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1.
Small ; : e2405487, 2024 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-39092672

RESUMO

Practical utilization of zinc-iodine (Zn-I2) batteries is hindered by significant challenges, primarily stemming from the polyiodide shuttle effect on the cathode and dendrite growth on the anode. Herein, a feasible redox-active electrolyte has been introduced with tetraethylammonium iodide as an additive that simultaneously addresses the above mentioned challenges via polyiodide solidification on the cathode and the electrostatic shielding effect on the anode. The tetraethylammonium (TEA+) captures water-soluble polyiodide intermediates (I3 -, I5 -), forming a solid complex at the cathode, thereby suppressing capacity loss during charge/discharge. Furthermore, the TEA+ mitigates dendrite growth on the Zn anode via the electrostatic shielding effect, promoting uniform and compact Zn deposition at the anode. Consequently, the Zn||Zn symmetric cell demonstrates superior cycling stability during Zn plating/stripping over 4,200 h at 1 mA cm-2 and 1 mAh cm-2. The Zn||NiNC full-cell exhibits a stable capacity retention of 98.4% after 20 000 cycles (>5 months) with near-unity Coulombic efficiency at 1 A g-1. The study provides novel insights for establishing a new direction for low-cost, sustainable, and long-lifespan Zn-I2 batteries.

2.
Prev Med Rep ; 45: 102827, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39114410

RESUMO

Objectives: In March 2023, all societal-level COVID-19 control measures were lifted by the Dutch government. This study was performed to understand the self-experienced burden of this new phase of COVID-19 on the perspectives and behaviors of severely immunocompromised individuals. Methods: This is an observational, descriptive, cross-sectional study in The Netherlands. An online survey was completed by severely immunocompromised individuals, to capture their general well-being (score from 1 = worst to 10 = best), mental and physical health, and daily and social activities during survey conduct and retrospectively for before onset of COVID-19. The survey was open for completion from May 24th until August 7nd, 2023. Results: Of the 236 respondents, 96.6 % had been vaccinated against COVID-19 and 24.6 % were shielding to avoid COVID-19 during survey conduct. The general well-being score for all respondents was 7.5 (±1.2 SD) before onset of the COVID-19 pandemic and 6.9 (±1.6 SD) during survey conduct (P<0.001). For the shielding group (n = 58), these scores were 7.6 (±1.0 SD) and 5.7 (±1.6 SD), respectively (P<0.001). Generally, for all questions about mental and physical health and daily and social activities, there was a trend towards more negative answers during survey conduct, compared with before onset of the COVID-19 pandemic, which was more pronounced for the shielding group. Conclusions: Despite absence of government-imposed societal measures, COVID-19 avoidance still had a self-experienced burden on perspectives and behaviors of immunocompromised individuals in The Netherlands, with a significantly lower general well-being during survey conduct, compared with before onset of COVID-19.

3.
Adv Sci (Weinh) ; : e2406758, 2024 Aug 08.
Artigo em Inglês | MEDLINE | ID: mdl-39116320

RESUMO

Transparent electromagnetic interference (EMI) shielding is highly desired in specific visual scenes, but the challenge remains in balancing their EMI shielding effectiveness (SE) and optical transmittance. Herein, this study proposed a directionally aligned silver nanowire (AgNW) network construction strategy to address the requirement of high EMI SE and satisfactory light transmittance using a rotation spraying technique. The orientation distribution of AgNW is induced by centrifugal inertia force generated by a high-speed rotating roller, which overcomes the issue of high contact resistance in random networks and achieves high conductivity even at low AgNW network density. Thus, the obtained transparent conductive film achieved a high light transmittance of 72.9% combined with a low sheet resistance of 4.5 Ω sq-1 and a desirable EMI SE value of 35.2 dB at X band, 38.9 dB in the K-band, with the highest SE of 43.4 dB at 20.4 GHz. Simultaneously, the excellent conductivity endowed the film with outstanding Joule heating performance and defogging/deicing ability, ensuring the visual transparency of windows when shielding electromagnetic waves. Hence, this research presents a highly effective strategy for constructing an aligned AgNW network, offering a promising solution for enhancing the performance of optical-electronic devices.

4.
J Environ Radioact ; 278: 107511, 2024 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-39096838

RESUMO

One of the major demands in gamma spectrometry of environmental samples is the accurate determination of activity concentration of present radionuclides (naturally occurring and those of artificial origin), due to the fact they are commonly of relatively low content. Thus, all these measurements have in common that the detection limit, in the spectral region of interest should be as low as possible. For this reason, the construction of a good passive, as well as active shield requires a detailed knowledge of the origin of the background events in the absence of an environmental sample. In addition, an analysis of the impact on detection limits due to the presence of the sample itself is also important. Also, the knowledge of the statistical basics for low-level counting is helpful to enable the best choice of detector characteristics (relative efficiency, peak to Compton ratio, resolution), measuring time, and required level of precaution against the different background contributions. In this paper, the background spectra of several gamma spectroscopy systems (with passive and active veto shields) are analyzed and discussed, regarding their capabilities for measurements of environmental samples. Furthermore, various environmental samples are analyzed by low-level gamma spectrometry, including the sample measurements in the presence of an active veto shield against cosmic-ray muons. The disturbance of radioactive equilibrium between members of radioactive series in the samples is commented on, together with the possibility of use of certain gamma lines (including their interference and the corresponding intensities) for radionuclide activities determination.

5.
Int J Biol Macromol ; : 134354, 2024 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-39098664

RESUMO

Traditional electromagnetic shielding materials are difficult to realize practical applications due to excessive fillers, poor mechanical properties, and difficulty in preservation, etc. Hydrogel is a biomaterial with good biocompatibility and sustainability, which not only can overcome the aforementioned issues, but its biomimetic hierarchical porous structure also enables multifunctional applications. In this paper, a honeycomb-like unidirectional porous wall structured hydrogel is prepared by a simple freeze-thaw cycle and salting out method. Polyvinyl alcohol (PVA) and chitosan (CS) form a double cross-linked network (DN) enhanced by MXene, resulting in excellent mechanical and flexibility. Due to the synergistic effects of MXene, water, Fe3O4, abundant interfaces and micrometer porous wall structure, the electromagnetic shielding performance is enhanced. EMI SE increases by 30.7 dB as the MXene concentration increases from 0 to 1.5 wt%, and EMI SE increases from 7.9 to 66.7 dB as the water content increases from 0 to 76 %. Besides this, we encapsulate the hydrogel into a simple sensor, the signal response is rapid, the response /recovery time is 50/100 ms respectively, and it exhibits good sensitivity (0.0187 kPa-1). Different signals are generated based on variations in pressure, which holds significant importance for the development of wearable flexible sensors and information encoding.

6.
Cereb Cortex ; 34(8)2024 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-39110414

RESUMO

Adaptive behavior is fundamental to cognitive control and executive functioning. This study investigates how cognitive control mechanisms and episodic feature retrieval interact to influence adaptiveness, focusing particularly on theta (4 to 8 Hz) oscillatory dynamics. We conducted two variations of the Simon task, incorporating response-incompatible, response-compatible, and neutral trials. Experiment 1 demonstrated that cognitive adjustments-specifically, cognitive shielding following incompatible trials and cognitive relaxation following compatible ones-are reflected in midfrontal theta power modulations associated with the Simon effect. Experiment 2 showed that reducing feature overlap between trials leads to less pronounced sequential modulations in behavior and midfrontal theta activity, supporting the hypothesis that cognitive control and feature integration share a common neural mechanism. These findings highlight the interaction of cognitive control processes and episodic feature integration in modulating behavior. The results advocate for hybrid models that combine top-down and bottom-up processes as a comprehensive framework to understand cognitive control dynamics and adaptive behavior.


Assuntos
Cognição , Conflito Psicológico , Função Executiva , Ritmo Teta , Humanos , Ritmo Teta/fisiologia , Masculino , Feminino , Adulto Jovem , Cognição/fisiologia , Adulto , Função Executiva/fisiologia , Tempo de Reação/fisiologia , Eletroencefalografia , Desempenho Psicomotor/fisiologia , Adaptação Psicológica/fisiologia , Encéfalo/fisiologia
7.
Int J Biol Macromol ; : 134183, 2024 Aug 01.
Artigo em Inglês | MEDLINE | ID: mdl-39112113

RESUMO

The physico-chemical and biological properties of natural rubber latex (NRL), entailing its biodegradability and biocompatibility, render it a promising material for various biomedical applications. This research explores the facile blending of NRL with dextrin in different compositions to investigate its potential as a prospective UV shielding transdermal patch for biomedical applications. The superior compatibility between the polymers after blending and the improved thermal stability have been established through FTIR, DSC, and TGA examinations, respectively. Optimization of blended polymers for compatibility, wettability, crystallinity, and static mechanical properties has been performed. Morphology characterization conducted via SEM and AFM techniques suggests a uniform morphology for the optimized blend system. The UV shielding ability of the blend has been confirmed by the evaluation of in-vitro UV shielding performance, UV protection factor (UPF), and the superior protection of the optimized system on living cells upon UV irradiation. The observed cell viability, swelling, erosion, porosity, hemocompatibility, and soil degradation properties suggest the NRL-DXT combination for the possible development of high-quality transdermal patches.

8.
Small ; : e2402938, 2024 Aug 07.
Artigo em Inglês | MEDLINE | ID: mdl-39113331

RESUMO

With the rapid development of electronic industry, it's pressing to develop multifunctional electromagnetic interference (EMI) shielding materials to ensure the stable operation of electronic devices. Herein, multilayered flexible PEG@PAN/MXene (Ti3C2Tx)/PVDF@SiO2 (PMF) composite film has been constructed from the level of microstructure design via coaxial electrospinning, coating spraying, and uniaxial electrospinning strategies. Benefiting from the effective encapsulation for PEG and high conductivity of MXene coating, PEG@PAN/MXene composite film with MXene coating loading density of 0.70 mg cm-2 exhibits high thermal energy storage density of 120.77 J g-1 and great EMI shielding performance (EMI SE of 34.409 dB and SSE of 49.086 dB cm3 g-1) in X-band (8-12 GHz). Therefore, this advanced composite film can not only help electronic devices prevent the influence of electromagnetic pollution in the X-band but also play an important role in electronic device thermal management. Additionally, the deposition of nano PVDF@SiO2 fibers (289 ± 128 nm) endowed the PMF composite film with great hydrophobic properties (water contact angle of 126.5°) to ensure the stable working of hydrophilic MXene coating, thereby breaks the limitation of humid application environments. The finding paves a new way for the development of novel multifunctional EMI shielding composite films for electronic devices.

9.
Sci Rep ; 14(1): 18046, 2024 Aug 05.
Artigo em Inglês | MEDLINE | ID: mdl-39103407

RESUMO

Rice straw is considered an agricultural waste harmful to the environment, which is abundant in most parts of the world. From this point, the present study is devoted to preparing new composites of two types of glue based on rice straw as a plentiful, low-cost matrix. Straw glue samples were prepared by mixing 20% wt. of rice straw with 80% wt. of animal glue (RS-An) and polyvinyl acetate (RS-PVAC) at different thicknesses of 1, 2, and 3 cm. The chemical composition of the prepared samples was identified by energy dispersive X-ray analysis and their morphology was examined using a scanning electron microscope. The mechanical test explored that RS-An and RS-PVAC respectively required a stress of 25.2 and 25.5 MPa before reaching the breaking point. γ-ray shielding performance was analyzed and determined at numerous photon energies from 0.059 to 1.408 MeV emitted from five-point γ-rays sources using NaI (Tl). Linear attenuation coefficient was calculated by obtaining the area under the peak of the energy spectrum observed from Genie 2000 software in the presence and absence of the sample. The experimental results of mass attenuation coefficient were compared with theoretical data of XCOM software with relative deviation ranging from 0.10 to 2.99%. Geant4 Monte Carlo simulation code was also employed to validate the experimental results. The relative deviation of XCOM and Geant4 outcomes was 0.09-1.77%, which indicates a good agreement between them. Other radiation shielding parameters such as half value layer (HVL), tenth value layer, and mean free path were calculated in three ways: experimentally, theoretically from the XCOM database, and by simulation using Geant4 code. Additionally, effective atomic number (Zeff), effective atomic number (Neff), equivalent atomic number (Zeq), and buildup factors were evaluated. It was confirmed that the γ-ray shielding properties were further boosted by mixing rice straw with the animal glue compared to the synthetic one.

10.
Int J Biol Macromol ; 277(Pt 4): 134563, 2024 Aug 06.
Artigo em Inglês | MEDLINE | ID: mdl-39116969

RESUMO

Despite the plethora of methods reported for fabricating ultraviolet (UV) shielding films using various UV absorbers to date, it remains a major challenge for the development of novel UV shielding films that simultaneously exhibit excellent transparency. In this work, a novel composite film (GA-x-CMC/PVA/PEI) is fabricated by integrating anionic carboxymethylcellulose (CMC), cationic polyethyleneimine (PEI), and polyvinyl alcohol (PVA) via electrostatic and hydrogen bond interactions and further cross-linking with glutaraldehyde (GA). Herein, PVA expands hydrogen bonding networks, reduces film haze, and enhances its mechanical strength. GA acts as a crosslinker in producing Schiff bases with PEI and acetals with CMC and PVA. The synthesized GA-x-CMC/PVA/PEI composite film possesses a notable amount of unsaturated -CH=N- bonds of Schiff base, resulting from the condensation of PEI and GA, which exhibit superior shielding efficiency against both UV-A and UV-B rays while maintaining exceptional transparency, visibility, and simultaneously enhancing mechanical properties and thermal stability. Notably, increasing the content of PEI leads to almost complete shielding of the entire UV spectrum (<400 nm) due to the increasing of the number of -CH=N- unsaturated bonds. Furthermore, the obtained film without any UV-shielding additives has exceptional mechanical properties, hydrophobicity, and antibacterial properties, rendering it a wide application prospect.

11.
Nanomaterials (Basel) ; 14(15)2024 Jul 31.
Artigo em Inglês | MEDLINE | ID: mdl-39120396

RESUMO

The increasing reliance on electronic technologies has elevated the urgency of effective electromagnetic interference (EMI) shielding materials. This review explores the development and potential of magnetite-incorporated one-dimensional (1D) carbon nanostructure hybrids, focusing on their unique properties and synthesis methods. By combining magnetite's magnetic properties with the electrical conductivity and mechanical strength of carbon nanostructures such as carbon nanotubes (CNTs) and carbon fibers (CFs), these hybrids offer superior EMI shielding performance. Various synthesis techniques, including solvothermal synthesis, in situ growth, and electrostatic self-assembly, are discussed in detail, highlighting their impact on the structure and properties of the resulting composites. This review also addresses the challenges in achieving homogeneous dispersion of nanofillers and the environmental and economic considerations of large-scale production. The hybrid materials' multifunctionality, including enhanced mechanical strength, thermal stability, and environmental resistance, underscores their suitability for advanced applications in aerospace, electronics, and environmental protection. Future research directions focus on optimizing synthesis processes and exploring new hybrid configurations to further improve electromagnetic properties and practical applicability.

12.
Nanomicro Lett ; 16(1): 248, 2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-39017957

RESUMO

The demand of high-performance thin-film-shaped deformable electromagnetic interference (EMI) shielding devices is increasing for the next generation of wearable and miniaturized soft electronics. Although highly reflective conductive materials can effectively shield EMI, they prevent deformation of the devices owing to rigidity and generate secondary electromagnetic pollution simultaneously. Herein, soft and stretchable EMI shielding thin film devices with absorption-dominant EMI shielding behavior is presented. The devices consist of liquid metal (LM) layer and LM grid-patterned layer separated by a thin elastomeric film, fabricated by leveraging superior adhesion of aerosol-deposited LM on elastomer. The devices demonstrate high electromagnetic shielding effectiveness (SE) (SET of up to 75 dB) with low reflectance (SER of 1.5 dB at the resonant frequency) owing to EMI absorption induced by multiple internal reflection generated in the LM grid architectures. Remarkably, the excellent stretchability of the LM-based devices facilitates tunable EMI shielding abilities through grid space adjustment upon strain (resonant frequency shift from 81.3 to 71.3 GHz @ 33% strain) and is also capable of retaining shielding effectiveness even after multiple strain cycles. This newly explored device presents an advanced paradigm for powerful EMI shielding performance for next-generation smart electronics.

13.
Int J Biol Macromol ; 276(Pt 1): 133897, 2024 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-39019368

RESUMO

Liquid metal (LM) based electromagnetic interference (EMI) shielding materials with high conductivity and continuous deformation capacity are important needs for meeting modern advanced electronic equipment. However, an independent free-standing film with LM is difficult to achieve due to its unique fluidity properties. Here, a simple alternating filtration film-forming method was utilized to orderly construct a sandwiched EMI shielding film with LM stabilized by bio-based oxhide gelatin (gel) as the intermediate conductive layer, and two films of aramid nanofibers/oxhide gel (ANF/gel) as the external insulating protective layers. This design not only prevents LM from being exposed to environmental conditions, but also reduces the risk of chemical corrosion in practical applications. Under optimal LM addition conditions, the sandwiched film (0.3-3 L) exhibited better EMI shielding performance of 50.4 dB in the X-band than the blended film (0.7 dB), as well as excellent mechanical properties (tensile strength of 65.8 MPa, strain 8.6 %). More importantly, the sandwiched film still maintained reliable EMI shielding performance after being experienced largely physical deformation. This study provides a new solution for preparing LM-based EMI shielding composites, and is expected to arouse pursuit of high EMI shielding effects of bio-based gel while also paying attention to their safety.

14.
Int J Biol Macromol ; 277(Pt 1): 133891, 2024 Jul 16.
Artigo em Inglês | MEDLINE | ID: mdl-39025190

RESUMO

Electronic systems and telecommunications have grown in popularity, leading to increasing electromagnetic (EM) radiation pollution. Environmental protection from EM radiation demands the use of environmentally friendly products. The design of EM interference (EMI) shielding materials using resources like nanocellulose (NC) is gaining traction. Cellulose, owing to its biocompatibility, biodegradability, and excellent mechanical and thermal properties, has attracted significant interest for developing EMI shielding materials. Recent advancements in cellulose-based EMI shielding materials, particularly modified cellulosic composites, are highlighted in this study. By incorporating metallic coatings compounded with conductive fillers and modified with inherently conductive elements, conductivity and effectiveness of EMI shielding can be significantly improved. This review discusses the introduction of EMI shields, cellulose, and NC, assessing environmentally friendly EMI shield options and diverse NC-based composite EMI shields considering their low reflectivity. The study offers new insights into designing advanced NC-based conductive composites for EMI shielding applications.

15.
ACS Nano ; 2024 Jul 22.
Artigo em Inglês | MEDLINE | ID: mdl-39038287

RESUMO

Indoor UV damage is a serious problem that is often ignored. Common glasses cannot filter UV rays well and have fragility and environmental issues. UV-shielding transparent wood (TW) holds promise, yet striking the right balance between blocking UV rays and allowing sufficient visible-light transmission poses a challenge. The pronounced capillary force, fueled by persistent moisture and extractives in wood, alongside the existence of multiphase interfaces, collectively hinder the uniform penetration of polymers and the effective dispersion of nanomaterials within the wood skeleton. Here, we incorporate high-pressure supercritical CO2 fluid-assisted impregnation (HSCFI) into fabricating UV-shielding TW. The supercritical CO2 pretreatment efficiently eliminates moisture and refines wood structure by extracting polar substances, resulting in a prominent 52.4% increase in average water permeability. Subsequently, this HSCFI method facilitates the infiltration of methyl methacrylate (MMA) monomer and Ce-ZnO nanorods (NRDs) into the refined anhydrous wood, leveraging the excellent solvency of supercritical CO2 for MMA. The impregnation rate of PMMA undergoes a substantial increase from 34.5 to 59.1%. With the robust UV-blocking capability of Ce-ZnO NRDs, thanks to dual-valence Ce doping widening the ZnO energy gap via the Burstein-Moss effect and their unique photoactive microstructure featuring a solid prism with a sharp hexahedral pyramidal tip, along with intrinsic physical scattering/reflection actions, Ce-ZnO NRDs@TW achieves an impressive 99.6% UVA radiation blockage (the highest for TW) and maintains high visible-light transmission (83.2%). Furthermore, Ce-ZnO NRDs@TW presents favorable energy-saving, sound absorption, and antifungal abilities, making it a promising candidate for future green buildings.

16.
ACS Appl Mater Interfaces ; 16(29): 38490-38500, 2024 Jul 24.
Artigo em Inglês | MEDLINE | ID: mdl-38980000

RESUMO

High-performance electromagnetic interference (EMI) shielding materials with high flexibility, low density, and hydrophobic surface are crucial for modern integrated electronics and telecommunication systems in advanced industries like aerospace, military, artificial intelligence, and wearable electronics. In this study, we present flexible and hydrophobic MXene/Ni-coated polyester (PET) fabrics featuring a double-layered structure, fabricated via a facile and scalable dip-dry coating process followed by electroless nickel plating. Increasing the dip-dry coating iterations up to 10 cycles boosts the MXene loading content (∼31 wt %) and electrical conductivity (∼86 S/cm) of MXene-coated PET fabrics, while maintaining constant porosity (∼95%). The addition of a Ni layer enhances hydrophobicity, achieving a high water contact angle of ∼114° compared to only MXene-coated PET fabrics (∼49°). Furthermore, the 30 µm thick MXene/Ni-coated PET fabric demonstrates superior electrical conductivity (∼113.8 S/cm) and EMI shielding effectiveness (∼35.7 dB at 8-12 GHz) compared to only MXene- or Ni-coated PET fabrics. The EMI shielding performance of the MXene/Ni-coated PET fabric remains more stable in an air environment than only MXene-coated fabrics due to the outer Ni layer with excellent hydrophobicity and oxidation stability. Additionally, the MXene/Ni-coated PET fabric exhibits impressive Joule heating performance, swiftly converting electrical energy into heat and reaching high steady-state temperatures (32-92 °C) at low applied voltages (0.5-1.5 V).

17.
ACS Appl Mater Interfaces ; 16(29): 38620-38630, 2024 Jul 24.
Artigo em Inglês | MEDLINE | ID: mdl-38982840

RESUMO

Polymers are often used as adhesives to improve the mechanical properties of flexible electromagnetic interference (EMI) shielding layered films, but the introduction of these insulating adhesives inevitably reduces the EMI performance. Herein, ultrafine aramid nanofibers (UANF) with a diameter of only 2.44 nm were used as the binder to effectively infiltrate and minimize the insulating gaps in MXene films, for balancing the EMI shielding and mechanical properties. Combining the evaporation-induced scalable assembly assisted by blade coating, flexible large-scale MXene/UANF films with highly aligned and compact MXene stacking are successfully fabricated. Compared with the conventional ANF with a larger diameter of 7.05 nm, the UANF-reinforced MXene film exhibits a "brick-mortar" structure with higher orientation and compacter stacking MXene nanosheets, thus showing the higher mechanical properties, electrical conductivity, and EMI shielding performance. By optimizing MXene content, the MXene/UANF film can achieve the optimal tensile strength of 156.9 MPa, a toughness of 2.9 MJ m-3, satisfactory EMI shielding effectiveness (EMI SE) of 40.7 dB, and specific EMI SE (SSE/t) of 22782.4 dB cm2/g). Moreover, the composite film exhibits multisource thermal conversion functions including Joule heating and photothermal conversion. Therefore, the multifunctional MXene/UANF EMI shielding film with flexibility, foldability, and robust mechanical properties shows the practical potential in complex application environments.

18.
Small ; : e2402510, 2024 Jul 10.
Artigo em Inglês | MEDLINE | ID: mdl-38984762

RESUMO

With the rapid advancement of electronic technology, traditional textiles are challenged to keep up with the demands of wearable electronics. It is anticipated that multifunctional textile-based electronics incorporating energy storage, electromagnetic interference (EMI) shielding, and photothermal conversion are expected to alleviate this problem. Herein, a multifunctional cotton fabric with hierarchical array structure (PPy/NiCoAl-LDH/Cotton) is fabricated by the introduction of NiCoAl-layered double hydroxide (NiCoAl-LDH) nanosheet arrays on cotton fibers, followed by polymerization and growth of continuous dense polypyrrole (PPy) conductive layers. The multifunctional cotton fabric shows a high specific areal capacitance of 754.72 mF cm-2 at 5 mA cm-2 and maintains a long cycling life (80.95% retention after 1000 cycles). The symmetrical supercapacitor assembled with this fabric achieves an energy density of 20.83 Wh cm-2 and a power density of 0.23 mWcm-2. Moreover, the excellent electromagnetic interference shielding (38.83 dB), photothermal conversion (70.2 °C at 1000 mW cm-2), flexibility and durability are also possess by the multifunctional cotton fabric. Such a multifunctional cotton fabric has great potential for using in new energy, smart electronics, and thermal management applications.

19.
Materials (Basel) ; 17(13)2024 Jun 21.
Artigo em Inglês | MEDLINE | ID: mdl-38998135

RESUMO

This paper summarizes the possibility of employing knitted textile barriers as a shield against electromagnetic fields to protect the human body from their negative impact. Ten variants of knitted fabrics made of electrically conductive yarns, steel, and copper wire that differed in stitch pattern, structural parameters, and raw material, were designed, manufactured, and tested. The knitted fabrics produced differed in structural parameters, including course and wale density, surface density, thickness, thread length in the loop, wale and course take-up, volume cover factor, and surface porosity. These parameters were examined in accordance with the research methodology used in knitting. Barrier measurements were taken in the direction of the wales and in the direction of the courses for two frequencies of electromagnetic fields: 2-4 GHz and 4-7 GHz. It was observed that the shielding effectiveness of the manufactured materials depends on the structural parameters of the fabric, the stiches applied, and the type of yarn.

20.
Materials (Basel) ; 17(13)2024 Jul 05.
Artigo em Inglês | MEDLINE | ID: mdl-38998407

RESUMO

The main objective of this work was to propose and evaluate a methodology for shielding-gas selection in additive manufacturing assisted by wire arc additive manufacturing (WAAM) with an austenitic stainless steel as feedstock. To validate the proposed methodology, the impact of multi-component gases was valued using three different Ar-based blends recommended as shielding gas for GMA (gas metal arc) of the target material, using CMT (cold metal transfer) as the process version. This assessment considered features that potentially affect the building of the case study of thin walls, such as metal transfer regularity, deposition time, and geometrical and metallurgical characteristics. Different settings of wire-feed speeds were conceived to maintain a similar mean current (first constraint for comparison's sake) among the three gas blends. This approach implied different mean wire-feed speeds and simultaneously forced a change in the deposition speed to maintain the same amount of material deposited per unit of length (second comparison constraint). The composition of the gases affects the operational performance of the shielding gases. It was concluded that by following this methodology, shielding-gas selection decision-making is possible based on the perceived characteristics of the different commercial blends.

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