramatically boosted activities.

Optimization of biosurfactant production from Pseudomonas sp. CQ2 and its application for remediation of heavy metal contaminated soil.

The present study was conducted to enhance the biosurfactant production yield of Pseudomonas sp. CQ2 isolated from the Chongqing oilfield (China). Besides, the capability of biosurfactant and underlying mechanism for remediation of heavy metal contaminated soil was also investigated. Our results suggested that maximum biosurfactant production (40.7 g/L) was attained at 35 °C by using soybean oil and ammonium nitrate as carbon and nitrogen sources with pH 7, rotational speed of 175 rpm and inoculation ratio of 3%). The removal efficiencies of 78.7, 65.7 and 56.9% for Cd, Cu and Pb respectively were achieved at optimized bioleaching conditions (pH: 11, soil/solution ratio: 30:1 and non-sterilized soil), comparative tests between common chemical surfactants (SDS, Tween-80) and biosurfactants demonstrated the larger removal capacity of biosurfactants. Through SEM-EDX, it was found that the granular material disappeared, the content of Cd, Cu and Pb decreased significantly, and the soil surface became smooth with hole formation after soil washing following bioleaching. ATR-FTIR results showed that the carboxyl functional groups in biosurfactants could chelate heavy metals. These results indicated that biosurfactants from Pseudomonas sp. CQ2 could effectively eliminate Cd, Cu, and Pb from soil.

Facile Synthesis of the Amorphous Carbon Coated Fe-N-C Nanocatalyst with Efficient Activity for Oxygen Reduction Reaction in Acidic and Alkaline Media.

With the assistance of surfactant, Fe nanoparticles are supported on g-C3N4 nanosheets by a simple one-step calcination strategy. Meanwhile, a layer of amorphous carbon is coated on the surface of Fe nanoparticles during calcination. Transmission electron microscopy (TEM), scanning electron microscope (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and inductively coupled plasma (ICP) were used to characterize the morphology, structure, and composition of the catalysts. By electrochemical evaluate methods, such as linear sweep voltammetry (LSV) and cyclic voltammetry (CV), it can be found that Fe25-N-C-800 (calcinated in 800 °C, Fe loading content is 5.35 wt.%) exhibits excellent oxygen reduction reaction (ORR) activity and selectivity. In 0.1 M KOH (potassium hydroxide solution), compared with the 20 wt.% Pt/C, Fe25-N-C-800 performs larger onset potential (0.925 V versus the reversible hydrogen electrode (RHE)) and half-wave potential (0.864 V vs. RHE) and limits current density (2.90 mA cm-2, at 400 rpm). In 0.1 M HClO4, it also exhibits comparable activity. Furthermore, the Fe25-N-C-800 displays more excellent stability and methanol tolerance than Pt/C. Therefore, due to convenience synthesis strategy and excellent catalytic activity, the Fe25-N-C-800 will adapt to a suitable candidate for non-noble metal ORR catalyst in fuel cells.

Enhanced Oil Recovery by a Suspension of Core-Shell Polymeric Nanoparticles in Heterogeneous Low-Permeability Oil Reservoirs.

Polymeric nanoparticle suspension is a newly developed oil-displacing agent for enhanced oil recovery (EOR) in low-permeability reservoirs. In this work, SiO2/P(MBAAm-co-AM) polymeric nanoparticles were successfully synthesized by a simple distillation-precipitation polymerization method. Due to the introduction of polymer, the SiO2/P(MBAAm-co-AM) nanoparticles show a favorable swelling performance in aqueous solution, and their particle sizes increase from 631 to 1258 nm as the swelling times increase from 24 to 120 h. The apparent viscosity of SiO2/P(MBAAm-co-AM) suspension increases with an increase of mass concentration and swelling time, whereas it decreases as the salinity and temperature increase. The SiO2/P(MBAAm-co-AM) suspension behaves like a non-Newtonian fluid at lower shear rates, yet like a Newtonian fluid at shear rates greater than 300 s-1. The EOR tests of the SiO2/P(MBAAm-co-AM) suspension in heterogeneous, low-permeability cores show that SiO2/P(MBAAm-co-AM) nanoparticles can effectively improve the sweep efficiency and recover more residual oils. A high permeability ratio can result in a high incremental oil recovery in parallel cores. With an increase of the permeability ratio of parallel cores from 1.40 to 15.49, the ratios of incremental oil recoveries (low permeability/high permeability) change from 7.69/4.61 to 23.61/8.46. This work demonstrates that this SiO2/P(MBAAm-co-AM) suspension is an excellent conformance control agent for EOR in heterogeneous, low-permeability reservoirs. The findings of this study can help to further the understanding of the mechanisms of EOR using SiO2/P(MBAAm-co-AM) suspension in heterogeneous, low-permeability reservoirs.