Chlorinated organic pollutants in global flooded soil and sediments: Pollution status and potential risk.

Chlorinated organic pollutants (COPs) were widely detected in anaerobic environments while there is limited understanding of their pollution status and potential environmental risks. Here, we applied meta-analysis to identify the occurrence status, pollution sources, and environmental risk of COPs from 246 peer-published literature, including 25 kinds of COPs from 977 sites. The results showed that the median concentrations of COPs were at the ng g-1 level. By the combination of principal component analysis (PCA) and positive matrix factorization (PMF), we established 7 pollution sources for COPs. Environmental risk assessment found 73.3% of selected sites were at a security level but the rest were not, especially for the wetlands. The environmental risk of COPs was usually underestimated by the existing evaluation methods, such as without the consideration of the non-extractable residues (NER) and the multi-process coupling effect. Especially, the synergetic coupling associations between dechlorination and methanogenesis might increase the risk of methane emission that has barely been previously considered in previous risk assessment approaches. Our results expanded the knowledge for the pollution control and remediation of COPs in anaerobic environments.

Teor de vitamina C, β-caroteno e minerais em camu-camu cultivado em diferentes ambientes / Levels of vitamin C, β-carotene and minerals in camu-camu cultivated in different environments

RESUMO: O objetivo deste trabalho foi avaliar a influência do tipo de cultivo (ambiente seco e alagado) sobre o teor de vitamina C, β-caroteno e minerais (cálcio, magnésio, enxofre, zinco, ferro, manganês, cobre, boro, nitrogênio, fósforo e potássio) de camu-camu. As vitaminas citadas foram determinadas por cromatografia líquida de alta eficiência, enquanto que os minerais cálcio, magnésio, zinco, cobre, manganês e ferro por espectrometria de absorção atômica, o potássio por fotometria de chama e o fósforo, boro e enxofre por espectrofotometria, nos comprimentos de onda 725 e 420nm, respectivamente. O fruto cultivado em ambiente seco apresentou maior (P<0,05) teor de vitamina C (13.756,79mg 100g1/peso seco) e da maioria dos minerais investigados (cálcio, magnésio, enxofre, ferro, cobre, nitrogênio, fósforo e potássio). Os teores de β-caroteno não variaram (P>0,05) em função dos diferentes ambientes.

ABSTRACT: The aim of this study was to evaluate the influence of crop type (dry and flooded environment) on vitamin C, β-carotene and minerals (calcium, magnesium, sulfur, zinc, iron, manganese, copper, boron, nitrogen, phosphorus and potassium), of camu-camu content. Vitamins were determined by high performance liquid chromatography, calcium, magnesium, zinc, copper, manganese and iron by atomic absorption spectrometry, potassium by flame photometry and phosphorous, boron and sulfur by spectrophotometry in wave lengths 725 and 420nm, respectively. Fruit grown in a dry environment showed higher (P<0.05) vitamin C content (13756.79mg 100g-1/dry weight) and generally higher mineral content (calcium, magnesium, sulfur, iron, copper, nitrogen, phosphorus and potassium). β-carotene content was not influenced (P>0.05) by different environments.