Stable water isotopes as a tool for assessing groundwater infiltration in sewage networks in cold climate conditions.

Effective identification and quantification of groundwater (GW) infiltration into sewage collection networks represents an important step towards sustainable urban water management. In many countries, including northern regions, sewage networks are aging to the point where renovation is needed. This study focused on the utilization of stable water isotopes as tracer substances for GW infiltration detection. The main objectives were to investigate the validity of the method for quantifying GW infiltration in cold climate conditions and to test the robustness of this method under assumed low GW infiltration rates. In general, the stable water isotopes (δ18O) produced reliable results regarding origin identification and quantification of GW infiltration rates in winter conditions (continuous below zero temperatures and snow accumulation during preceding months). The 1.6‰ distinction between the δ18O isotope composition signals of the two water sources (drinking water from river and groundwater) in the studied network was sufficient to allow source separation. However, a larger distinction would reduce the uncertainties connected to GW-fraction identification in situations where low GW infiltration rates (<8%) are expected. Due to the climate conditions (no surface water inflow), GW infiltration to the network branch monitored represented the totality of I/I (infiltration/surface inflow) flows and was estimated to reach a maximum daily rate of 6.5%. This being substantially lower than the 29% yearly average I/I rate of ca 29% reported for the city's network. Overall, our study tested the stable water isotope method for GW infiltration detection in sewage networks successfully and proved the suitability of this method for network assessment in cold climate conditions. Isotope sampling could be part of frequent monitoring campaigns revealing potential infiltration and, consequently, the need for renovation.

The Importance of Interactions at the Molecular Level: A Spectroscopic Study of a New Composite Sorber Material.

The functional properties of a new composite material having water vapor getter properties have been investigated by a large arsenal of characterization techniques. The composite system is originated by combining two constituents having very different chemical natures, a magnesium perchlorate (Mg(ClO4)2) salt and a polymeric acrylic matrix. In particular, Fourier transform infrared (FT-IR) and Raman spectroscopy have been fundamental to understand the type of interactions between the salt and the matrix in different hydration conditions. It was found that in the anhydrous composite system the dispersed Mg(ClO4)2 salt retains its molecular structure, because Mg2+ cations are still surrounded by their [ClO4]- counter-anions; at the same time, the salt and the polymeric matrix chemically interact each other at the molecular level. These interactions gradually vanish in the presence of water, and disappear in the fully hydrated composite system, where the Mg2+ cations are completely solvated by the water molecules.