Experimental evaluation of low-displacement compression ignited engines operating with hydroxy gas as a supplementary gaseous fuel.

A large proportion of annual production of worldwide greenhouses gases results from the use of internal combustion engines. This experimental work evaluates the influence of dual-fuel operation on the overall emissions of a low-displacement compression-ignition engine based on operational conditions such as torque, rotational speed, and load. Hydroxy gas is used as a supplementary gaseous fuel while using pure diespel or palm oil biodiesel as baseline fuels. The CO, CO2, NOx, and HC emissions levels were carefully characterized through experimental measurements and statistical analysis. The influence of hydroxy enrichment was also examined on the engine's fuel consumption. The study incorporates an in-house hydroxy generator to store and supply the gas in the intake air system using an electrolyzer. The results demonstrated that the ANOVA analysis provides accurate predictions compared to experimental measurements with less than 5% relative error. The use of hydroxy reduces the SFC by up to 25%, which represents an economic advantage of dual-fuel operation, additionally it decreases CO, HC, and CO2 emissions. However, with hydroxy enrichment, NOx emissions levels escalate at medium and high loads. Overall, hydroxy enrichment demonstrates to be a robust alternative from an environmental and economic perspective. Future research will be focused on evaluating the biodiesel - hydroxy dual operation, broadening the spectrum of biodiesel concentration percentages, and selecting different raw materials for biofuel production.

Comparative life cycle assessment of three 2030 scenarios of the Brazilian cement industry.

The cement industry is intensive in energy and feedstock use. It includes three main phases: raw materials and energy supply, transport, and manufacturing. The sector is known for its considerable environmental impacts. The increase in energy efficiency and the use of non-fossil fuels and raw materials are considered mature technologies in cement industries. We evaluate different environmental impacts of the production of 1 t of cement in four Brazilian scenarios. We compare one business-as-usual reference scenario (case 1) to three alternative 2030 carbon mitigation sectoral plan scenarios (cases 2, 3a, and 3b) that assume mature technologies. We analyze all 18 impact categories within the ReCiPe 2016 Life Cycle Assessment methodology. Results show reductions in 17 impact categories, ranging from no change in ozone depletion (case 2) to 39% reduction in fossil resource scarcity (case 3b). The effects on climate change decreased 14% in case 2 and 33% in cases 3a and 3b. The clinkerization process is the greatest contributor to atmospheric impacts, while raw material consumption to toxicity impacts. In contrast, there is no single main process contributing to resource depletion impacts. The changes in cement production lead to carbon emission reductions above expected levels and to reductions in other environmental impact categories modeled in ReCiPe 2016 method.

Energy demand and emissions of a passenger vehicle fueled with CNG, gasohol, hydrous ethanol and wet ethanol based on the key points of the WLTC.

A compact sedan vehicle powered by a 1.4 dm3 spark ignition engine fueled with compressed natural gas (CNG), Brazilian gasoline, hydrous ethanol 95% v/v and wet ethanol 88% v/v was evaluated throughout the Worldwide harmonized Light vehicles Test Cycle (WLTC) key points. The vehicle operating points with longest residence time on the WLTC were selected to fuel consumption and emissions evaluation at steady state conditions. The top five key operating points reported in this work accounted for 22% of the total time spent in the entire cycle. The results indicated a significant reduction on greenhouse gases (GHG) emissions and energy demand for operation with CNG. The ethanol-water blends provided reduced emissions of nitrogen oxides (NOx), but increased specific fuel consumption, carbon monoxide (CO) and GHG emissions in comparison to CNG and gasoline. The operation with gasoline resulted in the minimum CO emissions for all fuels tested, as well as the best fuel consumption between liquid fuels, despite the highest values of carbon dioxide (CO2), and increased NOx. Even though ethanol produced little total unburned hydrocarbons (THC), the emissions of alcohols and aldehydes raised an alert for this renewable fuel, whereas CNG emitted the least amount of such pollutants.

Emissions of an agricultural engine using blends of diesel and hydrous ethanol / Emissões de motor agrícola utilizando misturas de óleo Diesel e etanol hidratado

The growing global demand of energy, the decrease of petroleum reserves and the current of environmental contamination problems, make it imperative to study renewable energy sources for use in internal combustion engines, in order to decrease the dependence on fossil fuels and reduce emissions of pollutant gases. This study aimed to evaluate the emissions of a diesel-cycle engine of an agricultural tractor that uses diesel S500 (B5) mixed with 3, 6, 9, 12 and 15% of hydrous ethanol. It determined emissions of CO2 (ppm), NOx (ppm), and opacity (k value) of gases. A standard procedure was applied considering eight operating modes (M1, M2, M3, M4, M5, M6, M7, and M8) by breaking with an electric dynamometer in a laboratory. The experimental design was completely randomized, with 60 replicates and a 6 x 8 factorial design. Greater opacity and gas emissions were observed when the engine operated with 3% ethanol, while lower emissions occurred with 12 and 15%. With these fuels, the reduction of opacity, CO2, and NOx, in relation to diesel oil, was 24.49 and 26.53%, 4.96 and 5.15%, and 6.59 and 9.70%, respectively. In conclusion, the addition of 12 and 15% ethanol in diesel oil significantly reduces engine emissions.(AU)

A crescente demanda mundial por energia, a diminuição das reservas de petróleo e os atuais problemas de poluição ambiental, instigam o estudo de fontes renováveis de energia para utilização nos motores de combustão interna, visando à diminuição da dependência do combustível fóssil e redução das emissões de gases poluentes. Este trabalho teve por objetivo avaliar as emissões de um motor ciclo Diesel de um trator agrícola utilizando óleo Diesel S500 (B5) e, em mistura com 3, 6, 9, 12 e 15% de etanol hidratado. As variáveis avaliadas foram as emissões de CO2 (ppm), NOx (ppm) e a opacidade (valor k) dos gases. Para a avaliação utilizou-se procedimento normalizado, com aplicação de oito modos de operação (M1; M2; M3; M4; M5; M6; M7 e M8), por meio da frenagem com um dinamômetro elétrico, em laboratório. O delineamento experimental foi inteiramente casualizado, com 60 repetições e no esquema fatorial 6x8. Os maiores valores de opacidade e emissões de CO2 e NOx foram alcançados com 3% de etanol, enquanto que os menores valores foram obtidos quando o motor utilizou 12 e 15%. Com estes combustíveis, a redução da opacidade, CO2 e NOx, em relação ao óleo diesel, foi de 24,49 e 26,53%; 4,96 e 5,15% e 6,59 e 9,70%, respectivamente. Conclui-se que, a adição de 12 e 15% de etanol no óleo diesel reduz significativamente as emissões do motor.(AU)

Emissions of an agricultural engine using blends of diesel and hydrous ethanol / Emissões de motor agrícola utilizando misturas de óleo Diesel e etanol hidratado

The growing global demand of energy, the decrease of petroleum reserves and the current of environmental contamination problems, make it imperative to study renewable energy sources for use in internal combustion engines, in order to decrease the dependence on fossil fuels and reduce emissions of pollutant gases. This study aimed to evaluate the emissions of a diesel-cycle engine of an agricultural tractor that uses diesel S500 (B5) mixed with 3, 6, 9, 12 and 15% of hydrous ethanol. It determined emissions of CO2 (ppm), NOx (ppm), and opacity (k value) of gases. A standard procedure was applied considering eight operating modes (M1, M2, M3, M4, M5, M6, M7, and M8) by breaking with an electric dynamometer in a laboratory. The experimental design was completely randomized, with 60 replicates and a 6 x 8 factorial design. Greater opacity and gas emissions were observed when the engine operated with 3% ethanol, while lower emissions occurred with 12 and 15%. With these fuels, the reduction of opacity, CO2, and NOx, in relation to diesel oil, was 24.49 and 26.53%, 4.96 and 5.15%, and 6.59 and 9.70%, respectively. In conclusion, the addition of 12 and 15% ethanol in diesel oil significantly reduces engine emissions.

A crescente demanda mundial por energia, a diminuição das reservas de petróleo e os atuais problemas de poluição ambiental, instigam o estudo de fontes renováveis de energia para utilização nos motores de combustão interna, visando à diminuição da dependência do combustível fóssil e redução das emissões de gases poluentes. Este trabalho teve por objetivo avaliar as emissões de um motor ciclo Diesel de um trator agrícola utilizando óleo Diesel S500 (B5) e, em mistura com 3, 6, 9, 12 e 15% de etanol hidratado. As variáveis avaliadas foram as emissões de CO2 (ppm), NOx (ppm) e a opacidade (valor k) dos gases. Para a avaliação utilizou-se procedimento normalizado, com aplicação de oito modos de operação (M1; M2; M3; M4; M5; M6; M7 e M8), por meio da frenagem com um dinamômetro elétrico, em laboratório. O delineamento experimental foi inteiramente casualizado, com 60 repetições e no esquema fatorial 6x8. Os maiores valores de opacidade e emissões de CO2 e NOx foram alcançados com 3% de etanol, enquanto que os menores valores foram obtidos quando o motor utilizou 12 e 15%. Com estes combustíveis, a redução da opacidade, CO2 e NOx, em relação ao óleo diesel, foi de 24,49 e 26,53%; 4,96 e 5,15% e 6,59 e 9,70%, respectivamente. Conclui-se que, a adição de 12 e 15% de etanol no óleo diesel reduz significativamente as emissões do motor.

Sample preparation for the analysis of fire debris - Past and present.

Identification of ignitable liquids from fire debris is such a major part of an arson investigation that much time and effort has gone into advancing sample preparation techniques to capture complicated and unexpected hydrocarbon compounds. Advancements in sample preparation have been made in order to account for biodegradation of commonly used accelerants, rarely encountered compounds, such as vegetable oils, biodiesel, and alcohols. Improvements have also been made to manage interference from the sample matrix, particularly with regards to new materials. This paper is a review of the sample preparation techniques that are foundational to fire debris analysis as well as recent advances. Also explored are modifications to the traditional sample preparation methods to accommodate the analysis of environmental samples (soil and water), and the presence of vegetable oils and biofuels on the fire scene.

Performance of an agricultural engine using mineral diesel and ethanol fuels / Desempenho de um motor agrícola utilizando Diesel mineral e etanol

The global demand for alternatives for mineral diesel oil is growing due to the need for satisfying sustainability and environmental requirements, forcing industries and research institutions to develop new alternative fuels. The objective of this study was to evaluate the performance parameters of an agricultural engine using two different fuels: mineral diesel oil and ethanol. The experiment was conducted on a dynamometric stand using two engines for agricultural use but with a modified fuel injection system, suitable for both diesel and ethanol, in the speed range 1200-2300rpm. The performance of the engines was analyzed considering the power take-off from the tractors for each fuel, as established in the standard NBR ISO 1585. The data obtained showed that at the working speed that provides 540rpm at the power take-off, the engine performance changed when powered by ethanol, with a reduction in the maximum power and increased specific fuel consumption.

A demanda mundial por combustíveis alternativos ao óleo Diesel mineral vem crescendo, tanto pela sustentabilidade, quanto por exigências ambientais. Isso faz com que as indústrias e as instituições de pesquisa desenvolvam novas alternativas para o uso destes combustíveis. Nesse contexto, objetivou-se avaliar os parâmetros de desempenho de um motor agrícola, com dois diferentes combustíveis, Diesel mineral e etanol. O experimento foi realizado em bancada dinamométrica, utilizando dois motores de uso agrícola, porém, com alterações no sistema de injeção de combustível, Diesel e etanol, na faixa de rotação entre 1200 e 2300rpm. O desempenho dos motores foi analisado por meio da tomada de potência dos tratores para cada combustível, conforme estabelece a norma NBR ISO 1585. A partir dos dados obtidos, concluiu-se que, ao considerar a rotação de trabalho que fornece 540rpm na tomada de potência, houve alteração no desempenho do motor movido a etanol, com redução da potência máxima e aumento do consumo específico de combustível.

Performance of an agricultural engine using mineral diesel and ethanol fuels / Desempenho de um motor agrícola utilizando Diesel mineral e etanol

The global demand for alternatives for mineral diesel oil is growing due to the need for satisfying sustainability and environmental requirements, forcing industries and research institutions to develop new alternative fuels. The objective of this study was to evaluate the performance parameters of an agricultural engine using two different fuels: mineral diesel oil and ethanol. The experiment was conducted on a dynamometric stand using two engines for agricultural use but with a modified fuel injection system, suitable for both diesel and ethanol, in the speed range 1200-2300rpm. The performance of the engines was analyzed considering the power take-off from the tractors for each fuel, as established in the standard NBR ISO 1585. The data obtained showed that at the working speed that provides 540rpm at the power take-off, the engine performance changed when powered by ethanol, with a reduction in the maximum power and increased specific fuel consumption. (AU)

A demanda mundial por combustíveis alternativos ao óleo Diesel mineral vem crescendo, tanto pela sustentabilidade, quanto por exigências ambientais. Isso faz com que as indústrias e as instituições de pesquisa desenvolvam novas alternativas para o uso destes combustíveis. Nesse contexto, objetivou-se avaliar os parâmetros de desempenho de um motor agrícola, com dois diferentes combustíveis, Diesel mineral e etanol. O experimento foi realizado em bancada dinamométrica, utilizando dois motores de uso agrícola, porém, com alterações no sistema de injeção de combustível, Diesel e etanol, na faixa de rotação entre 1200 e 2300rpm. O desempenho dos motores foi analisado por meio da tomada de potência dos tratores para cada combustível, conforme estabelece a norma NBR ISO 1585. A partir dos dados obtidos, concluiu-se que, ao considerar a rotação de trabalho que fornece 540rpm na tomada de potência, houve alteração no desempenho do motor movido a etanol, com redução da potência máxima e aumento do consumo específico de combustível. (AU)

Performance of an agricultural engine using mineral diesel and ethanol fuels

ABSTRACT: The global demand for alternatives for mineral diesel oil is growing due to the need for satisfying sustainability and environmental requirements, forcing industries and research institutions to develop new alternative fuels. The objective of this study was to evaluate the performance parameters of an agricultural engine using two different fuels: mineral diesel oil and ethanol. The experiment was conducted on a dynamometric stand using two engines for agricultural use but with a modified fuel injection system, suitable for both diesel and ethanol, in the speed range 1200-2300rpm. The performance of the engines was analyzed considering the power take-off from the tractors for each fuel, as established in the standard NBR ISO 1585. The data obtained showed that at the working speed that provides 540rpm at the power take-off, the engine performance changed when powered by ethanol, with a reduction in the maximum power and increased specific fuel consumption.

RESUMO: A demanda mundial por combustíveis alternativos ao óleo Diesel mineral vem crescendo, tanto pela sustentabilidade, quanto por exigências ambientais. Isso faz com que as indústrias e as instituições de pesquisa desenvolvam novas alternativas para o uso destes combustíveis. Nesse contexto, objetivou-se avaliar os parâmetros de desempenho de um motor agrícola, com dois diferentes combustíveis, Diesel mineral e etanol. O experimento foi realizado em bancada dinamométrica, utilizando dois motores de uso agrícola, porém, com alterações no sistema de injeção de combustível, Diesel e etanol, na faixa de rotação entre 1200 e 2300rpm. O desempenho dos motores foi analisado por meio da tomada de potência dos tratores para cada combustível, conforme estabelece a norma NBR ISO 1585. A partir dos dados obtidos, concluiu-se que, ao considerar a rotação de trabalho que fornece 540rpm na tomada de potência, houve alteração no desempenho do motor movido a etanol, com redução da potência máxima e aumento do consumo específico de combustível.

Comparison between biodegradable polymers from cassava starch and glycerol as additives to biogas production / Comparação entre glicerol e polímero biodegradável a base de mandioca como aditivos na biodigestão anaeróbia

In this study, we compared cassava starch-based biodegradable polymers (PBMs) and glycerol (G) as additives used to increase biogas production from the co-digestion of swine wastewater (ARS). We chose to work with an inoculum comprising 40% (v/v) of the total volume of the reactor; this inoculum was obtained from a Canadian model digester for treating swine waste. In the anaerobic digestion process, batch reactors were used on a laboratory scale with a total volume of approximately 4 L and a working volume of 3.2 L. Three treatments were conducted to compare the efficiency of solid removal, the chemical oxygen demand (COD), and the production of biogas. The first treatment contained only swine waste; the second included the addition of glycerol at 1, 3, and 5% (w/v); and the third treatment included the addition of 1, 3, and 5% (w/v) of PBM residue in relation to the swine wastewater. From the results, it can be concluded that higher yields were obtained for the treatment with 3% PBM and 1% glycerol. Most treatments showed high removal rates of total solids and total volatile solids. Reductions lower than 70% were obtained only for treatments with PBM and glycerol at a ratio of 5%.

O presente trabalho tem por finalidade comparar o potencial aditivo no aumento da produção de biogás de polímeros biodegradáveis a base de fécula de mandioca (PBM) e do glicerol, já comumente empregado com essa finalidade, ambos em co-digestão com água residuária de suinocultura. Utilizou-se como matéria-prima para produção de biogás, água residual de suinocultura, material plástico biodegradável produzido a partir de fécula de mandioca e glicerina bruta proveniente do processo de produção de biodiesel. Optou-se por trabalhar com 40% (v/v) de inóculo do volume total do reator. Para a condução do processo de digestão anaeróbia empregaram-se reatores com alimentação batelada de escala laboratorial de volume total de aproximadamente 4 litros e volume útil de 3,2 litros. Foram realizados 3 tratamentos visando comparar a eficiência da remoção de sólidos, demanda química de oxigênio e produção de biogás. O primeiro tratamento conteve apenas resíduo de suíno, o segundo a adição de glicerol em percentuais de 1, 3 e 5% (m/v) no mesmo resíduo e o terceiro a adição de 1, 3 e 5% (m/v) do polímero biodegradável a base de fécula de mandioca ao resíduo suíno. A partir dos resultados pode-se concluir que as maiores produções foram obtidas no tratamento de 3% de PBM e 1% de glicerol. A maioria dos tratamentos apresentou elevadas taxas de remoção de sólidos totais e sólidos totais voláteis. Apen

Comparison between biodegradable polymers from cassava starch and glycerol as additives to biogas production / Comparação entre glicerol e polímero biodegradável a base de mandioca como aditivos na biodigestão anaeróbia

In this study, we compared cassava starch-based biodegradable polymers (PBMs) and glycerol (G) as additives used to increase biogas production from the co-digestion of swine wastewater (ARS). We chose to work with an inoculum comprising 40% (v/v) of the total volume of the reactor; this inoculum was obtained from a Canadian model digester for treating swine waste. In the anaerobic digestion process, batch reactors were used on a laboratory scale with a total volume of approximately 4 L and a working volume of 3.2 L. Three treatments were conducted to compare the efficiency of solid removal, the chemical oxygen demand (COD), and the production of biogas. The first treatment contained only swine waste; the second included the addition of glycerol at 1, 3, and 5% (w/v); and the third treatment included the addition of 1, 3, and 5% (w/v) of PBM residue in relation to the swine wastewater. From the results, it can be concluded that higher yields were obtained for the treatment with 3% PBM and 1% glycerol. Most treatments showed high removal rates of total solids and total volatile solids. Reductions lower than 70% were obtained only for treatments with PBM and glycerol at a ratio of 5%.

O presente trabalho tem por finalidade comparar o potencial aditivo no aumento da produção de biogás de polímeros biodegradáveis a base de fécula de mandioca (PBM) e do glicerol, já comumente empregado com essa finalidade, ambos em co-digestão com água residuária de suinocultura. Utilizou-se como matéria-prima para produção de biogás, água residual de suinocultura, material plástico biodegradável produzido a partir de fécula de mandioca e glicerina bruta proveniente do processo de produção de biodiesel. Optou-se por trabalhar com 40% (v/v) de inóculo do volume total do reator. Para a condução do processo de digestão anaeróbia empregaram-se reatores com alimentação batelada de escala laboratorial de volume total de aproximadamente 4 litros e volume útil de 3,2 litros. Foram realizados 3 tratamentos visando comparar a eficiência da remoção de sólidos, demanda química de oxigênio e produção de biogás. O primeiro tratamento conteve apenas resíduo de suíno, o segundo a adição de glicerol em percentuais de 1, 3 e 5% (m/v) no mesmo resíduo e o terceiro a adição de 1, 3 e 5% (m/v) do polímero biodegradável a base de fécula de mandioca ao resíduo suíno. A partir dos resultados pode-se concluir que as maiores produções foram obtidas no tratamento de 3% de PBM e 1% de glicerol. A maioria dos tratamentos apresentou elevadas taxas de remoção de sólidos totais e sólidos totais voláteis. Apen

Aspectos do coprocessamento de resíduos em fornos de clínquer / Aspects of waste co-processing in clinker kilns

A prática do coprocessamento de resíduos na indústria de cimento tem se expandido devido à necessidade crescente de uma destinação ambiental e socialmente mais adequada de resíduos perigosos provenientes de diversos processos industriais. O objetivo deste trabalho foi realizar uma revisão sobre o coprocessamento de resíduos em fornos de clínquer, no Brasil e no mundo, visando contribuir para a otimização dos processos, identificando os aspectos já estudados e os que ainda demandam pesquisas. Foram abordados aspectos socioambientais e tecnológicos do coprocessamento, bem como a análise do ciclo de vida (ACV) na produção de cimento, e a produção técnico-científica sobre o coprocessamento.

The practice of co-processing of residues has increased due to the requirement of environmental and social friendly disposal of dangerous wastes from several industrial processes. The aim of this work was to perform a revision of co-processing of residues in Brazil and in the world, aiming at process optimization and also to identify the aspects already studied as well as those which still request research efforts. Social, environmental, and technological aspects of co-processing were discussed in the present work as well as the life cycle analysis (LCA) in the cement production and the technical and scientific literature about co-processing.

Performance of preheated crude soybean oildiesel blends as fuel in agricultural engines / Influência da colheita mecanizada na produção cafeeira

The mechanized harvest of coffee in the South of Minas Gerais has promoted a better product quality and loss reduction, increasing producers profit. However, studies on the effect of mechanization on productivity of the culture throught the years are needed since the mechanized harvest not will done can damage the plant. This work was aimed at evaluating the effect of mechanized harvest the coffee productivity comparing it with manual harvest. A completely randomized design with 8 treatments and 10 replications was adopted, in random parcels with 40 plants in average in the harvests of 2000 and 2004. The productivity of coffee was not influenced by mechanized harvest through the years, even when using the harvest one or twice on coffee plants field. The vibration connecting rods increase produced higher amount of harvested grains, however, the defoliation increased proportionally to the vibration whit two passes of harvester defoliation was greater than the manual harvester in all harvests evaluated periods.(AU)

A colheita mecanizada de café no sul de Minas Gerais tem promovido uma melhor qualidade do produto e redução de perdas, aumentando os lucros dos cafeicultores. Porém, a lavoura cafeeira ainda necessita de estudos sobre o efeito da mecanização na produtividade da cultura ao longo dos anos, uma vez que a colheita mecanizada malconduzida pode causar danos na planta. O objetivo deste trabalho foi avaliar o efeito da colheita mecanizada na produtividade da cultura cafeeira, ao longo dos anos, comparativamente com colheita no sistema manual. O delineamento utilizado foi o inteiramente casualizado, com 8 tratamentos e 3 repetições, em parcelas aleatórias contendo em média 40 plantas nas safras de 2000 a 2004, realizando a colheita tanto de forma mecanizada quanto manual. A produtividade da lavoura cafeeira não foi influenciada pela colheita mecanizada ao longo dos anos, passando a colhedora uma ou duas vezes na lavoura. O aumento de vibração das hastes promoveu uma maior quantidade de grãos colhidos, porém a desfolha aumentou proporcionalmente ao aumento de vibração. Com duas passadas da colhedora, a desfolha foi maior que a colheita manual em todas as safras agrícolas estudadas.(AU)