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1.
Environ Sci Technol ; 2024 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-38968232

RESUMO

The ongoing transition toward electric vehicles (EVs) is changing materials used for vehicle production, of which the consequences for the environmental performance of EVs are not well understood and managed. We demonstrate that electrification coupled with lightweighting of automobiles will lead to significant changes in the industry's demand not only for battery materials but also for other materials used throughout the entire vehicle. Given the automotive industry's substantial consumption of raw materials, changes in its material demands are expected to trigger volatilities in material prices, consequently impacting the material composition and attractiveness of EVs. In addition, the materials recovered during end-of-life recycling of EVs as the vehicle fleet turns over will impact recycled material supplies both positively and negatively, impacting material availabilities and the economic incentive to engage in recycling. These supply chain impacts will influence material usage and the associated environmental performance of not only the automotive sector but also other metal-heavy industries such as construction. In light of these challenges, we propose the need for new research to understand the dynamic materials impacts of the EV transition that encompasses its implications on EV adoption and fleet life cycle environmental performance. Effectively coordinating the coevolution of material supply chains is crucial for making the sustainable transition to EVs a reality.

2.
Artigo em Inglês | MEDLINE | ID: mdl-38968931

RESUMO

Quantitative contrast-enhanced breastcomputed tomography (CT) has the potential to improve the diagnosis and management of breast cancer. Traditional methods using energy-integrated detectors and dual-exposure images with different incident spectra for material discrimination can increase patient radiation dose and be susceptible to motion artifacts and spectral resolution loss. Photon Counting Detectors (PCDs) offer a promising alternative approach, enabling acquisition of multiple energy levels in a single exposure and potentially better energy resolution. Gallium arsenide (GaAs) is particularly promisingfor breast PCD-CT due to its high quantum efficiency and reduction of fluorescence X-rays escaping the pixel within the breast imaging energy range. In this study, the spectral performance of a GaAs PCD for quantitative iodine contrast-enhanced breast CT was evaluated. A GaAs detector with a pixel size of 100 µm, a thickness of 500 µm was simulated. Simulations were performed using cylindrical phantoms of varying diameters (10 cm, 12 cm, and 16 cm) with different concentrations and locations of iodine inserts, using incident spectra of 50, 55, and 60 kVp with 2 mm of added aluminum filtration and one exposure level corresponding to a Mean Glandular Doses (MGD) of approximately 10 mGy. We accounted for the effects of beam hardening and energy detector response using TIGRE CT open-source software and the publicly available Photon Counting Toolkit (PcTK). Material-specific images of the breast were produced using both projection and image-based material decomposition methods, and iodine component images were used to estimate iodine intake. Accuracy and precision of the proposed methods forestimating iodine concentration in breast CT images were assessed for different material decomposition methods, incident spectra, and breastphantom thicknesses. The results showed that both the beam hardening effect and imperfection in the detector response had a significant impact on performance in terms of Root Mean Squared Error (RMSE), precision, and accuracy of estimati.

3.
Mar Pollut Bull ; 205: 116623, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38964191

RESUMO

Studies on the conversion of organic materials into biochar have been preferred due to the effectiveness of biochar. Aquatic ecosystems harbor a significant amount of organic biomass, much of which is transferred to terrestrial systems, but often remains as waste. In this study, Posidonia oceanica (PO), Halidrys siliquosa (HS), Ulva lactuca (UL), and Codium fragile (CF), commonly found as marine waste along coastlines globally, were used as feedstocks for biochar production under four different pyrolysis conditions. Several analyses were conducted to characterize both marine waste and biochar forms in order to evaluate their potential for agricultural applications. The results showed that marine wastes and biochars contain almost all the necessary nutrients required for plant nutrition in varying proportions. The CF feedstock has a higher nitrogen (N) content than other feedstocks, while the UL contains greater phosphorus (P), potassium (K), and magnesium (Mg). Additionally, the PO exhibits high calcium (Ca), boron (B), and manganese (Mn) contents. Carbon (C) content also varied significantly depending on the biochar production technique. Temperature had a greater influence than holding time on the disparities in the elemental composition of biochars. The pH values of all types of biochar increased with rising temperature. However, the electrical conductivity (EC) values of HS and PO biochars decreased with increasing temperature. The highest mean BET surface area was observed in PO biochars. However, UL biochar has the most significant proportional increase compared to the UL feedstock by 218 times. All characteristics determined for all materials (feedstock, biochar) were within acceptable limits for application to soil. In conclusion, both marine waste and biochar forms may be confidently used for agricultural purposes, particularly in soil applications, when considering the characterization parameters within the scope of this research. Additionally, supporting and developing these results with more comprehensive analysis and research would be more suitable to reveal the potential of these marine wastes for agricultural systems.

4.
Environ Res ; : 119519, 2024 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-38964582

RESUMO

The shaping of covalent organic frameworks (COFs), requiring the conversion of non-processible COF powders into applicable architectures with additional functionality, remains a challenge. Using pre-electrospun polymer fibers as a sacrificial template, herein, we report a green synthesis of an architecture in the form of COF hollow fibers with an inner layer of peroxidase-like iron oxide nanoparticles as a catalytic material. When compared to peroxidase-like pristine iron oxide nanoparticles, these COF hollow fibers demonstrate higher catalytic breakdown of crystal violet due to their peroxidase-like activity via advanced oxidation process. Furthermore, as a potential adsorbent, hollow COF fibers exhibit significantly effective adsorption capacity and removal efficiency of organic solvent and oil from water. Because of their magnetic nature, COF hollow fibers can be easily recovered and have exhibited high recycling stability for both catalytic dye degradation and organic solvent removal from water.

5.
Int J Biol Macromol ; : 133631, 2024 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-38964688

RESUMO

Controllable heparin-release is of great importance and necessity for the precise anticoagulant regulation. Efforts have been made on designing heparin-releasing systems, while, it remains a great challenge for gaining the external-stimuli responsive heparin-release in either intravenous or catheter delivery. In this study, an azobenzene-containing ammonium surfactant is designed and synthesized for the fabrication of photoresponsive heparin ionic complexes through the electrostatic complexation with heparin. Under the assistance of photoinduced trans-cis isomerization of azobenzene, the obtained heparin materials perform reversible athermal phase transition between ordered crystalline and isotropic liquid state at room temperature. Compared to the ordered state, the formation of isotropic state can effectively improve the dissolving of heparin from ionic materials in aqueous condition, which realizes the photo-modulation on the concentration of free heparin molecules. With good biocompatibility, such a heparin-releasing system addresses photoresponsive anticoagulation in both in vitro and in vivo biological studies, confirming its great potential clinical values. This work provides a new designing strategy for gaining anticoagulant regulation by light, also opening new opportunities for the development of photoresponsive drugs and biomedical materials based on biomolecules.

6.
Artigo em Inglês | MEDLINE | ID: mdl-38959869

RESUMO

OBJECTIVE: The availability of tissue-mimicking materials (TMMs) for manufacturing high-quality phantoms is crucial for standardization, evaluating novel quantitative approaches, and clinically translating new imaging modalities, such as photoacoustic imaging (PAI). Recently, a gel comprising the copolymer styrene-ethylene/butylene-styrene (SEBS) in mineral oil has shown significant potential as TMM due to its optical and acoustic properties akin to soft tissue. We propose using artists' oil-based inks dissolved and diluted in balsam turpentine to tune the optical properties. APPROACH: A TMM was fabricated by mixing a SEBS copolymer and mineral oil, supplemented with additives to tune its optical absorption and scattering properties independently. A systematic investigation of the tuning accuracies and relationships between concentrations of oil-based pigments and optical absorption properties of the TMM across visible and near-infrared wavelengths using collimated transmission spectroscopy was conducted. The photoacoustic spectrum of various oil-based inks was studied to analyze the effect of increasing concentration and depth. MAIN RESULTS: Artists' Oil-based inks dissolved in turpentine proved effective as additives to tune the optical absorption properties of mineral oil SEBS-gel with high accuracy. The TMMs demonstrated long-term stability and suitability for producing phantoms with desired optical absorption properties for PAI studies. SIGNIFICANCE: The findings, including tuning of optical absorption and spectral shape, suggest that this TMM facilitates the development of more sophisticated phantoms of arbitrary shapes. This approach holds promise for advancing the development of PAI, including investigation of the spectral coloring effect. In addition, it can potentially aid in the development and clinical translation of ultrasound optical tomography.

7.
Artigo em Inglês | MEDLINE | ID: mdl-38960923

RESUMO

As one of the important devices for large-scale electrochemical energy storage, sodium-ion batteries have received much attention due to the abundant resources of raw materials. However, whether it is a base station power source, an energy storage power station, or a start-stop power supply, long energy cycle life (more than 5000 cycles), high stability, and safety performance are application prerequisites. Regrettably, currently, few sodium-ion batteries can meet this requirement, mainly due to shortcomings in positive electrode performance. We report a sufficiently stable sodium-ion battery cathode material, Na2Fe0.95P2O7, that retains 97.5% capacity after 5000 charge/discharge cycles. The use of nonstoichiometry in the lattice enables simultaneous modification of the crystal and electronic structure, promoting Na2Fe0.95P2O7 to be extremely stable while still being able to achieve a capacity of 92 mAh g-1 and stable cycling at high temperatures up to 60 °C. Our results confirm the positive effect of nonstoichiometric ratios on the performance of Na2Fe0.95P2O7 and provide a reliable idea to promote the practical application of sodium-ion batteries.

8.
ACS Appl Mater Interfaces ; 16(26): 33396-33403, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38961570

RESUMO

Germanium has been recognized as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity and excellent lithium-ion diffusivity. Nonetheless, it is challenging to enhance both the high-rate performance and long-term cycling stability simultaneously. This study introduces a novel heterostructure composed of germanium nanosheets integrated with graphene (Ge NSs@Gr). These nanosheets undergo an in situ phase transformation from a hydrogen-terminated multilayer germanium compound termed germanane (GeH) derived via topochemical deintercalation from CaGe2. This approach mitigates oxidation and prevents restacking by functionalizing the exfoliated germanane with octadecenoic organic molecules. The resultant germanium nanosheets retain their structural integrity from CaGe2 and present an exposed, active (111) surface that features an open crystal lattice, facilitating swift lithium-ion migration conducive to lithium storage. The composite material delivers a substantial reversible capacity of 1220 mA h g-1 at a current density of 0.2 C and maintains a capacity of 456 mA h g-1 even at an ultrahigh current density of 10 C over extended cycling. Impressively, a capacity of 316 mA h g-1 remains after 5000 cycles. The exceptional high-rate performance and durable cycling stability underscore the Ge NSs@Gr anode's potential as a highly viable option for LIBs.

9.
ACS Appl Mater Interfaces ; 16(26): 33285-33293, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38961568

RESUMO

The foreseeable global cobalt (Co) crisis has driven the demand for cathode materials with less Co dependence, where high-nickel layered oxides are a promising solution due to their high energy density and low cost. However, these materials suffer from poor cycling stability and rapid voltage decay due to lattice displacement and nanostrain accumulation. Here, we introduced an exothermic TiN dopant via a scalable coating method to stabilize LiNi0.917Co0.056Mn0.026O2 (NCM92) materials. The exothermic reaction of TiN conversion generates extra heat during the calcination process on the cathode surface, promotes the lithiation process, and tunes the morphology of the cathode material, resulting in compact and conformal smaller particle sizes to provide better particle integration and lithium diffusion coefficient. Moreover, the Ti dopant substitutes the Ni3+ site to generate stronger Ti-O bonding, leading to higher structural stability and extended cycle life. The Ti-doped NCM (NCM92_TiN) shows a remarkable cycling stability of maintaining 80% capacity retention for 400 cycles, while bare NCM92 can only reach 88 cycles. Furthermore, the NCM92_TiN cathodes demonstrate an enhanced rate capability and achieve a discharge capacity of over 168 mAh g-1 at 5C.

10.
Artigo em Inglês | MEDLINE | ID: mdl-38954283

RESUMO

Biomechanics-based patient-specific modeling is a promising approach that has proved invaluable for its clinical potential to assess the adversities caused by ischemic heart disease (IHD). In the present study, we propose a framework to find the passive material properties of the myocardium and the unloaded shape of cardiac ventricles simultaneously in patients diagnosed with ischemic cardiomyopathy (ICM). This was achieved by minimizing the difference between the simulated and the target end-diastolic pressure-volume relationships (EDPVRs) using black-box Bayesian optimization, based on the finite element analysis (FEA). End-diastolic (ED) biventricular geometry and the location of the ischemia were determined from cardiac magnetic resonance (CMR) imaging. We employed our pipeline to model the cardiac ventricles of three patients aged between 57 and 66 years, with and without the inclusion of valves. An excellent agreement between the simulated and the target EDPVRs has been reached. Our results revealed that the incorporation of valvular springs typically leads to lower hyperelastic parameters for both healthy and ischemic myocardium, as well as a higher fiber Green strain in the viable regions compared to models without valvular stiffness. Furthermore, the addition of valve-related effects did not result in significant changes in myofiber stress after optimization. We concluded that more accurate results could be obtained when cardiac valves were considered in modeling ventricles. The present novel and practical methodology paves the way for developing digital twins of ischemic cardiac ventricles, providing a non-invasive assessment for designing optimal personalized therapies in precision medicine.

11.
Artigo em Inglês | MEDLINE | ID: mdl-38954707

RESUMO

Real-time detection of harmful gases at room temperature has become a serious problem in public health and environmental monitoring. Two-dimensional materials with semiconductor properties BiOCl is a promising gas-sensitive material due to its large specific surface area and adjustable band gap as well as outstanding safety characteristics. However, limited by the weak gas adsorption sites and sluggish charge-transfer ability, the performance of BiOCl could not be fully exploited. Oxygen vacancy (Vo) engineering can introduce lattice defects, thereby significantly increasing the local charge density and enhancing the adsorption of gases, which is an effective strategy to enhance the gas-sensing performance. In this work, we composite BiOCl with a vacancy (Vo-BiOCl) and reduced graphene oxide (rGO) to construct a Vo-BiOCl/rGO heterostructure with enhanced gas adsorption sites. Experimental and theoretical calculations show that Vo can enhance the adsorption of gases and the introduction of rGO forms a high-quality heterostructure with BiOCl, which can effectively reduce the band gap of BiOCl and promote electron transfer, thereby improving the sensitivity of the sensor. Benefiting from above, Vo-BiOCl/rGO achieves the ability to detect low concentrations of NO2/NH3 at room temperature, with high sensitivity (55% at 1 ppm of NO2 and -28% at 1 ppm of NH3), fast response time (40 s at 1 ppm of NO2 and 2 s at 1 ppm of NH3), good stability (over 150 days), and fully recoverable gas sensitivity.

12.
Chemistry ; : e202400189, 2024 Jul 03.
Artigo em Inglês | MEDLINE | ID: mdl-38958147

RESUMO

Because of its high specific capacity and superior rate performance, porous carbon is regarded as a potential anode material for lithium-ion batteries (LIBs). However, porous carbon materials with wide pore diameter distributions suffer from low structural stability and low electrical conductivity during the application process. During this study, the calcium carbonate nanoparticle template method is used to prepare coal tar pitch-derived porous carbon (CTP-X). The coal tar pitch-derived porous carbon has a well-developed macroporous-mesoporous-microporous hierarchical porous network structure, which provides abundant active sites for Li+ storage, significantly reduces polarization and charge transfer resistance, shortens the diffusion path and promotes the rapid transport of Li+. More specifically, the CTP-2 anode shows high charge capacity (496.9 mAh g-1 at 50 mA g-1), excellent rate performance (413.6 mAh g-1 even at 500 mA g-1), and high cycling stability (capacity retention rate of about 100% after 1,000 cycles at 2 A g-1). The clean and eco-friendly large-scale utilization of coal tar pitch will facilitate the development of high-performance anodes in the field of LIBs.

13.
Soc Hist Med ; 37(1): 116-140, 2024 Feb.
Artigo em Inglês | MEDLINE | ID: mdl-38947279

RESUMO

Medical schools rely on a wide range of tools, technologies and materials for their teaching, on books, and bodies, and on the buildings which house them. This article considers the histories of this material culture in the three oldest medical schools operating in Ghana today. Borrowing theoretical concepts from Science and Technology Studies, medical anthropology and postcolonial political economy, this article takes that the material culture of modern medical education often binds contemporary pedagogy to outdated ideas and faraway places. The agential, proselytising nature of these historied materials agitates against the localisation of biomedicine and contributes to a distracting scientific imaginary which remains centred around historical, often imperial centres of knowledge production in Europe and North America.

14.
Heliyon ; 10(12): e32878, 2024 Jun 30.
Artigo em Inglês | MEDLINE | ID: mdl-38975073

RESUMO

Household single-use packaging has poor rates of recycling, and presents a challenge in transitioning to a circular packaging economy. This study characterises the flows of household single-use packaging in the municipal waste system for 2020-21 in New South Wales, Australia. Households are an important source of packaging usage in Australia, accounting for over 40 % of all packaging used in 2020-21. Our focus spans 17 single-use packaging materials and 11 formats. We estimate the composition of single-use consumer packaging in the kerbside collection stream, and the ultimate fate of used packaging. Results show 1000 ± 8 % kt of packaging was used by households in NSW in 2020-21 (∼123 kg/cap). Composition of the used packaging stream was dominated by glass (36 %), paper (29 %) and plastic (28 %) packaging. HDPE (26 % of plastic packaging), LDPE (24 %) and PET (19 %) were the main polymers in use. 63 % ± 5 % of used packaging was collected for recycling, and 34 % ± 7 % was recovered via recyclate generation and overseas exports. Glass packaging had the highest recycling rates at 52 % ± 3 %, while plastic packaging had the poorest at 11 % ± 10 %. Findings indicate incorrect disposal of recyclables at the household to mixed-waste systems as a major limitation of the system to improve recycling rates. Expansion in recovery capacity is also essential for improving recycling rates, and the potential for generating the packaging-grade recyclate essential for meeting recycled content targets. The study offers contributions to the understanding of consumer packaging managed within the municipal waste system. Insights gained have application in informing sustainable packaging and waste management strategies.

15.
Cureus ; 16(6): e61720, 2024 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-38975485

RESUMO

This paper aims to evaluate the outcomes of a partial pulpotomy with mineral trioxide aggregate (MTA) in a maxillary first premolar with reversible pulpitis symptoms and signs. An intraoral periapical radiograph revealed a deep pulp-involving carious lesion without any indications of a periapical lesion, no history of night pain, and no tooth tenderness when percussion was applied. Caries removal is done using a round bur, 2-3 mm of inflamed pulp from the crown portion was removed, and bleeding was controlled within four minutes using 2.5% sodium hypochlorite, over which MTA was placed. After the setting of MTA, resin-modified glass ionomer cement was placed over it, and the tooth was restored using composite. The patient was asymptomatic in six months and one-year follow-up with no periapical changes and showed dentin bridge formation. Careful case selection, a precise selection of biomimetic material, and long-term follow-up validate the success of the treatment.

16.
Open Access J Sports Med ; 15: 67-75, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38975566

RESUMO

Purpose: While injuries among elite tennis athletes are extensively documented, a notable research gap exists regarding tennis injuries among club-level players. This study examines tennis injuries in German league players, with a particular emphasis on the impact of racquet properties and court surfaces, distinguishing between chronic and acute injuries. Patients and Methods: Retrospectively analyzing data from 600 tennis players over a 1.5-year period, a standardized questionnaire covered anthropometrics, injury characteristics, equipment usage, and court surface conditions. Results: The study identified 1012 tennis-related injuries, averaging 1.7 per player. Acute injuries predominantly affected the lower extremity (56%), with ankle injuries being the most prevalent, and ligaments were the most commonly affected structures (36.4%). Chronic complaints (reported by 364 athletes) focused on the upper extremity (63.2%), primarily tendon injuries (56.8%). Racket properties exhibited no significant impact on chronic upper extremity injuries. Conclusion: This study highlights a high incidence of acute lower extremity injuries, especially ankle ligament injuries, among German league tennis players. It offers crucial insights for devising targeted injury prevention strategies applicable to amateur, semi-professional, and professional tennis players, despite finding no significant link between racquet material and chronic upper extremity injuries.

17.
ACS Nano ; 2024 Jul 08.
Artigo em Inglês | MEDLINE | ID: mdl-38976597

RESUMO

Supported nonprecious metal catalysts such as copper (Cu) are promising replacements for Pt-based catalysts for a wide range of energy-related electrochemical reactions. Direct electrochemical deposition is one of the most straightforward and versatile methods to synthesize supported nonprecious metal catalysts. However, further advancement in the design of supported nonprecious metal catalysts requires a detailed mechanistic understanding of the interplay between kinetics and thermodynamics of the deposition phenomena under realistic reaction conditions. Here, we study the electrodeposition of Cu on carbon nanotubes and graphene derivatives under electrochemical conditions using in situ liquid cell transmission electron microscopy (TEM). By combining real-time imaging, electrochemical measurements, X-ray photoelectron spectroscopy (XPS), and finite-element analysis (FEA), we show that low-dimensional support materials, especially carbon nanotubes, are excellent for generating uniform and finely dispersed platinum group metal-(PGM)-free catalysts under mild electrochemical conditions. The electrodeposited Cu on graphene and carbon nanotubes is also observed to show good electrochemical activity toward nitrate reduction reactions (NO3RRs), further supported by density functional theory (DFT) calculations. Nitrogen doping plays an important role in guiding nonprecious metal deposition, but its low electrical conductivity may give rise to lower NO3RR activity compared to its nondoped analogue. The development of supported nonprecious metals through interfacial and surface engineering for the design of supported catalysts will substantially reduce the demand for precious metals and generate robust catalysts with better durability, thereby presenting opportunities for solving the critical problems in energy storage and electrocatalysis.

18.
Ann Biomed Eng ; 2024 Jul 08.
Artigo em Inglês | MEDLINE | ID: mdl-38977529

RESUMO

PURPOSE: Individual facial soft tissue properties are necessary for creating individualized finite element (FE) models to evaluate medical devices such as continuous positive airway pressure (CPAP) masks. There are no standard tools available to measure facial soft tissue elastic moduli, and techniques in literature require advanced equipment or custom parts to replicate. METHODS: We propose a simple and inexpensive soft tissue measurement (STM) indenter device to estimate facial soft tissue elasticity at five sites: chin, cheek near lip, below cheekbone, cheekbone, and cheek. The STM device consists of a probe with a linear actuator and force sensor, an adjustment system for probe orientation, a head support frame, and a controller. The device was validated on six ballistics gel samples and then tested on 28 subjects. Soft tissue thickness was also collected for each subject using ultrasound. RESULTS: Thickness and elastic modulus measurements were successfully collected for all subjects. The mean elastic modulus for each site is Ec = 53.04 ± 20.97 kPa for the chin, El = 16.33 ± 8.37 kPa for the cheek near lip, Ebc = 27.09 ± 11.38 kPa for below cheekbone, Ecb = 64.79 ± 17.12 kPa for the cheekbone, and Ech = 16.20 ± 5.09 kPa for the cheek. The thickness and elastic modulus values are in the range of previously reported values. One subject's measured soft tissue elastic moduli and thickness were used to evaluate custom-fit CPAP mask fit in comparison to a model of that subject with arbitrary elastic moduli and thickness. The model with measured values more closely resembles in vivo leakage results. CONCLUSION: Overall, the STM provides a first estimate of facial soft tissue elasticity and is affordable and easy to build with mostly off-the-shelf parts. These values can be used to create personalized FE models to evaluate custom-fit CPAP masks.

19.
Artigo em Inglês | MEDLINE | ID: mdl-38977551

RESUMO

Carbonaceous materials hydrothermally produced using waste biomass have small specific surface areas (SSA) and poor porosity properties. In this study, we prepare a novel carbonaceous material with excellent porosity properties by suppressing the formation of a secondary char phase (spheres) and promoting biomass hydrolysis by controlling the hydrothermal conditions. Rice husk powders, as the starting material, are hydrothermally treated using acidic solvents of different types and concentrations at 180 °C. The surfaces of the samples hydrothermally prepared using the acidic solvents have no spheres. In the case of 0.1-0.2 mol L-1 hydrochloric acid (HA), the amorphous carbonaceous materials contain numerous mesopores and exhibit a larger SSA (approximately 100 m2 g-1) than those prepared using acetic acid and distilled water. An increase in the hydrothermal temperature reduces the porosity properties of the materials. Finally, the high-porosity amorphous carbonaceous material showed excellent trimethylamine adsorption ability.

20.
Chempluschem ; : e202400364, 2024 Jul 08.
Artigo em Inglês | MEDLINE | ID: mdl-38978154

RESUMO

Nuclear energy is a competitive and environmentally friendly low-carbon energy source. It is seen as an important avenue for satisfying energy demands, responding to the energy crisis, and mitigating global climate change. However, much attention has been paid to achieving the effective treatment of radionuclide oxoanions produced in nuclear waste. Initially, advanced adsorbents were mainly available in powder form, which meant that additional purification processes were usually required for separation and recovery in industrial applications. Therefore, to meet the practical requirements of industrial applications, materials need to be molded and processed into forms such as beads, membranes, gels, and resins. Here, we summarize the fabrication of porous materials used for capturing typical radionuclide oxoanions, including UO22+, TcO4-, IO3-, SeO32-, and SeO4-.

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