Combined electrocoagulation and electrooxidation treatment system for real effluents from the fishing industry.

Fishing industries are characterized by high water consumption and a considerable content of organic matter and salt in their wastewater. In this work, a combined electrochemical process was studied at laboratory scale for the treatment of real wastewater from the processing of mackerel from an industrial facility located in the province of Buenos Aires that discharges to the sewer, which the plant is currently using and does not produce an effluent in discharge conditions. Taking advantage of the high conductivity of these effluents, in the electrocoagulation stage with aluminum anodes, it was possible to remove the coarsest fraction of suspended matter, achieving a Chemical Oxygen Demand (COD) removal of about 60%, at pH 7.5, showing a higher efficiency over the conventional treatment. Despite this superiority, the necessary removal was still not achieved; therefore, the wastewater treated by electrocoagulation was then subjected to electrooxidation, using a graphite anode and a titanium cathode, and with a first-order oxidation kinetics, achieving a final COD value lower than the discharge limit, after 7.5 min of processing at pH 6, obtaining an efficient treatment for removal of high concentrations dissolved organic matter and colloidal/suspended particles in this kind of effluent. All treatments were performed in batches. The removal of pollutants in the wastewater was verified by means of spectroscopic and voltammetric techniques; at the same time, these techniques, together with SEM-EDX analysis, proved the superiority of electrocoagulation over chemical coagulation. This study laid the groundwork for the design of modifications to the plant to achieve discharge parameters in accordance with current legislation.

Recent advances on modified reticulated vitreous carbon for water and wastewater treatment - A mini-review.

Recently, modifications on reticulated vitreous carbon (RVC) have attracted attention as a promising strategy to produce low-cost, stable, and highly active electrodes leading to significant advances in the water/wastewater treatment field compared with raw RVC. Modified RVC materials have been used as cathode, anode, and membrane. Improvements on physical and electrocatalytic properties are achieved by RVC modification via diverse strategies, including the deposition of metal oxides, the introduction of surface functional groups, and the formation of composites, which were used to remove organic contaminants and pathogens from water matrices, as summarized in this mini-review. This mini-review mainly focused on papers published from 2015 to 2020 that reported modified RVC electrodes to eliminate pollutants and pathogens from water matrices by electrochemical advanced oxidation processes. Likewise, news challenges and opportunities are discussed, and perspectives for the ongoing and future studies in this research field are also given.

Emerging pollutant treatments in wastewater: Cases of antibiotics and hormones.

Because of the intensive use of pharmaceutical substances in human life, studies on the detection of these chemical compounds and their metabolites as pollutants in water bodies are continuously reported. Some pharmaceutical agents are associated with adverse effects to aquatic life, even at very low concentrations (ng L-1 to µg L-1). For instance, the presence of antibiotics and hormones has been associated with increasing proliferation of antibiotic resistant pathogens and feminization and masculinization of some aquatic organisms. Currently, new attempts are being made to minimize or fully remove these types of pollutants from aquatic systems to protect the environment and human health. In this regard, physicochemical and biological treatments are among the most promising technologies for the treatment of wastewater containing pharmaceutical pollutants. These treatments are green alternatives for the degradation of hazardous organic compounds into nontoxic by-products. Here, we review some of the physicochemical and biological treatment methods used for the removal of the most extensively used antibiotics and hormones. Enzymatic oxidation, photocatalysis and electrochemical oxidation are described in terms of the aforementioned pharmaceutically active compounds (PhACs). The use of membrane technologies to separate different groups of antibiotics and hormones prior to biologic or physicochemical treatment methods is also addressed.