Concurrent removal of carbon and nutrients in a one-stage dual internal circulation airlift A2O bioreactor from milk processing industrial wastewater: Process optimization, sludge characteristics and operating cost evaluation.

In this work, a one-stage dual internal circulation airlift anaerobic/anoxic/aerobic (DCAL-A2O) bioreactor was continuously operated for concurrent removal of nutrients and organics from milk processing wastewater (MPW). Special configuration of the airlift A2O bioreactor created possibility of the formation of desired anaerobic, anoxic and aerobic zones in a single unit. The process functionality of the bioreactor was examined under three influential operating variables i.e. hydraulic retention time (HRT; 7-15 h), air flow rate (AFR; 1-3 L/min) and aerobic volume ratio (AVR; 0.324-0.464). The optimum region was identified at HRT of 13h, AFR of 2L/min and AVR of 0.437, leading to TCOD, TN and TP removal efficiency of 94.5 %, 59.6 %, and 62.2 %, respectively, and effluent turbidity of 8 NTU. The impact of feed biodegradability on the process performance of the bioreactor treating the MPW, soft drink wastewater (SDW) and soybean oil plant wastewater (SOW) was also assessed. From the results, the feed characteristics affected significantly the nutrients removal. Moreover, the feeding location played an effective role in the nutrient removal while treating the MPW at optimum operating conditions. In this study, the change in residual organic matters as soluble microbial products (SMP) was monitored at various operating conditions. In addition, the impact of SMP extracted from sludge, extracellular polymeric substances (EPS) comprising of loosely bound EPS (LB-EPS) and tightly bound EPS (TB-EPS) was analyzed on sludge characteristics as bio-flocculation and settleability properties. According to the obtained data, the increase in operating variables led to the reduction in contents of effluent SMP, sludge SMP, LB-EPS, turbidity, and SVI, thereby, the enhancement in the sludge characteristics. Meanwhile, analysis of microbial communities verified the presence of various functional bacterial species. The cost operating evaluation confirmed the cost effectiveness of the airlift A2O bioreactor in reduction of energy consumption for the MPW treatment.

Post-treatment of soft drink industrial wastewater using a new antibacterial ultra-filtration membrane prepared of Polyethersulfone blended with boehmite-tannic acid-graphene quantum dot.

Polymeric membranes have garnered great interest in wastewater treatment; however, fouling is known as their main limitation. Therefore, the blending of hydrophilic nanoparticles in polymeric membranes' structure is a promising approach for fouling reduction. Herein, a hydrophilic boehmite-tannic acid-graphene quantum dot (BM-TA-GQD) nanoparticle was synthesized and blended in a polyethersulfone polymeric membrane in different percentages. The fabricated membranes were characterized by scanning electron microscopy (SEM), atomic force microscopy (AFM) images, water contact angle, porosity measurement, and antibacterial and antifouling properties. Surface SEM images of the modified membranes showed good dispersion of nanoparticles up to 0.5 wt%, which resulted in hydrophilicity and pure water flux enhancement. Based on AFM images, the mean roughness (Sa) of the fabricated membranes decreased from 2.07 to 0.84 nm for the bare and optimum membranes, respectively. In terms of performance, increasing the nanoparticle percentages up to 0.5 wt% resulted in the flux recovery ratio developing from 44.58% for the bare membrane to 71.35% for the 0.5 wt% BM-TA-GQD/PES membrane (optimum membrane). The antibacterial property of fabricated membranes was studied against biologically treated soft drink industrial wastewater (BTSDIW) as a bacterial source. The results showed that the turbidity of solutions containing permeated wastewater from the modified membranes (0.1, 0.5, and 1 wt% of BM-TA-GQD) was lower than that obtained from the unmodified membrane. These results confirmed the antibacterial properties of fabricated membranes. Finally, the optimal membrane (0.5 wt% BM-TA-GQD) was examined for post-treatment of the BTSDIW. An effluent COD of 13 mg/L and turbidity of 2 NTU showed a successful performance of the filtration process. PRACTITIONER POINTS: Ultrafiltration PES membranes were modified by different loadings of BM-TA-GQD. Hydrophilicity improvement was achieved by adding BM-TA-GQD nanoparticles. Expansion of size and number of macro-voids in modified membranes was confirmed. Membrane roughness was reduced in the BM-TA-GQD blended membranes. The optimum membrane was efficient in COD and turbidity removal.

Enhancing nitrogen removal from wastewater in a low C/N ratio using an air-lift bio-electrochemical reactor (ALBER).

This study focuses on the development of an air-lift bio-electrochemical reactor (ALBER) with a continuous feeding regime. The objective is to enhance nitrogen removal from synthetic wastewater with a low carbon-to-nitrogen (C/N) ratio. The chemical oxygen demand (COD) and total nitrogen (TN) of the influent wastewater were 500 and 200 mg/L, respectively. The effect of four independent variables, i.e., temperature, hydraulic retention time (HRT), N-NH4+/TN ratio and current density in the range of 16-32 °C, 6-12 h, 25-75%, and 2-10 A/m2, respectively, at three levels on the bio-electrochemical reactor performance were investigated during the bio-electrochemical reactor operation. The Face Center Cube (FCC) of response surface methodology (RSM) was used for design of experiments and model of obtained data. The ALBER achieved the maximum TN removal of 73% (146 mg/l) using external voltage and zeolite/plastic medium at temperature of 16 °C, HRT of 6 h, current density of 2 A/m2 and N-NH4+/TN ratio of 75%. The results indicated that shortening the HRT from 12 to 6 h, reducing the temperature from 32 °C to 24 °C, increasing the current density from 2 to 6 A/m2 and the reduction of nitrate concentration caused an increase in the TN removal. The results indicated that the performance of air-lift bio-electrochemical for nitrogen removal could be attributed to autotrophic denitrification (AD) and simultaneous nitrification/denitrification (SND). The research findings suggest that the ALBER should be further studied for potential use in treating industrial wastewater at low temperatures.

Arsenic and total dissolved solids removal using antibacterial/antifouling nanofiltration membranes modified by functionalized graphene oxide and copper ferrodioxide.

The intrinsic hydrophilicity of metal compounds, such as copper ferrite (CuFe2 O4 ), and organic compounds, including graphene oxide (GO) and triethylenetetramine (TETA), make them promising adsorbents for heavy metals removal. The presence of lone pairs in these compounds is observed in modified polyethersulfone membranes used for the separation of arsenic (As) and total dissolved solids (TDS), including mono and divalent salts from aqueous solutions. The objective of this study was to investigate the performance of GO-TETA-CuFe2 O4 membranes for wastewater treatment applications. The membranes were characterized for their optimal mechanical strength (tensile strength) and high negative charge (zeta potential) on the surface. Separation tests were conducted at different pressures and pH levels to evaluate the membrane's effectiveness in removing contaminants. In addition, the membranes were examined for their antibacterial properties. The modified membrane exhibited superior performance compared with the control membrane, with TDS removal rates of 93.8%, As3+ removal rates of 81.2%, and As5+ removal rates of 87.9%. The contact angle of the modified membrane was reduced, resulting in an increase in pure water flux from 13.11 to 27.87 L/m2 .h. The modified membrane also demonstrated significantly higher resistance to fouling than the control membrane, with a resistance increase from 6.78 × 10+12 to 2.07 × 10+12  m-1 . This contributed to the improved separation performance of As and TDS in a cross-flow setup. The results suggest that the GO-TETA-CuFe2 O4 modified membrane has great potential for use in water treatment applications. PRACTITIONER POINTS: GO-TETA-CuFe2 O4 was successfully used for modification of PES NF membrane structure. The efficiency of blended NF membranes with GO-TETA-CuFe2 O4 significantly increased. The modified membranes exhibited significant water flux and antifouling properties. The GO-TETA-CuFe2 O4 /PES membranes showed high rejection of heavy metal ions and TDS than PES. The GO-TETA-CuFe2 O4 /PES membranes exhibited desirable antibacterial activity.

Design of a new polyethersulfone nanofiltration membrane with anti-fouling properties using supported protic ionic liquid modification for dye/salt removal.

Facile techniques to fabricate the nanofiltration membranes with ideal molecular sieving is one of the most interesting subjects in membrane separation technology. In this study, the application of modified graphene oxide (GO) with triethylenetetramine (TETA), CuFe2 O4 , and acetic acid (AC) (supported GO-TETA-CuFe2 O4 @AC) as a supported protic ionic liquid (PIL) modifier for polyethersulfone (PES) membrane was evaluated to approve the improvement of anti-fouling properties and wastewater rejection of the fabricated membranes. To enhance the key properties of graphene oxide, it was modified by hydrophilic nanomaterials (TETA-CuFe2 O4 ). High flux and promising flux recovery ratio (up to 95% compared to the unmodified membrane) can be observed in the modified membranes. The modified membranes by GO-TETA-CuFe2 O4 @AC were studied at optimum concentrations (0.5 wt.%) for salt rejection and different dyes. The obtained data indicated that the modified membranes by GO-TETA-CuFe2 O4 @AC indicated higher salt removal (up to 97% for BaCl2 than the unmodified membrane), which was related to the efficient modification. The obtained pure water flux (PWF) for bare and optimal modified membrane from 13.11 to 27.87 kg/m2 ·h, respectively. To exact evaluate the effect of membrane modification on performance examination, the modified membranes were evaluated for chlorine resistance testing. This study aimed to develop cost-effective nanofiltration (NF) membranes with high anti-fouling properties and to determine the maximum filtration capacity of in-time dyes and salts in effluents. PRACTITIONER POINTS: A GO-TETA-CuFe2O4 mixed matrix membrane was prepared for removal of salts and dyes. The effect of GO-TETA-CuFe2O4 enhanced the hydrophilicity and porosity. The membrane exhibited superior antifouling properties and ions rejection.

Treatment capacity of a novel flexible fibre biofilm bioreactor treating high-strength milk processing wastewater.

This study was focused on the capacity investigation of a novel multistage flexible fibre biofilm reactor (MS-FFBR) to treat milk processing wastewater (MPW) with high organic loading (OLR). The MS-FFBR performance was evaluated at four intermediate stages separately, and also the final effluent quality of the overall system with an influent chemical oxygen demand (CODin) ranged from 1500 ± 20 to 6000 ± 50 mg/L and hydraulic retention times (HRTs) of 8, 12, and 16 h. By comparting the bioreactors into the four stages effectively enhanced the bioreactor's performance. The maximum TCOD removal efficiency was achieved at the first stage, which was about 89 ± 20, 82 ± 20, and 78 ± 20% at HRTs of 16, 12, 8 h, and low CODin of 1600 ± 20, 1590 ± 20, and 1673 ± 20 mg/L, respectively. However, the first stage had less contribution to TCOD removal at high CODin concentrations, reported to be about 42 ± 4%, 46 ± 4%, and 25 ± 4% at CODin of 5960 ± 40, 5830 ± 40, and 5870 ± 40 mg/L, respectively. Furthermore, the MS-FFBR was effective in removing total suspended solids (TSS) and turbidity. The bioreactor has reduced the effluent turbidity to 9.0 ± 0.2, 20.0 ± 0.6, and 16.1 ± 0.5 NTU at low CODin concentrations of 1600 ± 20, 1590 ± 20, and 1670 ± 20 mg/L and HRTs of 16, 12, and 8 h, respectively. The bioreactor revealed a high COD removal rate increased from 2.3 ± 0.1 to 12.2 ± 0.4 kg TCOD/m3d by increasing the OLR from 2.4 ± 0.1 to 17.6 ± 0.4 kg TCOD/m3d, confirming high reactor capacity for treatment of high-strength wastewater. Kinetic studies confirmed that the biomass yield was low at various HRTs ranging from 0.1 to 0.2 gVSS/gCOD.

Phosphorus removal and recovery: state of the science and challenges.

Phosphorus is one of the main nutrients required for all life. Phosphorus as phosphate form plays an important role in different cellular processes. Entrance of phosphorus in the environment leads to serious ecological problems including water quality problems and soil pollution. Furthermore, it may cause eutrophication as well as harmful algae blooms (HABs) in aquatic environments. Several physical, chemical, and biological methods have been presented for phosphorus removal and recovery. In this review, there is an overview of phosphorus role in nature provided, available removal processes are discussed, and each of them is explained in detail. Chemical precipitation, ion exchange, membrane separation, and adsorption can be listed as the most used methods. Identifying advantages of these technologies will allow the performance of phosphorus removal systems to be updated, optimized, evaluate the treatment cost and benefits, and support select directions for further action. Two main applications of biochar and nanoscale materials are recommended.

Enhanced oil removal from a real polymer production plant by cellulose nanocrystals-serine incorporated polyethersulfone ultrafiltration membrane.

As discharging oily wastewater from industries to the environment is a potential threat for the aquatic ecosystem, in this research, oil removal from a real case of Kermanshah polymer production plant wastewater was investigated. The focus of this study was on improving the oil rejection performance of polyethersulfone (PES) ultrafiltration membrane due to adding cellulose nanocrystals (CNC) and modified CNC with serine amino acid (CNC-Ser) in PES mix matrix. From the results, the membranes embedded with CNC-Ser showed better performance in terms of water flux, flux recovery ratio, and oil rejection (higher than 97%) compared to the modified membranes with CNC. The lowest water contact angle (41.37°), smoother surface, and higher negative surface potential (- 24 mV) were achieved for the optimum loading of CNC-Ser. Besides, long-term performance of the membranes with optimum loading of CNC and CNC-Ser were compared in both dead-end and cross-flow setups.

A reusable visible driven N and C-N doped TiO2 magnetic nanocomposites for photodegradation of direct red 16 azo dye in water and wastewater.

The visible active N-doped TiO2/ZnFe2O4 (urea-TiO2/ZnFe2O4) and CN-codoped TiO2/ZnFe2O4 (L-asparagine-TiO2/ZnFe2O4) nanocomposites were successfully synthesized by the sol-gel-hydrothermal method for direct red 16 (DR16) photodegradation. Their properties of the prepared nanocomposites were analysed using XRD, FT-IR, FE-SEM, EDX, DRS and PL tests. The DRS and PL results confirmed a narrow band-gap energy and low recombination rate of photo-produced electron and hole pairs, respectively. The effect of adding various dopant agents (urea and L-asparagine) with different loadings and magnetic nanoparticle (ZnFe2O4) into TiO2 sol on the photodegradation of DR16 was also evaluated. As a result, the L-asparagine (2 wt. %)-TiO2/ZnFe2O4 is the best photocatalyst compared to the other modified TiO2 nanocomposites due to its narrow band gap and high quantum efficiency. The catalyst concentration (1-2 g/L), DR16 concentration (25-45 ppm), initial pH (4-10), and irradiation time (30-90 min) as numerical variables were also considered for photocatalytic process analysis and moulding by central composite design (CCD). The increase in the pH and dye concentration reduces the photodegradation efficiency while irradiation time and catalyst concentration effectively improved its photodegradation efficiency. The DR16 was completely removed at 25 ppm of DR16, initial pH of 4 and 1.5 g/L of photocatalyst after 90-min irradiation. The photoactivity test was also repeated four times by reused L-asparagine-TiO2/ZnFe2O4 photocatalyst at optimum conditions. The decrease of dye degradation and loss of photocatalyst were not significant which was approved by the good performance and high recovery capability of the prepared nanocomposite.

Color removal from wastewater using a synthetic high-performance antifouling GO-CPTMS@Pd-TKHPP/polyether sulfone nanofiltration membrane.

Modified graphene oxide with 5,10,15,20-tetrakis-(4-hexyloxyphenyl)-porphyrin and palladium (II) (signified by GO-CPTMS@Pd-TKHPP) prepared as a novel antifouling polyether sulfone (PES) blended nanofiller membrane. The membrane efficiency has been analyzed such as pure water flux (PWF), hydrophilicity, and antifouling features. By increasing of modified graphene oxide percentage from 0 to 0.1 wt.% in the polymer matrix, the PWF was incremented from 14.35 to 37.33 kg/m2·h at 4 bar. The membrane flux recovery ratio (FRR) has been investigated by applying powdered milk solution; the FRR results indicated that the 0.1 wt.%-modified graphene oxide membrane showed a positive effect on fouling behavior with Rir and FRR value 8.24% and 91.76%, respectively. The nanofiltration membrane performance was assessed applying the Direct Red 16 dye rejection. It was demonstrated that the optimal membranes (0.1 wt.%-modified graphene oxide) had notable dye removal (99.58% rejection). The results are also verified by measuring the scanning electron microscopy (SEM), water contact angle (WCA), and atomic microscopy analysis (AFM).

Effect of Different Operational Conditions on the Treatment Performance of Milk Processing Wastewater (MPW) Using a Single Stage Flexible Fibre Biofilm Reactor (SS-FFBR).

The performance of a biofilm system, single-stage flexible fibre biofilm reactor (SS-FFBR) treating milk processing wastewater (MPW) is evaluated under various process and operational conditions. The system behavior is analyzed with different biological and physical parameters. Results show that the high COD removal efficiency of 95% is obtained at a low CODin concentration of 809 mg/L. However, the COD removal is slightly decreased to 91.7% once the CODin concentration incremented to nearly 4000 mg/L. The effect of organic loading rate (OLR) on the SS-FFBR performance is examined as total suspended solids removal efficiency, dissolved oxygen, and turbidity. The SS-FFBR showed considerable performance, so that 89.9% and 89.7% removal efficiencies in terms of COD and TSS removals, respectively, obtained at the highest OLR of 11.7 kg COD/m3d. TSS removal efficiency of 96.7% is obtained at a low OLR of 1.145 kg COD/m3d. A linear relationship between the OLR and COD removal rate was revealed. The COD removal rate was incremented from 1.08 to 10.68 kg COD/m3d as the OLR increased from 1.145 to 11.7 kg COD/m3d. Finally, the operating system is a promising technique recommended to treat various industrial wastewaters with high OLR.

A new anti-fouling polysulphone nanofiltration membrane blended by amine-functionalized MCM-41 for post treating waste stabilization pond's effluent.

Developing an effective and stable separation membrane for water treatment is of much interest while challenging because of the restrictions of membrane fouling and water flux reduction. To minimize this problem, in this work, highly porous and hydrophilic nanostructure of NH2-modified MCM-41 (NH2-MCM-41) was embedded successfully into the nanofiltration (NF) membrane body via commonly used phase inversion method. The unmodified and modified nanofiller was analyzed by Fourier Transform Infrared (FTIR) spectroscopy, X-Ray powder diffractometry (XRD), field emission scanning electron microscopy (FE-SEM), thermogravimetric analysis (TGA), and nitrogen adsorption-desorption. Furthermore, the modified membranes were characterized through surface and cross section FE-SEM images, the membrane surface roughness, hydrophilicity, antifouling properties and dye rejection. Benefiting from porous networks and enhanced hydrophilicity, the mixed matrix membranes (MMMs) revealed more prominent hydrophilic property as well as higher pure water flux (PWF) compared with naked membrane. The polysulphone (PSf) membrane modified with NH2-MCM-41-1.0 exhibited the highest pure water flux (PWF) of 65.43 kg/m2.h and superior antifouling characteristics with a flux recovery ratio (FRR) of around 97.0% and an irreversible fouling resistance (Rir) of 3.2%. Furthermore, the optimal membrane possessed high dye rejection (100%) and antifouling capacity (FRR of 97%) while filtering a field sample, effluent from a local stabilization pond treating municipal wastewater. The fabricated membrane in this study is believed to pave pathways for constructing NF membranes with superior effectiveness for other municipal and industrial wastewaters treatment.

A novel stochastic wastewater quality modeling based on fuzzy techniques.

Measurement and prediction of wastewater quality parameters are crucial for evaluating the risk to the receiving waters. This study presents new methods for the identification of outlier data and smoothing as an effective pre-processing technique prito to modelling. This new data processing method uses a combination of the autoregressive integrated moving average (ARIMA) model and -the adaptive neuro fuzzy inference system with fuzzy C-means clustering (FCM) (ANFIS-FCM). These new pre-processing methodsare compared to previously employed non-linear approaches for modelling of wastewater influent/effluent 5-day biochemical oxygen demand (BOD5), chemical oxygen demand (COD) and total suspended solids (TSS). Linear modelling of each parameter, 242 linear models, were investigated, and a linear model for each parameter was selected. The results of the non-linear models led to an acceptable prediction for qualitative parameters so that the high coefficient of determination (R 2 ) was observed for the influent and effluent BOD and TSS, respectively. The range of the R 2 for all models was recorded as 0.8-0.87 and 0.83-0.89, respectively. By a combination of the linear and non-linear mothods a hybrid model was introduced. The proposed hybrid model for the influent BOD with the highest correlation between the observed and predicted values, and limited scattering was identified as the optimal model (R2 = 0.95). The use of hybrid models to predict wastewater quality parameters improved the performance and efficiency of the models. In addition, a comparison of the hybrid model with the recently developed models in the literature indicates that the developed ARIMA-ANFIS-FCM outperformed other models.

Performance and kinetics analysis of an aerobic sequencing batch flexible fibre biofilm reactor for milk processing wastewater treatment.

In this study, a sequencing batch flexible fibre biofilm reactor (SB-FFBR) is used for efficient and cost-effective treatment of milk processing wastewater (MPW). The SB-FFBR, modified type of a typical sequencing batch reactor (SBR), is made up of eight bundles of flexible fibre as a supporting media for microorganisms'growth. The working volume and the cycle length of the bioreactor are 8 L and 24 h, respectively. The biological performance of the bioreactor is studied at 10, 3 and 10 various levels of the influent chemical oxygen demand (CODin; 610-8193 mg L-1), retention time (RT; 1, 1.6 and 2 days), and organic loading rate (OLR; 0.38-8.19 gCOD m-3d-1), respectively. From the results, the minimum COD and total suspended solids (TSS) removal efficiency of 86.8% and 77.3% were achieved at OLR of 8.2 kg COD m-3d-1, CODin of 8193 mg L-1 and RT of 1 day. While, an excellent COD and TSS removal efficiency were found to be 97.5% and 99.3%, respectively, at low OLR of 0.4 kg COD m-3d-1, CODin of 945 mg L-1 and RT of 2 days. Furthermore, the kinetic coefficients of COD removal were computed using a first order substrate removal model at different COD concentrations. The first order kinetic constant, (k), was 0.60, 0.65 and 0.357 h-1 for 500, 810 and 2000 mg COD L-1, respectively. The use of the flexible fibre as a packing material provided a huge surface area for more microorganism attachment. Therefore, the results demonstrated the SB-FFBR has acted as a suitable and effective strategy in treatment of milk processing industrial wastewater.

A novel L-Histidine (C, N) codoped-TiO2-CdS nanocomposite for efficient visible photo-degradation of recalcitrant compounds from wastewater.

The aim of current study is to synthesis novel visible driven photocatalysts (L-Histidine (C, N) codoped-TiO2-CdS) with different loadings of L-Hisitdine (1, 2, and 3 wt.%) and CdS (1:9, 7:1, and 1:5 mass ratios of CdS to TiO2). Then, their application for photo-degradation of methyl orange (MO) and biologically treated palm oil mill effluent (POME) were studied. The structure, optical properties, and morphology of the prepared nanocomposites were also characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), Fourier transform infrared (FT-IR), photoluminescence spectroscopy (PL), and diffuse reflectance spectra (DRS). DRS results indicated that all the modified samples with different L-Hisitdine and CdS loadings showed a red shift to visible region. The results of photo-degradation experiments showed that L-Hisitdine with a weight fraction of 2% and mass ratio of TiO2 to CdS of 7:1 were the optimum amount of the modifiers in the photocatalyst network. The PL intensity of the photocatalyst decreased with addition of L-Hisitdine and CdS nanoparticles due to a decrease in e-/h+ recombination. The effects of organic pollutant concentration, initial pH, catalyst concentration, and irradiation time on the photo-degradation process of MO and POME were studied using full faced centered central composite design (CCFD) under response surface methodology (RSM). The obtained results showed that MO was completely removed at initial concentration of 10 mg/L, acidic pH, and catalyst loading of 1.5 g/L after 120 min. The complete degradation of biologically treated POME was achieved at original pH, 300 mg/L of chemical oxygen demand (COD) concentration, catalyst loading of 2 g/L, and irradiation time of 2 h.

Using high frequency and low-intensity ultrasound to enhance activated sludge characteristics.

In this study, high-frequency ultrasound wave (1.8 MHz) at low intensity was applied to improve activated sludge settleability at high MLSS concentration. The effect of irradiation intensity, sonication mode, MLSS concentration and sample volume on the physical characteristics of sludge in a pilot scale settling column were investigated for optimizing the conditions. The obtained results showed that high-frequency ultrasound decreased the height of sludge (44%) and effluent turbidity (82.2%) and increased sludge settling velocity about 3 times at high biomass concentration. Irradiation intensity of 0.4 w/cm2 and sonication mode with interval times of 10 s showed the best results on the performance of the system at MLSS concentration of 8000 mg/L with a sample volume of 3 L.

Biological CNP removal from meat-processing wastewater in an innovative high rate up-flow A2O bioreactor.

A high rate up-flow anaerobic, anoxic and oxic (A2O) bioreactor was designed and operated for meat-processing wastewater (MPW) treatment as a single cost-effective system with the aim of simultaneous CNP removal. The influence of three essential factors, HRT, COD/TN ratio and aerated volume fraction on the reactor performance was assessed using response surface methodology (RSM). The required HRT to reach 98.5% COD removal was achieved at 7.5 h. Simultaneous CNP removal under denitrification rate of 199.4 mg/l.d gave high nitrate to nitrogen gas conversion of 74.6 mg/l. An HRT, COD/TN ratio and aerated volume fraction of 10 h, 100:20 and 60%, respectively, was a favored condition for an efficient nitrogen removal with effluent total Kjeldahl nitrogen (TKN) less than 70 mg/l. Under optimum condition, an HRT, COD/TN and aerated volume fraction of 8 h, 100:14 and 65%, respectively, resulted an effluent phosphorus of 43 mg/l, but 93.97 mg/l phosphorus was released in an anaerobic condition at 6 h. An effluent with a low turbidity of about 1.5 NTU and a sludge volume index (SVI) of 75.9 ml/g was achieved using at HRT of 12.5 h, COD/TN ratio of 100: 8 and aerated volume fraction of 50%. Under these conditions, the removal efficiencies for COD, TKN, nitrate-nitrogen (NO3--N), total nitrogen (TN) and phosphorus (PO43--P) were obtained to be 98.33, 92.06, 91.97, 90.48 and 83.48%, respectively. As a result, the application of the up-flow A2O bioreactor is a promising configuration to get hygienic water from wastewater.

Evaluating the process performance and potential of a high-rate single airlift bioreactor for simultaneous carbon and nitrogen removal through coupling different pathways from a nitrogen-rich wastewater.

The feasibility of a continuous feed and intermittent discharge airlift bioreactor for simultaneous carbon and nitrogen removal from a low COD/N wastewater was evaluated. The effect of two independent variables, HRT (10-20 h) and NH4+/(NH4++NO3-) ratio (0.25-0.75), on the bioreactor performance was studied. The relatively high anaerobic to aerobic time ratio made an effective contribution to NH4+, NO3-, and TN removal. TN removal was enhanced with increase in HRT and decrease in NH4+/NH4++NO3- and at the optimum condition, 616 mg/L (88%) and 213 mg/L (76%) of sCOD and TN were removed, respectively. The results suggested that the nitrogen removal process was based on a combination of anaerobic ammonium oxidation (Anammox), simultaneous nitrification-denitrification (SND), and presumable dissimilatory nitrate reduction to ammonium (DNRA) mechanisms.

Process optimization of CNP removal from industrial soft drink wastewater in a single up flow A2O with continuous feed and intermittent discharge regime.

Simultaneous removal of carbon and nutrients (CNP) in a single laboratory-scale bioreactor is advantageous in terms of reactor volume and energy consumption. In this study, an innovative up-flow anaerobic/anoxic/aerobic (A2O) single bioreactor with continuous feed and intermittent discharge (CFID) regime equipped with a movable aerator in the reactor height for simultaneous removal of CNP from soft drinks wastewater was successfully designed, fabricated and operated. The effects of four independent variables, i.e. hydraulic retention time (HRT), aerator height, biomass concentration and nitrogen/soluble chemical oxygen demand (N/sCOD) ratio at three levels in the range of 4-8 h, 37-55.5 cm, 4,000-6,000-1, and 0.05-0.2, respectively, on eight process responses were investigated. The central composite design (CCD) and response surface methodology (RSM) were applied to design the experimental conditions, model the obtained data, and optimize the process. The bioreactor provides three conditions with different dissolved oxygen (DO) (anaerobic, anoxic and aerobic) in a single bioreactor by placing the aerator in the middle of the reactor. As a result, the maximum sCOD, total nitrogen (TN) and total phosphorus (TP) removal were about 100, 92 and 41%, respectively. The optimum region obtained was an HRT of 5-11 h, a mixed liquor suspended solids (MLSS) concentration of 4,000-4,700 mgL-1, and an aerator height of 46.25 cm, at the N/sCOD ratio of 0.1.

Enhancement of anaerobic digestibility of waste activated sludge using photo-Fenton pretreatment.

Biological treatments, such as activated sludge process, are common methods to treat municipal and industrial wastewaters. However, they produce huge amounts of waste activated sludge (WAS). The excess sludge treatment and disposal are a challenge for wastewater treatment plants due to economic, environmental, and regulatory factors. In this study, photo-Fenton pretreatment (oxidation using hydrogen peroxide and iron catalyst aided with UV light) was optimized using response surface methodology (RSM) and central composite design (CCD) to determine the effects of three operating parameters (H2O2 dosage, H2O2/Fe2+ molar ratio, and irradiation time) on disintegration and dewaterability of WAS. MLVSS removal, capillary suction time (CST) reduction, sCOD, and EPS were obtained as 70%, 25%, 12,000 mg/L, and 500 mg/L, respectively, at the optimal conditions, i.e., 725 g H2O2/kg TS, H2O2/Fe2+ molar ratio 80, and irradiation time 40 min. Two batch-fed completely mixed mesophilic anaerobic digesters were then operated at 15-day solid retention time (SRT) and 37 ± 0.5 °C to compare the digestibility of untreated and photo-Fenton pretreated sludge in terms of volatile solids (VS) reduction, COD removal, and biogas production at steady-state operations. Photo-Fenton pretreatment followed by anaerobic digestion of WAS was very effective and yielded 75.7% total VS reduction, 81.5% COD removal, and 0.29-0.31 m3/kg VSfed·d biogas production rate, compared to 40.7% total VS solid reduction, 54.7% COD removal, and 0.12-0.17 m3/kg VSfed·d biogas production rate for control. Thus, photo-Fenton can be a useful pretreatment step in sludge management.