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1.
Sci Rep ; 14(1): 15911, 2024 Jul 10.
Artigo em Inglês | MEDLINE | ID: mdl-38987571

RESUMO

In order to develop a method for the production of crack-free cladding layers, we combined surface texturing technology with laser cladding, establishing a multi-field coupled numerical simulation model. A separate investigation was conducted into the temperature, stress, and fluid fields in laser cladding processes with and without texturing, seeking optimal cladding parameters, and conducted experiments. The results of the numerical simulations indicate that pre-set texturing effectively reduces the temperature gradient during the cladding process, thereby making the thermal cycle curve smoother. The residual stresses in the X, Y, and Z directions are reduced by 34.84%, 3.94%, and 50.22%, respectively. The introduction of texturing reduces the internal flow velocity of the melt pool, preventing the occurrence of a double vortex effect. Experimental results show that the residual stresses in the X, Y, and Z directions of the predefined textured cladding layer are reduced by approximately 41%, 8%, and 47%, respectively, compared to the non-textured cladding layer. This effectively improves the surface roughness and internal grain size of the cladding layer, with no significant defects at the metallurgical bonding positions, providing a reference for future improvements in cladding layer quality.

2.
Materials (Basel) ; 17(12)2024 Jun 12.
Artigo em Inglês | MEDLINE | ID: mdl-38930245

RESUMO

Friction stir processing (FSP) was performed on an AZ91 magnesium alloy cladding layer fabricated by a cold metal transfer (CMT) technique. Electrochemical properties and immersion corrosion behavior of the cladding layer before and after FSP in 3.5 wt.% NaCl solution were investigated. After applying the FSP, the corrosion potential and corrosion current density of the cladding layer increased from -1.455 V to -1.397 V and decreased from 4.135 µA/cm2 to 1.275 µA/cm2, respectively. The results of OM and SEM displayed the refinement of grains and the dispersion of ß-Mg17Al12 second phase in the friction stir processed (FSPed) cladding layer and more severe corrosion of the unprocessed sample. The corrosion rate of the FSPed cladding layer was lower, and a more compact corrosion product film was formed on the surface of the FSPed cladding layer. EDS results and XRD patterns showed that the corrosion products was mainly composed of Mg(OH)2. The increase in Al content in the α-Mg matrix, grain refinement, and fragmentation and dispersion of the ß-Mg17Al12 second phase induced by FSP were the main factors that led to the improvement in corrosion resistance of the cladding layer of the AZ91 magnesium alloy fabricated by CMT.

3.
Heliyon ; 10(11): e32672, 2024 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-38912442

RESUMO

This study investigated the potential of using stonepaste ceramics, which were widely preferred as a coating and decoration material on the facades of architectural buildings in ancient times and continues to be produced on a workshop scale today as a cladding material on building facades. Stonepaste ceramics, made from a mixture prepared with a high amount of crystalline quartz as well as frit, plastic clay, and bentonite raw materials, were hand-shaped and sintered at 930 °C after glazing. The physico-mechanical properties of stonepaste ceramics, their behaviour under various environmental conditions (resistance to chemicals, frost, and thermal shock), and their microstructures have been characterized. The characterization results were compared with the properties of commonly used facade cladding materials. It was determined that stonepaste ceramics had a very low firing shrinkage value (2.84 %) compared to that of other ceramic cladding materials, a higher water absorption value (11.79 %) than that of porcelain tiles and floor tiles, and close to wall tiles, and a flexural strength value (33.64MPa) higher than wall tiles and close to porcelain tiles despite the high-water absorption value. Ten cycles of thermal shock resistance showed that the body and glaze layer of the stonepaste ceramic material are well bonded to each other, and there is no significant thermal expansion mismatch between them. One hundred cycles of freeze-thaw conditions indicated that the stonepaste ceramic had good adhesion and thermal expansion compatibility between the glaze and the body but only chipping damage under the action of tensile forces caused by the freezing of water entering the pores of the body. In terms of behaviour against various chemicals, stonepaste ceramics were found to be highly resistant to high and low concentrations of household chemicals, swimming pool salts, and alkalis but less resistant to low concentrations of HCl and citric acid and high concentrations of HCl and lactic acid compared to other chemicals. The results show that stonepaste ceramics, despite their high-water absorption potential, have properties close to those of traditional ceramic tiles and, like these materials, can serve for significant periods in various environmental conditions when used as facade cladding. Consequently, it has been revealed that stonepaste ceramics can be used as a facade cladding material in sustainable, long-lasting, contemporary architectural facades thanks to their technical and protective properties.

4.
Materials (Basel) ; 17(10)2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38793428

RESUMO

Friction stir processing (FSP) is a solid-state treating method to enhance the mechanical properties of materials by altering their microstructure. In this study, FSP was applied to the AZ91 magnesium alloy cladding layer prepared using cold metal transition (CMT) technology, and the purpose was to investigate the effect of the traverse speed of the H13 steel stirring head under a constant rotation speed on the microstructure and mechanical properties of the cladding layer. The results demonstrated that FSP could effectively decrease the grain size of the cladding layer and lead to the dispersion and dissolution of the coarse ß-Mg17Al12 second phase into the α-Mg matrix. The mechanical characteristics of the processed cladding layer were significantly enhanced compared to the unprocessed cladding layer due to the grain refinement and second-phase strengthening induced by FSP. When the stirring head rotation speed was set at 300 r/min, the average microhardness and tensile properties of the specimens showed a tendency of initially increasing and then dropping as the traverse speed increased. The cladding layer, obtained at a traverse speed of 60 mm/min, displayed optimal mechanical properties with an average microhardness, tensile strength, and elongation of 85.6 HV0.1, 278.5 MPa, and 13.4%, respectively.

5.
Materials (Basel) ; 17(9)2024 Apr 30.
Artigo em Inglês | MEDLINE | ID: mdl-38730923

RESUMO

This study investigated how process parameters of laser cladding affect the microstructure and mechanical properties of WC-12Co composite coating for use as a protective layer of continuous caster rolls. WC-Co powders, WC-Ni powders, and Ni-Cr alloy powder with various wear resistance characteristics were evaluated in order to determine their applicability for use as cladding materials for continuous caster roll coating. The cladding process was conducted with various parameters, including laser powers, cladding speeds, and powder feeding rates, then the phases, microstructure, and micro-hardness of the cladding layer were analyzed in each specimen. Results indicate that, to increase the hardness of the cladding layer in WC-Co composite coating, the dilution of the cladding layer by dissolution of Fe from the substrate should be minimized, and the formation of the Fe-Co alloy phase should be prevented. The mechanical properties and wear resistance of each powder with the same process parameters were compared and analyzed. The microstructure and mechanical properties of the laser cladding layer depend not only on the process parameters, but also on the powder characteristics, such as WC particle size and the type of binder material. Additionally, depending on the degree of thermal decomposition of WC particles and evolution of W distribution within the cladding layer, the hardness of each powder can differ significantly, and the wear mechanism can change.

6.
Heliyon ; 10(9): e30176, 2024 May 15.
Artigo em Inglês | MEDLINE | ID: mdl-38765171

RESUMO

This investigation aims to study the effect of laser cladding parameters on the microstructure of Stellite 6 on the X19CrMoNbVN11-1 stainless-steel substrate. First, Stellite 6 powder was coated on the X19CrMoNbVN11-1 substrate using the laser cladding method. The effect of laser cladding parameters (i.e., laser power, scanning speed, and powder feed rate) was studied on the microstructure of deposits. The secondary dendritic arm spacing was assessed, and the structural defects were studied (e.g., lack of bonding, porosity, and crack). The results revealed that the microstructure has changed from coating/substrate interface to coating surface, from plate-cellular to columnar and equiaxed dendrites. Also, an increase in the laser power increased the cellular structure in the coating/substrate interface and equiaxed dendrites in the coating surface. The cooling rate (G × R) increased by increasing the scanning and powder injection rates. The microstructure of the Stellite 6 was composed of cobalt solid-solution γFCC.

7.
Sci Rep ; 14(1): 11685, 2024 May 22.
Artigo em Inglês | MEDLINE | ID: mdl-38778176

RESUMO

The purpose of this study was to investigate the effect of Al content on Fe-Ni-Al coatings. A Fe-Ni-Al coating was prepared using a semiconductor laser, and the influence of the Al content on the microstructure and properties of the coating was examined. The microstructure of the coating was characterized using scanning electron microscopy, X-ray diffraction, and energy-dispersive X-ray spectroscopy. The coefficient of thermal expansion of the coating was measured using a static thermomechanical analyzer. The microhardness and wear performance of the coating were analyzed using a microhardness tester and a wear testing machine. The results were as follows. The addition of Al to the Fe-Ni ferroalloy powder resulted in the in situ formation of an AlNi/Fe-Ni laser cladding layer. When the Al content was low, the coating mainly consisted of γ-[Fe,Ni] austenite. As the Al content increased, the matrix phase structure of the cladding layer transformed into the α phase. Consequently, the Invar effect was gradually compromised, leading to the generation of defects in the coating. When the Al content was 4%, the coating performance improved while maintaining a low coefficient of thermal expansion. At this point, there were relatively few cracks in the cladding layer, and it exhibited the best wear resistance.

8.
Materials (Basel) ; 17(3)2024 Jan 28.
Artigo em Inglês | MEDLINE | ID: mdl-38591470

RESUMO

Laser cladding is one of the emerging additive manufacturing technologies and has been adopted in various industrial fields. In this study, the morphological characteristics of a single clad of Inconel 718 manufactured by coaxial laser cladding with high laser power from 4200 W to 5400 W, powder feeding rate from 25 g/min to 50 g/min, and cladding speed from 20 mm/s to 50 mm/s are studied. The cross-section of the melt pool is analyzed and classified by type into three types: shallow dilution, flat dilution, and fluctuating dilution. Nine parameters are designed to describe the morphological characteristics of the clad, and the corresponding linear regression models are developed to establish a quantitative relationship between the combined process parameters and morphological characteristics. The results indicate that the total area of the cross-section A, the clad area above the substrate Ac, the area of the molten substrate Am, the total height of the cross-section H, the height of the clad above the substrate hc, the penetration depth hm, the clad width W, the dilution ratio D, and the wetting angle θ are determined by complex coupling of energy input and mass accumulation, and they are proportional to PF0.4/V, P0.5F/V, P/F0.2/V0.4, P2F0.6/V, PF0.7/V, P2/F/V0.3, P/V0.8, P/FV0.2, and PF7/V0.8, respectively. The large linear regression coefficients and the analysis residuals indicate the high reliability of the statistical linear regression models. This work aims to provide a comprehensive understanding of the influence of the main processing parameters on the morphological characteristics of the clad, which is of great value in providing a reference and laying a basis for the practical application of laser cladding technology at a high deposition rate.

9.
Materials (Basel) ; 17(7)2024 Mar 26.
Artigo em Inglês | MEDLINE | ID: mdl-38612012

RESUMO

Ni60-WC coatings with different WC contents on the bucket tooth substrates were pre- pared using laser cladding technology. Their abrasive wear properties were assessed using the dry sand rubber wheel test system. The substrate and the hard-facing layer were tested for comparison. The results showed that the hardness of the Ni60-WC coatings increased with the increase in WC content. The wear resistance of the bucket tooth substrate was greatly improved by hard-facing and laser cladding Ni60-WC coatings. The wear rate of the hard-facing layer was reduced to 1/6 of that of the tooth substrate. The wear rate of the laser cladding coatings with 20-40 wt.% WC was similar to that of the hard-facing layer. It is worth mentioning that the wear rate of the coatings with 60-80 wt.% WC was only 1/4 of that of the hard-facing layer. Micro-cutting with surface plastic deformation was the main wear mechanism of the substrate to form narrow and deep furrows. The wear mechanism of the hard-facing layer was mainly plastic deformation with a wide groove, and the surface cracks promoted the removal of the material. The removal of the binder phase caused by micro-cutting was the main wear mechanism of the laser cladding Ni60-WC coatings. However, the hard phase of WC hinders micro-cutting and plastic deformation, which improves the wear resistance of the coating.

10.
Sensors (Basel) ; 24(5)2024 Feb 25.
Artigo em Inglês | MEDLINE | ID: mdl-38475027

RESUMO

This study proposes a novel multipoint transducer system by utilizing the single-mode-multimode-thin-cladding fiber (SMTC) structure. This structure leverages the disparity in mode field diameter between the multimode fiber (MMF) and thin-cladding fiber (TCF) to generate high-amplitude ultrasonic signals safely and efficiently. The fabricated transducer exhibits signal amplitudes 2-3-fold higher compared to conventional laser-ultrasonic transducers. Simulation analysis investigates the impact of the length of the MMF and the diameter of the TCF on coupling efficiency. The coupling efficiency of individual transducer units can be accurately controlled by adjusting the length of the MMF. A three-point energy-balanced laser-ultrasonic transducer system was achieved, with improved energy conversion efficiencies, and the optimal thickness of candle soot nanoparticles (CSNPs) is experimentally determined. Additionally, we carried out experiments to compare the performance of the proposed SMTC-based transducer system under different material conditions using two different photoacoustic materials: graphite-epoxy resin and candle soot nanoparticle-polydimethylsiloxane (CSNP-PDMS) composite. CSNPs, as a cost-effective and easy-to-prepare composite material, exhibit higher photoacoustic conversion efficiency compared to graphite-epoxy resin. The proposed system demonstrates the potential for applications in non-destructive testing techniques.

11.
Materials (Basel) ; 17(5)2024 Feb 20.
Artigo em Inglês | MEDLINE | ID: mdl-38473442

RESUMO

The design of the resonant ultrasonic vibration-assisted laser cladding (R-UVALC) setup involved employing finite element analysis (FEA) to simulate the ultrasonic transducer, horn, and workpiece in a resonance state. The impact of R-UVALC on AlCrFeMnNi high-entropy alloys was assessed using various ultrasonic vibration amplitudes of 0, 5, 10, and 15 µm, with a constant frequency of 20 kHz. Ultrasonic vibrations reduced pores and cracks and increased the clad breadth, melt pool wetting angle, and laser-clad layer consistency. The columnar elongated grains in proximity to the substrate surface underwent a size reduction and transformed into grains with a more equiaxed shape with the utilization of ultrasonic vibrations at an amplitude of 5 µm. Laser cladding performed without ultrasonic vibrations yields two phases: face-centered cubic (FCC) and body-centered cubic (BCC). However, when the coating is exposed to ultrasonic vibrations with an amplitude of 5 µm, it forms a solitary body-centered cubic (BCC) phase. The microhardness tripled compared to the substrate, and the most significant microhardness value was achieved at 5 µm of ultrasonic vibration. The friction coefficient was assessed at an ambient temperature, revealing that an ultrasonic amplitude yields the lowest friction coefficient, demonstrating the excellent wear resistance properties of the coating. The analysis of the 3D surface profile of the wear indicates that the use of ultrasonic aid with a 5 µm amplitude leads to reduced depth of scars, and the primary wear mechanism observed is abrasive and oxidative wear with fewer grooves and debris. In addition, XPS analysis revealed the presence of metal components in an oxidized condition, suggesting that the wear process is oxidative in nature. Integrating the R-UVALC setup into a resonance state can significantly enhance the efficiency of the laser cladding process in the laser cladding field.

12.
Materials (Basel) ; 17(5)2024 Feb 28.
Artigo em Inglês | MEDLINE | ID: mdl-38473573

RESUMO

Hydrogen plays an important role in the corrosion of zirconium alloys, and the degree of influence highly depends on the alloy composition and conditions. In this work, the effects of hydrogenation on the corrosion behavior of Zircaloy-4 in water containing 3.5 ppm Li + 1000 ppm B at 360 °C/18.6 MPa were investigated. The results revealed that hydrogenation can shorten the corrosion transition time and increase the corrosion rates of Zircaloy-4. The higher corrosion rates can be ascribed to the larger stress in the oxide film of hydrogenated samples, which can accelerate the evolution of the microstructure of the oxide film. In addition, we also found that hydrogenation has little effect on the t-ZrO2 content in the oxide film and there is no direct correspondence between the t-ZrO2 content and the corrosion resistance of the Zircaloy-4.

13.
Materials (Basel) ; 17(5)2024 Feb 29.
Artigo em Inglês | MEDLINE | ID: mdl-38473600

RESUMO

The hardness and wear resistance of the surface of TC4 titanium alloy, which is widely used in aerospace and other fields, need to be improved urgently. Considering the economy, environmental friendliness, and high efficiency, Si-reinforced Ti-based composite coatings were deposited on the TC4 surface by the high-speed wire-powder laser cladding method, which combines the paraxial feeding of TC4 wires with the coaxial feeding of Si powders. The microstructures and wear resistance of the coatings were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), Vickers hardness tester, and friction and wear tester. The results indicate that the primary composition of the coating consisted of α-Ti and Ti5Si3. The microstructure of the coating underwent a notable transformation process from dendritic to petal, bar, and block shapes as the powder feeding speed increased. The hardness of the composite coatings increased with the increasing Si powder feeding rate, and the average hardness of the composite coating was 909HV0.2 when the feeding rate reached 13.53 g/min. The enhancement of the microhardness of the coatings can be attributed primarily to the reinforcing effect of the second phase generated by Ti5Si3 in various forms within the coatings. As the powder feeding speed increased, the wear resistance initially improved before deteriorating. The optimal wear resistance of the coating was achieved at a powder feeding rate of 6.88 g/min (wear loss of 2.55 mg and friction coefficient of 0.12). The main wear mechanism for coatings was abrasive wear.

14.
Sci Rep ; 14(1): 5160, 2024 Mar 02.
Artigo em Inglês | MEDLINE | ID: mdl-38431656

RESUMO

Deposition of high entropy alloy FeCoNiMnCu on SS-304 was carried out by microwave energy for application in "solid oxide fuel-cell (SOFC) interconnects". The ball-milling has been performed by taking "Fe, Co, Ni, Mn, and Cu" in equal 20 wt. % of before deposited on SS-304 substrate. The deposited steel with 20% Fe 20% Co 20% Ni 20% Mn 20% Cu high entropy alloy (HEA) was exposed to thermal-exposure in the air for up to 10 weeks at 800 °C. The uniform cladding distribution of 20% Fe 20% Co 20% Ni 20% Mn 20% Cu HEA particles can be apparently observed on SS-304 substrate by utilizing Scanning Electron Microscope (SEM), and Optical microscopy analysis. Homogeneity in the interfacial layer was evident by employing Scanning Electron Microscope (SEM) characterization. Results have indicated that after the thermal exposure of deposited steel with 20% Fe 20% Co 20% Ni 20% Mn 20% Cu in the air for up to ten weeks at 800 °C, a "protective Cr2O3 layer", and "high-entropy spinel coating" of (Fe, Co, Ni, Mn, Cu)3O4 have been formed. During microwave cladding, the emergence of harder-phases has contributed to the raised hardness. The wear behavior after coating of 20% Fe 20% Co 20% Ni 20% Mn 20% Cu HEA on SS-304 substrate has significantly enhanced due to the strengthened wear resistance and hardness of the coatings. Findings have exhibited that the formation of (Fe, Co, Ni, Mn, Cu)3O4 phase is a potential coating material for "SOFC interconnects" applications. Moreover, the cladding of SS304 with a composition of 20% Fe, 20% Co, 20% Ni, 20% Mn, and 20% Cu has demonstrated remarkable stability under thermal expansion studies. As the findings have revealed that the composite cladding has efficiently withstand significant variations in volume when subjected to elevated temperatures for a prolonged period of time, thus, exhibiting its superior thermal stability for SOFC-interconnect applications. Furthermore, the SEM images of the cladding surface, surface hardness, and tribocorrosion behavior of the coated material have been observed to identify the 20% Fe 20% Co 20% Ni 20% Mn 20% Cu HEA coating effect on SS-304 steel-substrate.

15.
Materials (Basel) ; 17(6)2024 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-38541419

RESUMO

The initial melting quality of a high-speed laser cladding layer has an important impact on its post-treatment and practical application. In this study, based on the repair of hydraulic support columns of coal mining machines, the influence of high-speed laser cladding process parameters on the quality of Fe-Cr-Ni alloy coatings was investigated to realize the accurate prediction of coating quality. The Taguchi orthogonal method was used to design the L25(56) test. The prediction models of the relationship between the cladding process and the coating quality were established using the Random Forest (RF) and AdaBoost (Adaptive Boosting, AB) algorithms, respectively. Then, the prediction accuracy of the two models was compared, and the process parameter features were screened for importance evaluation. The results show that the AB prediction model is more accurate than the RF prediction model and more sensitive to abnormal data. The importance evaluation based on the AdaBoost model shows that the scanning speed has a great influence on the height and surface roughness of the coating. On the other hand, the overlap rate is the most important factor in controlling the dilution ratio and near-surface grain size of high-speed laser melting coatings. In addition, the micro-hardness of the coating and the thermal effect of the substrate can be effectively enhanced by adjusting the laser power and scanning speed. Finally, it was verified that the AB prediction model could accurately estimate the quality indexes of the coating with a prediction error less than 6%. The results show that it is feasible to predict the quality of high-speed laser cladding with the AB algorithm. It provides a basis for the adjustment of process parameters in the subsequent quality control process of cladding.

16.
Materials (Basel) ; 17(4)2024 Feb 16.
Artigo em Inglês | MEDLINE | ID: mdl-38399161

RESUMO

With the rapid development of the advanced manufacturing industry, equipment requirements are becoming increasingly stringent. Since metallic materials often present failure problems resulting from wear due to extreme service conditions, researchers have developed various methods to improve their properties. Laser shock peening (LSP) is a highly efficacious mechanical surface modification technique utilized to enhance the microstructure of the near-surface layer of metallic materials, which improves mechanical properties such as wear resistance and solves failure problems. In this work, we summarize the fundamental principles of LSP and laser-induced plasma shock waves, along with the development of this technique. In addition, exemplary cases of LSP treatment used for wear resistance improvement in metallic materials of various nature, including conventional metallic materials, laser additively manufactured parts, and laser cladding coatings, are outlined in detail. We further discuss the mechanism by which the microhardness enhancement, grain refinement, and beneficial residual stress are imparted to metallic materials by using LSP treatment, resulting in a significant improvement in wear resistance. This work serves as an important reference for researchers to further explore the fundamentals and the metallic material wear resistance enhancement mechanism of LSP.

17.
Entropy (Basel) ; 26(1)2024 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-38248198

RESUMO

The extremely harsh environment of the high temperature plasma imposes strict requirements on the construction materials of the first wall in a fusion reactor. In this work, a refractory alloy system, WTaVTiZrx, with low activation and high entropy, was theoretically designed based on semi-empirical formula and produced using a laser cladding method. The effects of Zr proportions on the metallographic microstructure, phase composition, and alloy chemistry of a high-entropy alloy cladding layer were investigated using a metallographic microscope, XRD (X-ray diffraction), SEM (scanning electron microscope), and EDS (energy dispersive spectrometer), respectively. The high-entropy alloys have a single-phase BCC structure, and the cladding layers exhibit a typical dendritic microstructure feature. The evolution of microstructure and mechanical properties of the high-entropy alloys, with respect to annealing temperature, was studied to reveal the performance stability of the alloy at a high temperature. The microstructure of the annealed samples at 900 °C for 5-10 h did not show significant changes compared to the as-cast samples, and the microhardness increased to 988.52 HV, which was higher than that of the as-cast samples (725.08 HV). When annealed at 1100 °C for 5 h, the microstructure remained unchanged, and the microhardness increased. However, after annealing for 10 h, black substances appeared in the microstructure, and the microhardness decreased, but it was still higher than the matrix. When annealed at 1200 °C for 5-10 h, the microhardness did not increase significantly compared to the as-cast samples, and after annealing for 10 h, the microhardness was even lower than that of the as-cast samples. The phase of the high entropy alloy did not change significantly after high-temperature annealing, indicating good phase stability at high temperatures. After annealing for 10 h, the microhardness was lower than that of the as-cast samples. The phase of the high entropy alloy remained unchanged after high-temperature annealing, demonstrating good phase stability at high temperatures.

18.
Materials (Basel) ; 17(1)2024 Jan 04.
Artigo em Inglês | MEDLINE | ID: mdl-38204116

RESUMO

In this paper, Ni60/WC wear-resistant coatings have been created on the Ti6Al4V substrate surface using a pre-layered powder laser cladding method by deploying various scanning speeds of 8, 10, 12, and 14 mm/s. The coatings are characterized through X-ray diffraction (XRD), scanning electron microscopy (SEM), and a high-speed reciprocating fatigue wear tester. It is found that the phase composition of the coating comprises the synthesized, hard phase TiC and TiB2, the silicides WSi2 and W5Si3, and NiTi and γ-Ni solid solutions. At different scanning speeds, there is a metallurgical fusion line in the bonding area of the fused cladding layer, indicating a good metallurgical bonding between the substrate and the powder. At a low scanning speed, the coating develops into coarse dendrites, which shows significant improvement with scanning speed. The microhardness first increases and then decreases with the scanning speed, and the coating's average microhardness was 2.75-3.13 times higher than that of the substrate. The amount of mass wear has been reduced by 60.1-79.7% compared to the substrate. The wear behavior of the coatings was studied through detailed analysis of wear surfaces' microstructures and the amount of wear to identify the optimum scanning speed.

19.
Heliyon ; 10(2): e24494, 2024 Jan 30.
Artigo em Inglês | MEDLINE | ID: mdl-38293472

RESUMO

In this study, Ni60-WCx coatings (x = 0, 2, 4, 6 %) on 316L stainless steel (316Lss) were prepared via laser cladding technology. We examined all specimens s for microstructure, phase composition, microhardness and electrochemistry using several characterization techniques. It shows that the microstructure of the Ni-based coatings can be changed with WC powder. When the WC ratio is 2 %, crystalline crystals and cellular crystals can be found in the coating. As the WC ratio increases, more cellular crystals and fewer spiny crystals appear in the coating. When the WC ratio changes to 6 %, only cellular crystals can be found in the coating. The microhardness resultsshow that the Ni-based overcoat with added WC has a better microhardness compared to the pure Ni coating, and its average value of the coating area reaches a maximum value of 822.8 HV at a WC ratio of 2 %. That is due to the addition of WC which can cause regime transition. In addition, the Ni-based coating has better corrosion properties due to its different microstructure. When the WC ratio is 2 %, the specimen possesses the maximum Ecorr and smaller icorr with the best corrosion resistance.

20.
Materials (Basel) ; 17(2)2024 Jan 12.
Artigo em Inglês | MEDLINE | ID: mdl-38255567

RESUMO

The preheating of the substrate in laser additive superalloys can reduce residual stress and minimize cracking. However, this preheating process can lead to changes in the heat transfer conditions, ultimately affecting the resulting microstructure and mechanical properties. In order to explore the influence of substrate preheating on the formation of laser cladding, this research focuses on investigating the characteristics of Inconel 718, a nickel-based superalloy, as the subject of study. To simulate the temperature and flow field of laser cladding, a 3D computational fluid dynamics (CFD) model is employed. By varying the initial preheating conditions, an investigation is conducted into the distribution of the temperature field under different parameters. This leads to the acquisition of varying temperature gradients, G, and solidification speeds, R. Subsequently, an analysis is carried out on both the flow field and solidification microstructure in the melt pool. The results demonstrate that the preheating of the substrate results in a slower cooling rate, ultimately leading to the formation of a coarser microstructure.

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