A heparin-functionalized covered stent prepared by plasma technology.

In this study, the surface of the covered stent was treated by plasma technology to introduce amino functional groups, and glutaraldehyde and heparin were successfully grafted to prepare a heparin-functionalized covered stent (HPLCS). The preparation parameters such as plasma treatment power, plasma treatment time, concentration of glutaraldehyde and heparin, and pH of heparin solution were studied in detail. The functionalized heparin covered stent can make the titer of heparin reach 1.23 ± 0.03 IU/cm2. In animal experiments, after implantation in pigs for 6 months, the titer of heparin can still reach 0.93 ± 0.05 IU/cm2. This work provides a good method for preparing heparin covered stent.

A novel adsorbent based on aptamer prepared via "thiol-ene" click for specific recognition of phthalic acid esters.

In this paper, a novel adsorbent based on aptamer was prepared via "thiol-ene" click chemistry reaction and used for selective adsorbing the trace phthalic acid esters (PAEs) from drinking water and juice samples, which depended on the group selectivity of aptamers to the ester and the benzoyl groups of PAEs. The morphological structures of the obtained adsorbents were characterized by Fourier Transform infrared spectroscopy (FT-IR), fluorescence spectra, Energy Dispersive Spectrometer (EDS), Brunauer-Emmett-Teller (BET). The selectivity of the prepared adsorbent was evaluated and the results showed that the recovery of the adsorbent with aptamer for PAEs was 66.10-108.90%, while the recovery of adsorbent without aptamer was only 32.41-37.59%. The limit of detection (LOD) (S/N = 3) and limit of quantitation (LOQ) (S/N = 10) of PAEs coupled with HPLC-UV were obtained in the range of 0.11-0.88 µg L-1 and 0.22-1.33 µg L-1, respectively. This work gave a facile and efficient approach to for specific enrichment and highly sensitivity detection of PAEs.

A double-recognized aptamer-molecularly imprinted monolithic column for high-specificity recognition of ochratoxin A.

In this study, a double-recognized aptamer-molecularly imprinted monolithic column (Apt-MIP monolithic column) was prepared by introducing both aptamer and MIP to reduce non-specific adsorption. Its preparation parameters such as the time of photo-initiation, the dosage of photo-initiator and the concentration of aptamer were investigated in detail. The recovery ratios of ochratoxin A (OTA) to ochratoxin B (OTB) on Apt-MIP monolithic column, Apt monolithic column and MIP monolithic column were 116.1, 40.8 and 69, respectively. Even if the concentration of OTB was 10 times that of OTA, the recovery of OTB was only about 2.9%. Applied to beer samples, the prepared Apt-MIP monolithic column drastically resisted background adsorption and the high-specificity recognition for OTA was obtained with the recoveries of 95.5-105.9%. This work provided a simple and effective method to selectively identify OTA from complex samples.

Enhancement in the photocatalytic antifouling efficiency over cherimoya-like InVO4/BiVO4 with a new vanadium source.

The problem of marine life attachment and its pollution to facilities has caused a lot of great troubles in the development and application of marine resources. The holes generated by the photocatalytic coating materials under sunlight may produce strong oxidizing species and showed a significant effect on the degradation and bactericidal performance of environmental organic matter. In this paper, a novel bismuth vanadate/indium vanadate (BiVO4/InVO4) composite with cherimoya-like microstructure was fabricated using new vanadium source. It is found that the composite materials showed enhanced photocatalytic antifouling property. The degradation efficiency of the model pollutes (Rhodamine B, RhB) achieved 99.775% within 280 min over BiVO4/InVO4 nanostructures, and the sterilization rate of E. coli, S. aureus, P. aeruginosa and A. carterae achieved 99.7148%, 99.5519%, 99.5411% and 96.00%, respectively. Moreover, the circulate photocatalytic degradation of antibacteria experiments demonstrated the outstanding stability and reusability of BiVO4/InVO4 composite. According to the active free radical trapping experiments, the hydroxyl radical (OH) and superoxide radical (O2-) were certified to be the main reactive oxygen species in the BiVO4/InVO4 system. The distinctly enhanced photocatalytic performance of BiVO4/InVO4 nanomaterial primarily resulted from the narrow bandgap (about 1.86 eV). This study not only provides a new method for developing novel antibacterial materials, but also introduces a visible light-driven photocatalyst for water treatment and marine antifouling, especially for red tide control.