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1.
Phys Chem Chem Phys ; 2024 Jul 24.
Artigo em Inglês | MEDLINE | ID: mdl-39045818

RESUMO

Functionalized graphene oxide (GO) as a good additive can improve the performance of proton exchange membrane (PEM) via the introduction of various functional groups. How to balance the proton conductivity and durability of membrane based on functionalized GO is a key issue. In this work, benzoic-acid-functionalized GO(BAF-GO) and 1,2,4-triazole-functionalized GO(TF-GO) are employed as doping candidates, and the co-doping effect on membrane performance is investigated by means of experiment and molecular dynamics simulation. Meanwhile, the quantum chemistry method is implemented to explore the interaction between TF-GO, membrane and BAF-GO. The results reveal that the composite membrane exhibits high durability and enhanced proton conductivity. When the doping mass ratio of BAF-GO to TF-GO is 3 : 1, the proton conductivity can be greatly improved, especially under low-humidity conditions. Excessive addition of basic groups does not enhance proton transport.

2.
Sensors (Basel) ; 20(19)2020 Sep 27.
Artigo em Inglês | MEDLINE | ID: mdl-32992580

RESUMO

Detecting changes between the existing building basemaps and newly acquired high spatial resolution remotely sensed (HRS) images is a time-consuming task. This is mainly because of the data labeling and poor performance of hand-crafted features. In this paper, for efficient feature extraction, we propose a fully convolutional feature extractor that is reconstructed from the deep convolutional neural network (DCNN) and pre-trained on the Pascal VOC dataset. Our proposed method extract pixel-wise features, and choose salient features based on a random forest (RF) algorithm using the existing basemaps. A data cleaning method through cross-validation and label-uncertainty estimation is also proposed to select potential correct labels and use them for training an RF classifier to extract the building from new HRS images. The pixel-wise initial classification results are refined based on a superpixel-based graph cuts algorithm and compared to the existing building basemaps to obtain the change map. Experiments with two simulated and three real datasets confirm the effectiveness of our proposed method and indicate high accuracy and low false alarm rate.

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