Phosphate limitation enhances malic acid production on nitrogen-rich molasses with Ustilago trichophora.

BACKGROUND: An important step in replacing petrochemical products with sustainable, cost-effective alternatives is the use of feedstocks other than, e.g., pure glucose in the fermentative production of platform chemicals. Ustilaginaceae offer the advantages of a wide substrate spectrum and naturally produce a versatile range of value-added compounds under nitrogen limitation. A promising candidate is the dicarboxylic acid malic acid, which may be applied as an acidulant in the food industry, a chelating agent in pharmaceuticals, or in biobased polymer production. However, fermentable residue streams from the food and agricultural industry with high nitrogen content, e.g., sugar beet molasses, are unsuited for processes with Ustilaginaceae, as they result in low product yields due to high biomass and low product formation. RESULTS: This study uncovers challenges in evaluating complex feedstock applicability for microbial production processes, highlighting the role of secondary substrate limitations, internal storage molecules, and incomplete assimilation of these substrates. A microliter-scale screening method with online monitoring of microbial respiration was developed using malic acid production with Ustilago trichophora on molasses as an application example. Investigation into nitrogen, phosphate, sulphate, and magnesium limitations on a defined minimal medium demonstrated successful malic acid production under nitrogen and phosphate limitation. Furthermore, a reduction of nitrogen and phosphate in the elemental composition of U. trichophora was revealed under the respective secondary substrate limitation. These adaptive changes in combination with the intricate metabolic response hinder mathematical prediction of product formation and make the presented screening methodology for complex feedstocks imperative. In the next step, the screening was transferred to a molasses-based complex medium. It was determined that the organism assimilated only 25% and 50% of the elemental nitrogen and phosphorus present in molasses, respectively. Due to the overall low content of bioavailable phosphorus in molasses, the replacement of the state-of-the-art nitrogen limitation was shown to increase malic acid production by 65%. CONCLUSION: The identification of phosphate as a superior secondary substrate limitation for enhanced malic acid production opens up new opportunities for the effective utilization of molasses as a more sustainable and cost-effective substrate than, e.g., pure glucose for biobased platform chemical production.

A sustainable and economical solution for CO2 capture with biobased carbon materials derived from palm kernel shells.

This study investigates the synthesize of activated carbon for carbon dioxide adsorption using palm kernel shell (PKS), a by-product of oil palm industry. The adsorbent synthesis involved a simple two-step carbonization method. Firstly, PKS was activated with potassium oxide (KOH), followed by functionalization with magnesium oxide (MgO). Surface analysis revealed that KOH activated PKS has resulted in a high specific surface area of 1086 m2/g compared to untreated PKS (435 m2/g). However, impregnation of MgO resulted in the reduction of surface area due to blockage of pores by MgO. Thermogravimetric analysis (TGA) demonstrated that PKS-based adsorbents exhibited minimal weight loss of less than 30% up to 500 °C, indicating their suitability for high-temperature applications. CO2 adsorption experiments revealed that PKS-AC-MgO has achieved a higher adsorption capacity of 155.35 mg/g compared to PKS-AC (149.63 mg/g) at 25 °C and 5 bars. The adsorption behaviour of PKS-AC-MgO was well fitted by both the Sips and Langmuir isotherms, suggesting a combination of both heterogeneous and homogeneous adsorption and indicating a chemical reaction between MgO and CO2. Thermodynamic analysis indicated a spontaneous and thermodynamically favourable process for CO2 capture by PKS-AC-MgO, with negative change in enthalpy (- 0.21 kJ/mol), positive change in entropy (2.44 kJ/mol), and negative change in Gibbs free energy (- 729.61 J/mol, - 790.79 J/mol, and - 851.98 J/mol) across tested temperature. Economic assessment revealed that the cost of PKS-AC-MgO is 21% lower than the current market price of commercial activated carbon, indicating its potential for industrial application. Environmental assessment shows a significant reduction in greenhouse gas emissions (381.9 tCO2) through the utilization of PKS-AC-MgO, underscoring its environmental benefits. In summary, the use of activated carbon produced from PKS and functionalised with MgO shows great potential for absorbing CO2. This aligns with the ideas of a circular economy and sustainable development.

A method to assess the quality of additive manufacturing metal powders using the triboelectric charging concept.

A new method to assess the quality of additive manufacturing (AM) metal powders using the triboelectric charging concept is demonstrated using CpTi, Ti6Al4V, AlSi10Mg, IN 738, and SS 316L powders. For each powder tested, the surface chemical composition was first analyzed using X-ray photoelectron spectroscopy (XPS) to determine the composition of the passivation layer. Some modifications to the current GranuCharge™ setup, developed by GranuTools™, were then performed by incorporating a flow rate measuring tool to assess how tribocharging is affected as a function of flow rate. Variations in the tribocharging response have been found with the flow rate of CpTi, AlSi10Mg and SS 316L powders. Moreover, results suggest that the tribocharging behavior might not be the same even with powders fabricated with the same passivation process. Finally, the compressed exponential model of Trachenko and Zaccone was used to reproduce the tribocharging behavior of the powders. The models were found to work best when the stretch constant ß = 1.5, which is identical to the value found in other systems such as structural glasses, colloidal gels, entangled polymers, and supercooled liquids, which experience jamming when motion of individual particles become restricted, causing their motion to slow down.

Spatially Varying Costs of GHG Abatement with Alternative Cellulosic Feedstocks for Sustainable Aviation Fuels.

Cellulosic biomass-based sustainable aviation fuels (SAFs) can be produced from various feedstocks. The breakeven price and carbon intensity of these feedstock-to-SAF pathways are likely to differ across feedstocks and across spatial locations due to differences in feedstock attributes, productivity, opportunity costs of land for feedstock production, soil carbon effects, and feedstock composition. We integrate feedstock to fuel supply chain economics and life-cycle carbon accounting using the same system boundary to quantify and compare the spatially varying greenhouse gas (GHG) intensities and costs of GHG abatement with SAFs derived from four feedstocks (switchgrass, miscanthus, energy sorghum, and corn stover) at 4 km resolution across the U.S. rainfed region. We show that the optimal feedstock for each location differs depending on whether the incentive is to lower breakeven price, carbon intensity, or cost of carbon abatement with biomass or to have high biomass production per unit land. The cost of abating GHG emissions with SAF ranges from $181 Mg-1 CO2e to more than $444 Mg-1 CO2e and is lowest with miscanthus in the Midwest, switchgrass in the south, and energy sorghum in a relatively small region in the Great Plains. While corn stover-based SAF has the lowest breakeven price per gallon, it has the highest cost of abatement due to its relatively high GHG intensity. Our findings imply that different types of policies, such as volumetric targets, tax credits, and low carbon fuel standards, will differ in the mix of feedstocks they incentivize and locations where they are produced in the U.S. rainfed region.

A Solar to Chemical Strategy: Green Hydrogen as a Means, Not an End.

Green hydrogen is the key to the chemical industry achieving net zero emissions. The chemical industry is responsible for almost 2% of all CO2 emissions, with half of it coming from the production of simple commodity chemicals, such as NH3, H2O2, methanol, and aniline. Despite electrolysis driven by renewable power sources emerging as the most promising way to supply all the green hydrogen required in the production chain of these chemicals, in this review, it is worth noting that the photocatalytic route may be underestimated and can hold a bright future for this topic. In fact, the production of H2 by photocatalysis still faces important challenges in terms of activity, engineering, and economic feasibility. However, photocatalytic systems can be tailored to directly convert sunlight and water (or other renewable proton sources) directly into chemicals, enabling a solar-to-chemical strategy. Here, a series of recent examples are presented, demonstrating that photocatalysis can be successfully employed to produce the most important commodity chemicals, especially on NH3, H2O2, and chemicals produced by reduction reactions. The replacement of fossil-derived H2 in the synthesis of these chemicals can be disruptive, essentially safeguarding the transition of the chemical industry to a low-carbon economy.

Catalyst-Enhancing Hydrothermal Carbonization of Biomass for Hydrochar and Liquid Fuel Production-A Review.

The research impact of catalysts on the hydrothermal carbonization (HTC) process remains an ongoing debate, especially regarding the quest to enhance biomass conversion into fuels and chemicals, which requires diverse catalysts to optimize bio-oil utilization. Comprehensive insights and standardized analytical methodologies are crucial for understanding HTC's potential benefits in terms of biomass conversion stages. This review seeks to understand how catalysts enhance the HTC of biomass for liquid fuel and hydrochar production, drawing from the following key sections: (a) catalyst types applied in HTC processes; (b) biochar functionality as a potential catalyst; (c) catalysts increasing the success of HTC process; and (d) catalyst's effect on the morphological and textural character of hydrochar. The performance of activated carbon would greatly increase via catalyst action, which would progress the degree of carbonization and surface modification, alongside key heteroatoms. As catalytic HTC technology advances, producing carbon materials for thermochemical activities will become more cost-effective, considering the ever-growing demands for high-performance thermochemical technologies.

The feedstock anatomical properties determine biochar adsorption capacities: A study using woody bamboos (Bambuseae) and methylene blue as a model molecule.

Feedstock characteristics impact biochar physicochemical properties, and reproducible biochar properties are essential for any potential application. However, in most articles, feedstock aspects (i.e., taxonomic name of the species, part of the plant, and phenological phase) are scarcely reported. This research aimed at studying the effect of species and phenological stage of the feedstock on the properties of the derived biochars and, thus, adsorption capacities in water treatment. In this study, we analysed the anatomical characteristics of three different woody bamboo species [Guadua chacoensis (GC), Phyllostachys aurea (PA), and Bambusa tuldoides (BT)] in culms harvested at two different phenological phases (young and mature), and statistically correlated them with the characteristics of the six derived biochars, including their adsorption performance in aqueous media. Sclerenchyma fibres and parenchyma cells diameter and cell-wall width significantly differed among species. Additionally, sclerenchyma fibres and parenchyma cell-wall width as well as sclerenchyma fibre cell diameters are dependent on the phenological phase of the culms. Consequently, differences in biochar characteristics (i.e., yield and average pore diameter) were also observed, leading to differential methylene blue (MB) adsorption capacities between individuals at different phenological phases. MB adsorption capacities were higher for biochar produced from young culms compared to those obtained from matures ones (i.e., GC: 628.66 vs. 507.79; BT: 537.45 vs. 477.53; PA: 477.52 vs. 462.82 mg/g), which had smaller cell wall widths leading to a lower percentage of biochar yield. The feedstock anatomical properties determined biochar characteristics which modulated adsorption capacities.

Survival of biomass and waste power generation: A global overview.

Biomass and waste power generation holds the promise to secure electricity supply for a growing population and mitigate global warming simultaneously. Along with the increasing commission and installation of biomass/waste power units (BWPUs) across the globe, some BWPUs failures have been observed, including the cancellation of planned/commissioned BWPUs and the termination of those in operation before reaching their natural retirement. While empirical evidence suggests that factors like feedstock accessibility and policy instruments might affect the feasibility and performance of BWPUs, there is a lack of comprehensive investigation about why some BWPUs failed at the global scale. To fill this knowledge gap, this study quantifies the hazard ratio of BWPUs via a parametric survival analysis using a panel dataset covering a total of 12,829 BWPUs (relying on woody, non-woody, and waste biomass as raw feedstocks) located in 164 countries/regions worldwide for the period of 2001-2021. The analytical results suggest that large unit size is conducive to BWPUs failure, while feedstock accessibility and the implementation of policy instruments (including Feed-in-Tariff and carbon pricing) could largely reduce the hazard ratio of BWPUs, with varying impacts on BWPUs at the planned/commissioned stage or the operation stage, located in developed or developing countries. Our findings not only shed additional light on the fate of BWPUs, which is crucial to enriching our understanding about the development of the bioenergy sector worldwide, but also provide salient empirical evidence for policy-making in terms of ensuring feedstock accessibility, overcoming diseconomies of scale, and making fiscal instruments available and transparent to boost the confidence of investors and entrepreneurs in support of BWPUs development.

Robust, fully quantifiable and scalable bioprocess utilizing spent sulfite liquor with Corynebacterium glutamicum.

In this study, a bioprocessing strategy was designed to valorize ultra-filtered spent sulfite liquor (UF-SSL) without prior detoxification steps as well as using it purely as a carbon source supplement to defined or complex media. Hence, a minimal medium for the bioconversion of UF-SSL with Corynebacterium glutamicum was developed and process robustness and reproducibility were validated. Process quantifiability was ensured by development of a biomass measurement technique for matrices with high water-insoluble solids and verified using elemental balancing. Mechanistic modeling based on Monod equations was used to identify batch kinetics. In a final step, scale-up of the developed process was performed to showcase process maturity towards commercialisation.

Bacterial isolate collection from switchgrass rhizosphere.

We provide a collection of 78 bacterial isolates from the rhizosphere of switchgrass (Panicum virgatum L.) at the Lux Arbor Reserve in Delton, MI, a site of the Great Lakes Bioenergy Research Center (GLBRC), Michigan State University, MI, USA. We include information on isolation conditions and full-length 16S rRNA sequences.

Physicochemical properties and performance of non-woody derived biochars for the sustainable removal of aquatic pollutants: A systematic review.

Biochar is a carbon-rich material produced from the partial combustion of different biomass residues. It can be used as a promising material for adsorbing pollutants from soil and water and promoting environmental sustainability. Extensive research has been conducted on biochars prepared from different feedstocks used for pollutant removal. However, a comprehensive review of biochar derived from non-woody feedstocks (NWF) and its physiochemical attributes, adsorption capacities, and performance in removing heavy metals, antibiotics, and organic pollutants from water systems needs to be included. This review revealed that the biochars derived from NWF and their adsorption efficiency varied greatly according to pyrolysis temperatures. However, biochars (NWF) pyrolyzed at higher temperatures (400-800 °C) manifested excellent physiochemical and structural attributes as well as significant removal effectiveness against antibiotics, heavy metals, and organic compounds from contaminated water. This review further highlighted why biochars prepared from NWF are most valuable/beneficial for water treatment. What preparatory conditions (pyrolysis temperature, residence time, heating rate, and gas flow rate) are necessary to design a desirable biochar containing superior physiochemical and structural properties, and adsorption efficiency for aquatic pollutants? The findings of this review will provide new research directions in the field of water decontamination through the application of NWF-derived adsorbents.

O/S Exchange Reaction in Synthesizing Sulfur-Containing Polymers.

Using carbon disulfide (CS2) and carbonyl sulfide (COS) as sulfur-containing and one-carbon feedstocks to make value-added products is paramount for both pure and applied chemistry and environmental science. One of the practical strategies is to copolymerize these bulk chemicals with epoxides to produce sulfur-containing polymers. This approach contributes to improving the sustainability of polymer manufacturing, provides highly desired functional polymer materials, and has attracted much attention. However, these copolymerizations invariably exhibit the intensely complicated chemistry of O/S exchange reaction, leading to sulfur-containing polymers with diverse architectures. As the understanding of O/S exchange continues to deepen, recent efforts have guided significant advances in the synthesis of CS2- and COS-based polymers. This review examines the O/S exchange chemistry and summarizes the recent progress in this field to promote the further advance of synthesizing sulfur-containing polymers from CS2 and COS.

A comprehensive review on anaerobic digestion with focus on potential feedstocks, limitations associated and recent advances for biogas production.

With the escalating energy demand to accommodate the growing population and its needs along with the responsibility to mitigate climate change and its consequences, anaerobic digestion (AD) has become the potential approach to sustainably fulfil our demands and tackle environmental issues. Notably, a lot of attention has been drawn in recent years towards the production of biogas around the world in waste-to-energy perspective. Nevertheless, the progress of AD is hindered by several factors such as operating parameters, designing and the performance of AD reactors. Furthermore, the full potential of this approach is not fully realised yet due the dependence on people's acceptance and government policies. This article focuses on the different types of feedstocks and their biogas production potential. The feedstock selection is the basic and most important step for accessing the biogas yield. Furthermore, different stages of the AD process, design and the configuration of the biogas digester/reactors have been discussed to get better insight into process. The important aspect to talk about this process is its limitations associated which have been focused upon in detail. Biogas is considered to attain the sustainable development goals (SDG) proposed by United Nations. Therefore, the huge focus should be drawn towards its improvements to counter the limitation and makes it available to all the rural communities in developing countries and set-up the pilot scale AD plants in both developing and developed countries. In this regard, this article talks about the improvements and futures perspective related to the AD process and biogas enhancement.

Liming potential and characteristics of biochar produced from woody and non-woody biomass at different pyrolysis temperatures.

Large amount of wastes are burnt or left to decompose on site or at landfills where they cause air pollution and nutrient leaching to groundwater. Waste management strategies that return these food wastes to agricultural soils recover the carbon and nutrients that would otherwise have been lost, enrich soils and improve crop productivity. The incorporation of liming materials can neutralize the protons released, hence reducing soil acidity and its adverse impacts to the soil environment, food security, and human health. Biochar derived from organic residues is becoming a source of carbon input to soil and provides multifunctional values. Biochar can be alkaline in nature, with the level of alkalinity dependent upon the feedstock and processing conditions. This study conducted a characterization of biochar derived from the pyrolysis process of eggplant and Acacia nilotica bark at temperatures of 300 °C and 600 °C. An analysis was conducted on the biochar kinds to determine their pH, phosphorus (P), as well as other elemental composition. The proximate analysis was conducted by the ASTM standard 1762-84, while the surface morphological features were measured using a scanning electron microscope. The biochar derived from Acacia nilotica bark exhibited a greater yield and higher level of fixed carbon while possessing a lower content of ash and volatile components compared to biochar derived from eggplant. The eggplant biochar exhibits a higher liming ability at 600 °C compared to the acacia nilotica bark-derived biochar. The calcium carbonate equivalent, pH, potassium (K), and phosphorus (P) levels in eggplant biochars increased as the pyrolysis temperature increased. The results suggest that biochar derived from eggplant could be a beneficial resource for storing carbon in the soil, as well as for addressing soil acidity and enhancing nutrients availability, particularly potassium and phosphorus in acidic soils.

Biodiesel production and characteristics from waste frying oils: sources, challenges, and circular economic perspective.

Biodiesel serves as a viable alternative to traditional diesel due to its non-toxicity, biodegradability, and lower environmental footprint. Among the diverse edible and inedible feedstocks, waste frying oil emerges as a promising and affordable feedstock for biodiesel production. Commonly waste frying oils include those derived from palm, corn, sunflower, soybean, rapeseed, and canola. The primary challenge related to biodiesel production technologies is the high production cost, which poses a significant barrier to its widespread adoption. Thus, refining the production techniques is essential to enhance yield, reduce capital expenditure, and curtail raw material expenses. An examination of the research focusing on feedstock availability, production, hurdles, operational expenditures, and future potential is pivotal for identifying the most economically and technically viable solutions. This paper critically reviews such research by exploring feedstock availability, production techniques, challenges, and costs intrinsic to biodiesel synthesis. It also underscores the economic feasibility of biodiesel production, shedding light on the pivotal factors that influence profitability, especially when leveraging waste frying oils. Through an in-depth understanding of these considerations, optimal production and feedstock choices for biodiesel production can be identified. Addressing cost and production bottlenecks could potentially enhance the economic viability of waste frying oil-based biodiesel, thus fostering both environmental sustainability and more extensive adoption of biodiesel as an environmental-friendly fuel in the future.

Critical methods of geopolymer feedstocks activation for suitable industrial applications.

As health and safety issues emanating from human activities on terrestrial environment is becoming ever challenging, the production of Ordinary Portland Cement is identified as a key contributor. This technology threatens environmental quality by emitting significant quantity of carbon dioxide (CO2) that threatens Net Zero delivery. Consequently, the development of cement alternatives with substantial CO2 reduction/sequestration during production has become imperative. Geopolymers obtained from industrial residues are poised as promising alternatives in managing environmental systems but selection of appropriate method of activation has limited their wider industrial applications. This article discusses four key activation methods and their combinations used in four main feedstocks to advise on their energy requirements, product compressive strength and environmental/industrial applications. Reviewing and characterising 302 published literatures with focus on most relevant and recent advances in the field, this review found that hybrid techniques combining mechanical activation method produces geopolymers with the highest compressive strength and thus the best method. Geopolymer made by mechano-chemical activation method of slag achieved the highest compressive strength while geopolymer produced by microwave assisted activation of clay and ultrasonic activation of fly ash cum slag are most economical in curing energy demand. Hybrid activation is the current development in the field and integration of this method with mechanical activation is poised as the future geopolymer activation technology as it demonstrates greatest efficiency potential.

Navigating Pyrolysis Implementation-A Tutorial Review on Consideration Factors and Thermochemical Operating Methods for Biomass Conversion.

Pyrolysis and related thermal conversion processes have shown increased research momentum in recent decades. Understanding the underlying thermal conversion process principles alongside the associated/exhibited operational challenges that are specific to biomass types is crucial for beginners in this research area. From an extensive literature search, the authors are convinced that a tutorial review that guides beginners particularly towards pyrolysis implementation, from different biomasses to the thermal conversion process and conditions, is scarce. An effective understanding of pre-to-main pyrolysis stages, alongside corresponding standard methodologies, would help beginners discuss anticipated results. To support the existing information, therefore, this review sought to seek how to navigate pyrolysis implementation, specifically considering factors and thermochemical operating methods for biomass conversion, drawing the ideas from: (a) the evolving nature of the thermal conversion process; (b) the potential inter-relatedness between individual components affecting pyrolysis-based research; (c) pre- to post-pyrolysis' engagement strategies; (d) potential feedstock employed in the thermal conversion processes; (e) the major pre-treatment strategies applied to feedstocks; (f) system performance considerations between pyrolysis reactors; and (g) differentiating between the reactor and operation parameters involved in the thermal conversion processes. Moreover, pre-pyrolysis activity tackles biomass selection/analytical measurements, whereas the main pyrolysis activity tackles treatment methods, reactor types, operating processes, and the eventual product output. Other areas that need beginners' attention include high-pressure process reactor design strategies and material types that have a greater potential for biomass.

Renewable Energy Potential: Second-Generation Biomass as Feedstock for Bioethanol Production.

Biofuels are clean and renewable energy resources gaining increased attention as a potential replacement for non-renewable petroleum-based fuels. They are derived from biomass that could either be animal-based or belong to any of the three generations of plant biomass (agricultural crops, lignocellulosic materials, or algae). Over 130 studies including experimental research, case studies, literature reviews, and website publications related to bioethanol production were evaluated; different methods and techniques have been tested by scientists and researchers in this field, and the most optimal conditions have been adopted for the generation of biofuels from biomass. This has ultimately led to a subsequent scale-up of procedures and the establishment of pilot, demo, and large-scale plants/biorefineries in some regions of the world. Nevertheless, there are still challenges associated with the production of bioethanol from lignocellulosic biomass, such as recalcitrance of the cell wall, multiple pretreatment steps, prolonged hydrolysis time, degradation product formation, cost, etc., which have impeded the implementation of its large-scale production, which needs to be addressed. This review gives an overview of biomass and bioenergy, the structure and composition of lignocellulosic biomass, biofuel classification, bioethanol as an energy source, bioethanol production processes, different pretreatment and hydrolysis techniques, inhibitory product formation, fermentation strategies/process, the microorganisms used for fermentation, distillation, legislation in support of advanced biofuel, and industrial projects on advanced bioethanol. The ultimate objective is still to find the best conditions and technology possible to sustainably and inexpensively produce a high bioethanol yield.

An Overview of the Non-Energetic Valorization Possibilities of Plastic Waste via Thermochemical Processes.

The recovery and recycling/upcycling of plastics and polymer-based materials is needed in order to reduce plastic waste accumulated over decades. Mechanical recycling processes have made a great contribution to the circularity of plastic materials, contributing to 99% of recycled thermoplastics. Challenges facing this family of processes limit its outreach to 30% of plastic waste. Complementary pathways are needed to increase recycling rates. Chemical processes have the advantage of decomposing plastics into a variety of hydrocarbons that can cover a wide range of applications, such as monomers, lubricants, phase change materials, solvents, BTX (benzene, toluene, xylene), etc. The aim of the present work is to shed light on different chemical recycling pathways, with a special focus on thermochemicals. The study will cover the effects of feedstock, operating conditions, and processes used on the final products. Then, it will attempt to correlate these final products to some petrochemical feedstock being used today on a large scale.

Enhancing biomass conversion to bioenergy with machine learning: Gains and problems.

The growing concerns about environmental sustainability and energy security, such as exhaustion of traditional fossil fuels and global carbon footprint growth have led to an increasing interest in alternative energy sources, especially bioenergy. Recently, numerous scenarios have been proposed regarding the use of bioenergy from different sources in the future energy systems. In this regard, one of the biggest challenges for scientists is managing, modeling, decision-making, and future forecasting of bioenergy systems. The development of machine learning (ML) techniques can provide new opportunities for modeling, optimizing and managing the production, consumption and environmental effects of bioenergy. However, researchers in bioenergy fields have not widely utilized the ML concepts and practices. Therefore, a comparative review of the current ML techniques used for bioenergy productions is presented in this paper. This review summarizes the common issues and difficulties existing in integrating ML with bioenergy studies, and discusses and proposes the possible solutions. Additionally, a detailed discussion of the appropriate ML application scenarios is also conducted in every sector of the entire bioenergy chain. This indicates the modernized conversion processes supported by ML techniques are imperative to accurately capture process-level subtleties, and thus improving techno-economic resilience and socio-ecological integrity of bioenergy production. All the efforts are believed to help in sustainable bioenergy production with ML technologies for the future.