Quantification of methane and carbon dioxide surface emissions from a metropolitan landfill based on quasi-continuous eddy covariance measurement.

The Sudokwon landfill (SL) in the Seoul metropolitan area, South Korea, is among the world's largest landfills, striving to curtail landfill gas (LFG) emissions and achieve carbon neutrality by 2050. Since 2005, the SL Management Corporation (SLC) has measured LFG emissions (i.e., methane (CH4) and carbon dioxide (CO2)) using a dynamic flux chamber proposed by the US EPA. However, uncertainty prevails in validating the reduction of LFG emissions due to the limited spatiotemporal data coverage. In 2020, an eddy covariance (EC) system was installed to enhance measurements, revealing highly fluctuating LFG emissions driven by waste layer LFG production, LFG collection, and atmospheric pressure changes. During the study period, the annual CH4 emission increased slightly from 465.0 ± 4.2 to 485.5 ± 6.4 g C m-2, while that of CO2 decreased by 2/3 (from 408.7 ± 16.5 to 270.6 ± 18.8 g C m-2), primarily due to the doubled CO2 uptake by the vegetated topsoil. Our first long-term (March 2020 to February 2022) quasi-continuous monitoring using EC (with a gap-filling and partitioning technique based on Random Forest) emphasizes the difficulty of temporal upscaling of discontinuously observed surface emissions to quantify the LFG inventory and the need for continuous observations or suitable proxies (e.g., atmospheric CH4 concentration).

Spatial variation of methane oxidation and carbon dioxide sequestration in landfill biogeochemical cover.

The study investigated the spatial variation of potential methane (CH4) oxidation and residual carbon dioxide (CO2) sequestration in biogeochemical cover (BGCC) system designed to remove CH4, CO2, and hydrogen sulfide (H2S) from landfill gas (LFG) emissions. A 50 cm x 50 cm x 100 cm tank simulated BGCC system, comprising a biochar-amended soil (BAS) layer for CH4 oxidation, a basic oxygen furnace (BOF) slag layer for CO2 and H2S sequestration, and an upper topsoil layer. Synthetic LFG was flushed through the system in five phases, with each corresponding to different compositions and flow rates. Following monitoring, the system was dismantled, and samples were extracted from different depths and locations to analyze spatial variations, focusing on moisture content (MC), organic content (OC), pH, and electrical conductivity (EC). Additionally, batch tests on selected samples from BAS and BOF slag layers were performed to assess potential CH4 oxidation and residual carbonation capacity. The aim of study was to evaluate the BGCC's effectiveness in LFG mitigation, however this study focused on assessing spatial variations in physico-chemical properties, CH4 oxidation in the BAS layer, and residual carbonation in the BOF slag layer. Findings revealed CH4 oxidation in the BAS layer varied between 22.4 and 277.9 µg CH4/g-day, with higher rates in the upper part, and significant spatial variations at 50 cm below ground surface (bgs) compared to 85 cm bgs. The BOF slag layer showed a residual carbonation capacity of 40-49.3 g CO2/kg slag, indicating non-uniform carbonation. Overall, CH4 oxidation and CO2 sequestration capacities varied spatially and with depth in the BGCC system.

Exploring the potential of biofiltration for mitigating harmful gaseous emissions from small or old landfills: a review.

Landfills are widely employed as the primary means of solid waste disposal. However, this practice generates landfill gas (LFG) which contains methane (CH4), a potent greenhouse gas, as well as various volatile organic compounds and volatile inorganic compounds. These emissions from landfills contribute to approximately 25% of the total atmospheric CH4, indicating the imperative need to valorize or treat LFG prior to its release into the atmosphere. This review first aims to outline landfills, waste disposal and valorization, conventional gas treatment techniques commonly employed for LFG treatment, such as flares and thermal oxidation. Furthermore, it explores biotechnological approaches as more technically and economically feasible alternatives for mitigating LFG emissions, especially in the case of small and aged landfills where CH4 concentrations are often below 3% v/v. Finally, this review highlights biofilters as the most suitable biotechnological solution for LFG treatment and discusses several advantages and challenges associated with their implementation in the landfill environment.

Numerical investigation and optimal design of capillary barrier cover with passive gas collection pipes on the performance at limiting landfill gas emissions.

Relying solely on soil properties may not fully ensure the performance of capillary barrier covers at limiting landfill gas (LFG) emissions. This study proposed to install passive gas collection pipes in the coarse-grained soil layers of capillary barrier covers to enhance their performance at limiting LFG emissions. First, the LFG generation rate of municipal solid waste and its influencing factors were analyzed based on empirical formulas. This information provided necessary bottom boundary conditions for the analyses of LFG transport through capillary barrier covers with passive gas collection pipes (CBCPPs). Then, numerical simulations were conducted to investigate the LFG transport properties through CBCPPs and reveal relevant influencing factors. Finally, practical suggestions were proposed to optimize the design of CBCPPs. The results indicated that the maximum whole-site LFG generation rate occurred at the end of landfilling operation. The gas collection efficiency (E) of CBCPPs was mainly controlled by the ratio of the intrinsic permeability between the coarse- and fine-grained soil (K2/K1) and the laying spacing between gas collection pipes (D). E increased as K2/K1 increased but decreased as D increased. An empirical expression for estimating E based on K2/K1 and D was proposed. In practice, CBCPPs were supposed to be constructed once the landfilling operation finished. It is best to select the fine- and coarse-grained soils with K2/K1 exceeding 10,000 to construct CBCPPs.

Landfill gas collection efficiency: Categorization of data from existing in-situ measurements.

Landfill methane emissions are commonly estimated using cover-type dependent default collection efficiency values, with a first-order decay model or measured gas collection. Current default collection efficiencies used in the United States were predominately derived from 4 studies conducted during or prior to 2007 that relied on flux chambers. Flux chambers are limited by small sample sizes, placement restrictions, and the inability to measure emissions from gas or leachate collection systems. Since 2007, over 14 new studies have been completed using more advanced technologies that allow for direct measurement of methane plumes from most or all of a landfill's surface. On average, these measurements are 2-3 times greater than emissions predicted by current models and collection efficiency defaults. In lieu of measuring emissions from all landfills, updating collection efficiency defaults can bring modeled emissions into better alignment with measurements. To this end, collection efficiency estimates derived from measured data were categorized into cover types and then adjusted to account for cases where whole plume measurement was an amalgamation of multiple cover types. The resultant adjusted default values were 41% for daily cover, 69% for intermediate cover, and 71% for final cover. Direct measurement of landfill methane emissions is preferrable to account for the full range of variables driving landfill emissions, including collection system design and operation. However, applying these updated defaults back into the landfill emission models eliminates underprediction of landfill emissions for the dataset reviewed, and would provide a more accurate estimate of landfill gas emissions where measurements are unavailable.

Effects of Hydrophobic Biochar-Modified Landfill Soil Cover on Methane Oxidation.

Landfill cover soils play an important role in mitigating landfill methane (CH4) emissions. Incorporating biochar into the soil has proven effective in reducing CH4 emissions. However, the role of hydrophobic biochar in this context remains underexplored. This study investigated the CH4 removal efficiency of a biochar-modified landfill soil cover column (RB) and hydrophobic biochar-modified landfill soil cover column (RH) under varying CH4 influx gas concentrations (25 and 35%), simulated CH4 inflow rates (10, 15, and 20 ml/min), and temperatures (20, 25, 30, 35, and 40 °C). RH consistently outperformed RB in terms of CH4 removal efficiency under these experimental conditions. The optimal conditions for CH4 degradation by both RB and RH were observed at a CH4 influx gas concentration of 35%, a simulated CH4 inflow rate of 10 ml/min, and a temperature of ~30 °C. RH achieved a CH4 removal rate of up to 99.96%. In summary, the addition of hydrophobic biochar enhanced the air permeability and hydrophobicity of landfill cover soils, providing a promising alternative to conventional cover soils for reducing CH4 emissions from landfills.

Life Cycle Analysis of Fischer-Tropsch Diesel Produced by Tri-Reforming and Fischer-Tropsch Synthesis (TriFTS) of Landfill Gas.

Renewable liquid fuels production from landfill waste provides a promising alternative to conventional carbon-intensive waste management methods and has the potential to contribute to the transition toward low-carbon fuel pathways. In this work, we investigated the life cycle greenhouse gas (GHG) emissions of producing Fischer-Tropsch diesel from landfill gas (LFG) using the TriFTS catalytic conversion process and compared it to fossil-based petroleum diesel. A life cycle-based comparison was made between TriFTS diesel and other LFG waste management pathways, LFG-to-Electricity and LFG-to-Compressed renewable natural gas (RNG), on a per kilogram of feedstock basis as well as on a per MJ of energy basis, which also included the LFG-to-Direct Combustion pathway. The study considered flaring of LFG as the common underlying counterfactual scenario for all of the waste-to-energy product pathways. We estimated the life cycle GHG emissions for TriFTS diesel to be -36.4 carbon dioxide equivalent (grams CO2e)/MJ which is significantly lower than its fossil fuel counterpart which was estimated to be 90.5 g CO2e/MJ on a cradle-to-grave basis. The life cycle emission results from both perspectives (per kg feedstock and per MJ energy output) show that TriFTS diesel is a viable alternative energy pathway from LFG when compared to other pathways, primarily due to the main product being a renewable fuel that can serve as a drop-in fuel for diesel-based uses, within both the waste industry as well as the larger market. Further sensitivity analysis was performed based on the production of TriFTS diesel with the counterfactual waste management scenario of LFG-to-Flaring as well as the alternative LFG-to-Electricity waste management pathway. The sensitivity of the carbon intensity for TriFTS diesel to flaring efficiency and the carbon intensity of the electricity grid were also investigated. The study highlights the potential for the TriFTS conversion process technology to contribute to the waste industry's closed loop and decarbonization initiatives and to provide low carbon fuel for transportation.

Assessment of landfill gas storage and application regarding energy management: A case study in the province of Quebec, Canada.

Landfills are extensively applied to dispose of municipal solid wastes in developed and developing countries. Landfill gas generation from biodegradable organic wastes can be collected and converted to energy. When the gas collection system is shutdown, some of this gas can accumulate and be stored inside the landfill. Using the gas storage capacity of the landfill gets a better management of the landfill site because the collected stored gas could transform the landfill into a cheap gas storage system to provide short-term energy and use the energy when needed. This novel study analyzes the stored methane using the gas collection data of a landfill in Quebec province, Canada, for modulating energy production from landfill gas. Twenty episodes of the gas collection system's shutdown and restart as well as different gas flow durations were studied. The results showed that the collected stored methane is accumulated in an average of 2.5 h. Additionally, the collected stored methane represents 10.5% of landfill gas flow. Although the results are site-specific, the methodology of this paper can be used on other landfill sites with similar size and collection conditions. Designing new landfills could take into consideration some elements to enhance gas storage capacity. For instance, designing landfill daily covers with more granular materials and higher porosities can be the next step to enhance the landfill as a gas storage system during shutdowns.

Advanced IoT Pressure Monitoring System for Real-Time Landfill Gas Management.

This research presents a novel stand-alone device for the autonomous measurement of gas pressure levels on an active landfill site, which enables the real-time monitoring of gas dynamics and supports the early detection of critical events. The developed device employs advanced sensing technologies and wireless communication capabilities, enabling remote data transmission and access via the Internet. Through extensive field experiments, we demonstrate the high sampling rate of the device and its ability to detect significant events related to gas generation dynamics in landfills, such as flare shutdowns or blockages that could lead to hazardous conditions. The validation of the device's performance against a high-end analytical system provides further evidence of its reliability and accuracy. The developed technology herein offers a cost-effective and scalable solution for environmental landfill gas monitoring and management. We expect that this research will contribute to the advancement of environmental monitoring technologies and facilitate better decision-making processes for sustainable waste management.

Growth Media Efficacy in Biochemical Methane Potential Assays.

The Biochemical Methane Potential (BMP) assay is a vital tool for quantifying the amount of methane that specific biodegradable materials can generate in landfills and similar anaerobic environments. Applications of the protocol are extensive and while simple in design, the BMP assay can use anaerobic seed from many different types of sources to determine the methane potential from most biodegradable substrates. Many researchers use differing protocols for this assay, both including and excluding the use of synthetic growth medias, intended to provide vital nutrients and trace elements that facilitate methanogenesis and leave the substrate being tested as the only limiting factor in methane generation potential. The variety of previous approaches inspired this effort to determine the efficacy of adding synthetic growth media to BMP assays. The presented findings suggest the use of M-1 synthetic growth media, defined in this study, at a volumetric ratio of 10% active sludge: 90% M-1 media yielded optimal results in terms of gas yield and reduced variability.

Effects of landfill food waste diversion: a focus on microbial populations and methane generation.

The early stages of municipal solid waste degradation in landfills are complex harmonies of physical, biological, and chemical interactions that all work in concert to degrade trash into smaller and more stable materials. While many approaches have been taken to understand parts of this process, this new work attempted to simulate the early stages of landfills in controlled laboratory environments while observing the impacts of food waste content at different concentrations. This was completed by operating landfill lysimeters in a laboratory for approximately 1000 days, simulating landfill interior conditions while measuring the gas and liquid byproducts to study the impact of food waste presence in these environments. Metagenomic analysis after the experiment identified over 18,000 individual species and allowed comparison with past studies while also surveying microorganisms present in landfills. Similar populations found in past studies suggested the current experiments successfully replicated landfill conditions. While food waste diversion had a discernable impact on gas production, it did not show a clear and consistent impact on the microbiomes identified in this study.

Evaluation of stabilization status of the landfill layers by comparing long-term monitoring data of methane emission with FOD model estimate.

Long-term monitoring and treatment of landfill leachate (LFL) and landfill gas (LFG) is required until landfilled municipal solid waste (MSW) is sufficiently stabilized and post-closure care can be terminated. Monitoring data of methane (CH4) emissions in LFG from a marine landfill over 30 years were compared with the IPCC first order decay (FOD) model estimates. The observed changes in CH4 showed a similar attenuation trend to the estimates, but the observed CH4 emissions were only about 30% of the estimate over 30 years; LFL is considered to be another pathway for organic carbon to be released to the environment, but the total organic carbon in discharged LFL was only about 0.2% of CH4 carbon in LFG emission over the same period. The increase in the CO2/CH4 ratio in LFG over time suggests that the discrepancy between estimated and observed emissions is due to methane oxidation in the overlying soil, in addition to the high coefficient values used in the FOD model. Total organic carbon (TOC) in LFL discharged as effluent reached a maximum value in the early stages of the landfill and gradually decreased, but only to about one-third of the maximum value after more than 30 years and a decrease in the amount of effluent. As incineration of MSW is expected to reduce organic carbon and nitrogen, the CH4 reduction effect of incineration of business and household waste and sewage sludge was investigated using FOD model estimates.

Variations of trace metals in combustion chamber deposit in landfill gas engine a long period of time.

The combustion chamber deposit (CCD) is a major problem for the gas engines that formed accumulating of the metal oxides during the oxidation of trace compounds in the landfill gas (LFG). Therefore, the LFG was purified with activated carbon (AC) before in use to reduce deposit formation in gas engines. The AC treatment demonstrated the high removal capacity by reducing to below 1 % of the mass ratios of Si and Ca in the deposit. Unfortunately, the AC treatment caused the formation of black deposit in the intercooler that was analyzed by EDS and XRD. First time in this study, the variation of the elements of the CCD was comparatively investigated over a long period of time in 2010 and in 2019 without -AC treatment of LFG. The variation of the concentrations of C, Ca, N, S, Sb, Si- and Sn in the CCD were confirmed by the analysis with ICP-OES and SEM-EDS for 9-year period. It was determined with EDS analysis that while Sb and Sn were relatively low, C and N were high based on 2010. It has been determined that there is a proportional change depending on the time of the elements forming in the deposit.

Removing siloxanes and hydrogen sulfide from landfill gases with biochar and activated carbon filters.

Landfill gas (LFG) is formed by microorganisms within a landfill; it can be utilized as a renewable fuel in power plants. Impurities such as hydrogen sulfide and siloxanes can cause significant damage to gas engines and turbines. The aim of this study was to determine the filtration efficiencies of biochar products made of birch and willow to remove hydrogen sulfides, siloxanes, and volatile organic compounds from the gas streams compared to activated carbon. Experiments were conducted on a laboratory scale with model compounds and in a real LFG power plant where microturbines are used to generate power and heat. The biochar filters removed heavier siloxanes effectively in all of the tests. However, the filtration efficiency for volatile siloxane and hydrogen sulfide declined quickly. Biochars are promising filter materials but require further research to improve their performance.

XANES/EXAFS and quantum chemical study of the speciation of arsenic in the condensate formed in landfill gas processing: Evidence of the dominance of As-S species.

The XANES/EXAFS data and quantum chemical simulations presented in this study demonstrate several features of the chemistry of arsenic compounds found in the condensates and solids generated in landfill gas (LFG) processing carried out for renewable natural gas (RNG) production. The XANES data show the decrease in the position of the absorption edge of As atoms, similar to that characteristic for sulfur-containing As solutes and solids. The EXAFS data show that the As-O and As-S distances in these matrixes are similar to those in thioarsenates. Quantum-chemical calculations demonstrated the close agreement between the experimental and modeled As-S and As-O distances determined for a range of methylated and thiolated arsenic solutes. These calculations also showed that the increase of the number of the As-S bonds in the coordination shell of arsenic is accompanied by a consistent decrease of the charges of As atoms. This decrease is correlated with the number of the As-S bonds, in agreement with the trend observed in the XANES data. These results provide insight into the intrinsic chemistry and reactivity of As species present in LFG matrixes; they may be helpful for the development of treatment methods to control arsenic in these systems.

Understanding landfill gas behavior at elevated temperature landfills.

Landfill gas (LFG) wellhead data were compared to understand the range of observations due to unique conditions at five elevated temperature landfills (ETLFs) in the U.S. Correlations of the primary gas ratio, CH4:CO2, show distinct compositional indicators for (1) typical operation, (2) subsurface exothermic reactions (SERs), (3) high moisture content, and (4) air intrusion that can help operators and regulators diagnose conditions across gas extraction wells. ETLFs A, B, D, and E showed similar trends, such as decreasing CH4 and increasing CO2, CO, and H2 that have been previously described. ETLF C uniquely exhibited elevated CH4 and temperatures simultaneously due to carbonation (i.e., CO2 consumption) of a steel slag which was used as alternative daily cover (ADC). At the maximum gas well temperature, T = 82 °C/180 °F, CH4 and CO2 concentrations were 47% and 28%, respectively. At ETLFs A, B, and E, H2 > 50% were regularly observed in affected gas wells for several years. At the five ETLFs, maximum CO concentrations ranged from 1400-16,000 ppmv. Like the analysis of CH4:CO2, it is hypothesized here that H2 (%):CO (ppmv) may infer the types of waste that are thermally degrading. Co-disposal of industrial wastes and MSW and the use of potentially reactive ADCs should remain an important consideration for landfill operators and regulators because of their potential long-term impacts to LFG quality.

Assessment of landfill gases by LandGEM and energy recovery potential from municipal solid waste of Kanpur city, India.

The world due to increased urbanization and globalization is facing major environmental challenges. Anthropogenic emissions of Greenhouse gases (GHG) like carbon dioxide and methane are on the rise and unsustainable which needs to be regulated. Open dumping of Municipal Solid Waste (MSW) contributes to generation of greenhouse gases like carbon dioxide and methane. This is because large fractions of the waste open dumped are organic in nature which undergoes anaerobic decomposition leading to generation of GHGs. In particular, methane has a high potential for energy generation and if utilized could be highly beneficial. The present study assesses the generation of landfill gases, primarily methane generation potential from MSW generated in Kanpur city using LandGEM 3.02 version model developed by USEPA for the period 2015-2030. It was observed from the study that the cumulative LFGs generation, methane emission and energy recovery potential estimated as 233.44 × 106 m3, 116 × 106 m3 and 858.14 × 106 MJ respectively. Uncertainty analysis carried out showed that variation in methane emissions maybe attributed to input parameters of k and Lo of the LandGEM model. The study shows that there exists high potential to control the greenhouse gas emissions by utilizing the methane generated for energy production.

Volatile and semi-volatile organic compounds in landfill gas: Composition characteristics and health risks.

Gas emitted from landfills contains a large quantity of volatile organic compounds (VOCs) and semi-volatile organic compounds (SVOCs), some of which are carcinogenic, teratogenic, and mutagenic, thereby posing a serious threat to the health of landfill workers and nearby residents. However, the global hazards of VOCs and SVOCs in landfill gas to human health remain unclear. To quantify the global risk distributions of these pollutants, we collected the composition and concentration data of VOCs and SVOCs from 72 landfills in 20 countries from the core database of Web of Science and assessed their human health risks as well as analyzed their influencing factors. Organic compounds in landfill gas were found to primarily result from the biodegradation of natural organic waste or the emissions and volatilization of chemical products, with the concentration range of 1 × 10-1-1 × 106 µg/m3. The respiratory system, in particular, lung was the major target organ of VOCs and SVOCs, with additional adverse health impacts ranging from headache and allergies to lung cancer. Aromatic and halogenated compounds were the primary sources of health risk, while ethyl acetate and acetone from the biodegradation of natural organic waste also exceeded the acceptable levels for human health. Overall, VOCs and SVOCs affected residents within 1,000 m of landfills. Air temperature, relative humidity, air pressure, wind direction, and wind speed were the major factors that influenced the health risks of VOCs and SVOCs. Currently, landfill risk assessments of VOCs and SVOCs are primarily based on respiratory inhalation, with health risks due to other exposure routes remaining poorly elucidated. In addition, potential health risks due to the transport and transformation of landfill gas emitted into the atmosphere should be further studied.

Impact of Landfill Gas Exposure on Vegetation in Engineered Landfill Biocover Systems Implemented to Minimize Fugitive Methane Emissions from Landfills.

Engineered landfill biocovers (LBCs) minimize the escape of methane into the atmosphere through biological oxidation. Vegetation plays a crucial role in LBCs and can suffer from hypoxia caused by the displacement of root-zone oxygen due to landfill gas and competition for oxygen with methanotrophic bacteria. To investigate the impact of methane gas on vegetation growth, we conducted an outdoor experiment using eight vegetated flow-through columns filled with a 45 cm mixture of 70% topsoil and 30% compost, planted with three types of vegetation: native grass blend, Japanese millet, and alfalfa. The experiment included three control columns and five columns exposed to methane, as loading rates gradually increased from 75 to 845 gCH4/m2/d over a period of 65 days. At the highest flux, we observed a reduction of 51%, 31%, and 19% in plant height, and 35%, 25%, and 17% in root length in native grass, Japanese millet, and alfalfa, respectively. The column gas profiles indicated that oxygen concentrations were below the levels required for healthy plant growth, which explains the stunted growth observed in the plants used in this experiment. Overall, the experimental results demonstrate that methane gas has a significant impact on the growth of vegetation used in LBCs.

Assessment of gas dispersion near an operating landfill treated by different intermediate covers with soil alone, low-density polyethylene (LLDPE), or ethylene vinyl alcohol (EVOH) geomembrane.

This study evaluated the impact area of odiferous gas (i.e., H2S) dispersion near an operating landfill installed with three different intermediate covers, including soil alone, linear low-density polyethylene (LLDPE), or ethylene vinyl alcohol (EVOH) geomembrane (GM). By using the finite element method employing Reynolds-averaged Navier-Stokes and Fick's Law coupled equations, the performance of the different cover cases for reducing odor dispersion was comparatively evaluated considering environmental factors, including topographic, meteorology, and gas emission. The odor dispersion patterns and the size of affected residents were analyzed for the twelve different scenarios varied with the cover type and seasonal variation. According to the results, it was found that the wind speed affected the time of odor dispersions more with the relatively flat terrain conditions around the landfill but barely affected the size of the dispersion area. Moreover, it was found that the higher concentration (100 ppb) of odor gas is mainly located within a 5.0-km distance from the landfill. Among four seasons, the odor covers the largest area in summer, which is mainly due to the landfill producing more odor gas and giving a higher source concentration in summer. The gas dispersion simulation for different covers showed that the type of covering layer significantly affects the impact area boundary of gas odor. The results showed that the odor area of the LLDPE GM cover case is 1.3% of soil alone case, and the case of EVOH GM is 14.5% of LLDPE GM case. At the same time, the number of residents that may be affected by the odor of the LLDPE GM case and EVOH GM case is 4.81% and 0.63% of soil alone case, respectively.