Molecular Recognition between Carbon Dioxide and Biodegradable Hydrogel Models: A Density Functional Theory (DFT) Investigation.

In this research, we explore the potential of employing density functional theory (DFT) for the design of biodegradable hydrogels aimed at capturing carbon dioxide (CO2) and mitigating greenhouse gas emissions. We employed biodegradable hydrogel models, including polyethylene glycol, polyvinylpyrrolidone, chitosan, and poly-2-hydroxymethacrylate. The complexation process between the hydrogel and CO2 was thoroughly investigated at the ωB97X-D/6-311G(2d,p) theoretical level. Our findings reveal a strong affinity between the hydrogel models and CO2, with binding energies ranging from -4.5 to -6.5 kcal/mol, indicative of physisorption processes. The absorption order observed was as follows: chitosan > PVP > HEAC > PEG. Additionally, thermodynamic parameters substantiated this sequence and even suggested that these complexes remain stable up to 160 °C. Consequently, these polymers present a promising avenue for crafting novel materials for CO2 capture applications. Nonetheless, further research is warranted to optimize the design of these materials and assess their performance across various environmental conditions.

Feasibility analysis of green hydrogen production from oceanic energy.

Oceanic energy, such as offshore wind energy and various marine energy sources, holds significant potential for generating green hydrogen through water electrolysis. Offshore-generated hydrogen has the potential to be transported through standard pipelines and stored in diverse forms. This aids in mitigating the variability of renewable energy sources in power generation and, consequently, holds the capacity to reshape the framework of electrical systems. This research provides a comprehensive review of the existing state of investigation and technological advancement in the domain of offshore wind energy and other marine energy sources for generating green hydrogen. The primary focus is on technical, economic, and environmental issues. The technology's optimal features have been pinpointed to achieve the utmost capacity for hydrogen production, providing insights for potential enhancements that can propel research and development efforts forward. The objective of this study is to furnish valuable information to energy companies by presenting multiple avenues for technological progress. Concurrently, it strives to expand its technical and economic outlook within the clean fuel energy sector. This analysis delivers insights into the best operating conditions for an offshore wind farm, the most suitable electrolyzer for marine environments and the most economical storage medium. The green hydrogen production process from marine systems has been found to be feasible and to possess a reduced ecological footprint compared to grey hydrogen production.

Effects of the size and cost reduction on a discounted payback period and levelized cost of energy of a zero-export photovoltaic system with green hydrogen storage.

Zero-export photovoltaic systems are an option to transition to Smart Grids. They decarbonize the sector without affecting third parties. This paper proposes the analysis of a zero-export PVS with a green hydrogen generation and storage system. This configuration is feasible to apply by any self-generation entity; it allows the user to increase their resilience and independence from the electrical network. The technical issue is simplified because the grid supplies no power. The main challenge is finding an economic balance between the savings in electricity billing, proportional to the local electricity rate, and the complete system's investment, operation, and maintenance expenses. This manuscript presents the effects of the power sizing on the efficacy of economic savings in billing (ηSaving) and the effects of the cost reduction on the levelized cost of energy (LCOE) and a discounted payback period (DPP) based on net present value. In addition, this study established an analytical relationship between LCOE and DPP. The designed methodology proposes to size and selects systems to use and store green hydrogen from the zero-export photovoltaic system. The input data in the case study are obtained experimentally from the Autonomous University of the State of Quintana Roo, located on Mexico's southern border. The maximum power of the load is LPmax = 500 kW, and the average power is LPmean = 250 kW; the tariff of the electricity network operator has hourly conditions for a medium voltage demand. A suggested semi-empirical equation allows for determining the efficiency of the fuel cell and electrolyzer as a function of the local operating conditions and the nominal power of the components. The analytical strategy, the energy balance equations, and the identity functions that delimit the operating conditions are detailed to be generalized to other case studies. The results are obtained by a computer code programmed in C++ language. According to our boundary conditions, results show no significant savings generated by the installation of the hydrogen system when the zero-export photovoltaic system Power ≤ LPmax and DPP ≤ 20 years is possible only with LCOE ≤ 0.1 $/kWh. Specifically for the Mexico University case study, zero-export photovoltaic system cost must be less than 310 $/kW, fuel cell cost less than 395 $/kW, and electrolyzer cost less than 460 $/kW.

Transporting offshore wind power in the Western Gulf of Mexico: retrofitting existing assets for power transmission via green hydrogen-a review.

The USA recently announced it is planning on deploying 30 GW of offshore wind by 2030 (national goal for offshore wind). Part of this development will be in the Gulf of Mexico, which has both wind potential and pre-existing oil and gas pipelines, only a portion of which is currently being used. Examining whether these assets can be used to economically transport power back from future Gulf wind farms should be a first step for developers. The question of whether laying new high-voltage direct current submarine cable versus repurposing pipeline to transport wind power will be examined. This paper looks at the hydrogen market and its use to transport wind power, what it would take to retrofit pipeline to carry hydrogen, a cost analysis given available data, and a look at potential policy support. There is a need to assess pipelines individually; however, retrofitting existing infrastructure should be considered an alternative to laying new submarine transmission cables. Additionally, alleviating the issue of oil and gas stranded assets through pipeline reuse may provide political support in hastening the energy transition.

Photovoltaic Electrochemically Driven Degradation of Calcon Dye with Simultaneous Green Hydrogen Production.

In this study, for the first time, the production of green hydrogen gas (H2) in the cathodic compartment, in concomitance with the electrochemical oxidation (EO) of an aqueous solution containing Calcon dye at the anodic compartment, was studied in a PEM-type electrochemical cell driven by a photovoltaic (PV) energy source. EO of Calcon was carried out on a Nb/BDD anode at different current densities (7.5, 15 and 30 mA cm-2), while a stainless steel (SS) cathode was used for green H2 production. The results of the analysis by UV-vis spectroscopy and total organic carbon (TOC) clearly showed that the electrochemical oxidation (EO) of the Calcon dye after 180 min of electrolysis time by applying 30 mA cm-2 reached up to 90% of degradation and 57% of TOC removal. Meanwhile, under these experimental conditions, a green H2 production greater than 0.9 L was achieved, with a Faradaic efficiency of 98%. The hybrid electrolysis strategy is particularly attractive in the context of a circular economy, as these can be coupled with the use of more complex water matrices to transform organic depollution into an energy resource to produce H2 as a chemical energy carrier.