RESUMO
Objective: To investigate the properties of zirconia toughened glass infiltrated nanometer-ceramic composite (Al 2O 3/nZrO 2) . Methods: Zirconia toughened glass infiltrated nanometer-ceramic composite(Al 2O 3/nZrO 2)powder was prepared with combination of chemical co-precipitation method and ball milling. The shape, size, partical distribution, crystal phase and chemical composition were measured and analyzed. Results: (1) The crystal phase composition of the studied nanometer ceramic composite powder was made up with ?-Al 2O 3, t-ZrO 2 and m-ZrO 2 examined by XRD?(2) The density of the powder was 4.12 g/cm 3?(3) The particle distribution of the powder ranged 0.02～3.0 ?m?(4)Observed with SEM, the particle profile of the powder was regular, the ratio of length and width of the particles was about 1.2. Conclusion: The studied nanometer ceramic composite powder owns good homogeneity, stable chemical composition, reasonable powder-size gradation and may be favourable in the improvement of the packing density of ceramics.
RESUMO
?Objective: To study the preparation method of nanometer powder of zirconia, which was used to toughen dental alumina ceramics. Methods: The inorganic precursors at the concentrations of 0.0155 , 0.03, 0.05, 0.1 and 0.28 mol/L were used to prepare zirconia powder via precipitation method. Ammonia water was added into the said solutions to control the pH value at 7.0, 8.5 and 9. The dried precipitation product was then calcined. The prepared zirconia powder were studied by using X ray diffraction (XRD) and scanning electron microscope (SEM). Results: The zirconia powder prepared under the condition of 0.03 0.05 mol/L concentration of inorganic precursors, pH = 8.5, and calcined at 700 ℃ for 2 h was even in size,well dispersed and well micronized. The diameter of the final powder was about 100 nm. Conclusion: With proper preparation condition, weakly agglomerated powder of zirconia in nanometer size can be obtained.
