Understanding the Toughening Mechanism of Silane Coupling Agents in the Interfacial Bonding in Steel Fiber-Reinforced Cementitious Composites.

Interfacial bonding between a fiber and a matrix plays an essential role in composites, especially in fiber-reinforced cementitious composites that are superior forms for bearing flexural and tension load in construction applications. Yet, despite the importance, effective and economic approaches to improve the interfacial bonding between a steel fiber and a cementitious matrix remain unfeasible. Herein, we report a pathway adopting a silane coupling agent (SCA) to modify an interfacial transition zone (ITZ) and enhance interfacial bonding. This approach involves coating a SCA layer onto a steel fiber, where tight physical and chemical bondings (via cross-linking of silicate chains) with a cementitious matrix are formed, leading to an 83.5% increase in pullout energy. Combining nanoindentation and an atomistic force microscope with molecular simulation, we find that SCA increases the surface roughness of the steel fiber, accelerates the hydration reaction of cement clinker, and promotes the volume fraction of the C-S-H phase, inducing a denser and more uniform ITZ with an adequate stress-transfer capability that shifts the mode of failure from interfacial debonding to cement cracking. This work presents an effective and economical approach to improve interfacial bonding, and it enables us to design more durable fiber-reinforced cementitious composites, which can be massively used to build innovative infrastructures.

Experimental Investigation on Interfacial Defect Criticality of FRP-Confined Concrete Columns.

Defects between fiber reinforced polymer (FRP) and repaired concrete components may easily come out due to misoperation during manufacturing, environmental deterioration, or impact from external load during service life. The defects may cause a degraded structure performance and even the unexpected structural failure. Different non-destructive techniques (NDTs) and sensors have been developed to assess the defects in FRP bonded system. The information of linking up the detected defects by NDTs and repair schemes is needed by assessing the criticality of detected defects. In this study, FRP confined concrete columns with interfacial defects were experimentally tested to determine the interfacial defect criticality on structural performance. It is found that interfacial defect can reduce the FRP confinement effectiveness, and ultimate strength and its corresponding strain of column deteriorate significantly if the interfacial defect area is larger than 50% of total confinement area. Meanwhile, proposed analytical model considering the defect ratio is validated for the prediction of stress⁻strain behavior of FRP confined columns. The evaluation of defect criticality could be made by comparing predicted stress⁻strain behavior with the original design to determine corresponding maintenance strategies.

Influence of Wind Pressure on the Carbonation of Concrete.

Carbonation is one of the major deteriorations that accelerate steel corrosion in reinforced concrete structures. Many mathematical/numerical models of the carbonation process, primarily diffusion-reaction models, have been established to predict the carbonation depth. However, the mass transfer of carbon dioxide in porous concrete includes molecular diffusion and convection mass transfer. In particular, the convection mass transfer induced by pressure difference is called penetration mass transfer. This paper presents the influence of penetration mass transfer on the carbonation. A penetration-reaction carbonation model was constructed and validated by accelerated test results under high pressure. Then the characteristics of wind pressure on the carbonation were investigated through finite element analysis considering steady and fluctuating wind flows. The results indicate that the wind pressure on the surface of concrete buildings results in deeper carbonation depth than that just considering the diffusion of carbon dioxide. In addition, the influence of wind pressure on carbonation tends to increase significantly with carbonation depth.

Effect of Stress Amplitude on the Damping of Recycled Aggregate Concrete.

Damping characterizes the energy dissipation capacity of materials and structures, and it is affected by several external factors such as vibrating frequency, stress history, temperature, and stress amplitude. This study investigates the relationship between the damping and the stress amplitude of environment-friendly recycled aggregate concrete (RAC). First, a function model of a member's loss factor and stress amplitude was derived based on Lazan's damping-stress function. Then, the influence of stress amplitude on the loss tangent of RAC was experimentally investigated. Finally, parameters used to determine the newly derived function were obtained by numerical fitting. It is shown that the member's loss factor is affected not only by the stress amplitude but also by factors such as the cross section shapes, boundary conditions, load types, and loading positions. The loss tangent of RAC increases with the stress amplitude, even at low stress amplitude. The damping energy exponent of RAC is not identically equal to 2.0, indicating that the damping is nonlinear. It is also found that the energy dissipation capacity of RAC is superior to that of natural aggregate concrete (NAC), and the energy dissipation capacity can be further improved by adding modified admixtures.