Formability of the 5754-Aluminum Alloy Deformed by a Modified Repetitive Corrugation and Straightening Process.

Sheets of 5754-aluminum alloy processed by a modified repetitive corrugation and straightening (RCS) process were tested in order to measure their formability. For this purpose, forming limit curves were derived. They showed that the material forming capacity decreased after being processed by RCS. However, they kept good formability in the initial stages of the RCS process. The formability study was complemented with microstructural analysis (derivation of texture) and mechanical tests to obtain the strain-rate sensitivity. The texture analysis was done by employing X-ray diffraction, obtaining pole figures, and the orientation distribution function. It was noticed that the initial texture was conserved after successive RCS passes, but the intensity dropped. RCS process did not induce ß-fiber, contrary to common deformation process. The strain-rate sensitivity coefficient was measured through tensile tests at different temperatures and strain rates; the coefficient of the samples processed after one and two passes were still relatively high, indicating the capacity to delay necking, in agreement with the good formability observed in the initial passes of the RCS process.

Comparative in Mechanical Behavior of 6061 Aluminum Alloy Welded by Pulsed GMAW with Different Filler Metals and Heat Treatments.

Precipitation hardening aluminum alloys are used in many industries due to their excellent mechanical properties, including good weldability. During a welding process, the tensile strength of the joint is critical to appropriately exploit the original properties of the material. The welding processes are still under study, and gas metal arc welding (GMAW) in pulsed metal-transfer configuration is one of the best choices to join these alloys. In this study, the welding of 6061 aluminum alloy by pulsed GMAW was performed under two heat treatment conditions and by using two filler metals, namely: ER 4043 (AlSi5) and ER 4553 (AlMg5Cr). A solubilization heat treatment T4 was used to dissolve the precipitates of ß"- phase into the aluminum matrix from the original T6 heat treatment, leading in the formation of ß-phase precipitates instead, which contributes to higher mechanical resistance. As a result, the T4 heat treatment improves the quality of the weld joint and increases the tensile strength in comparison to the T6 condition. The filler metal also plays an important role, and our results indicate that the use of ER 4043 produces stronger joints than ER 4553, but only under specific processing conditions, which include a moderate heat net flux. The latter is explained because Mg, Si and Cu are reported as precursors of the production of ß"- phase due to heat input from the welding process and the redistribution of both: ß" and ß precipitates, causes a ductile intergranular fracture near the heat affected zone of the weld joint.

Intensification of Electrochemical Performance of AA7075 Aluminum Alloys Using Rare Earth Functionalized Water-Based Polymer Coatings.

This work reports the effect of different amounts of ceria nanoparticles on UV resistance and barrier properties of water-based polyurethane (WPU) on glass and AA7075 aluminum alloy substrates. Hybrid coatings were synthesized from an aliphatic WPU⁻HDI (1,6-hexamethylene di-isocyanate) and cerium oxide nanoparticles (CeO2) with an average particle size distribution of about 25 nm. Different nanoceria amounts (1, 3 and 5 wt %), mixing times (30, 60 and 120 min) and methods to disperse the nanostructures into the polymer matrix (magnetic stirring and sonication) were evaluated. Initially, the dispersion of CeO2 nanoparticles embedded in the polymer matrix and displacement in the corrosion potential (Ecorr) were analyzed by confocal scanning laser microscopy (CLSM) and open circuit potential (Eocp) measurements. According to this behavior, the dispersion and water ratio required during the polymerization process were established. Coated samples obtained after the second stage were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), atomic force microscopy (AFM) and optical light microscopy. In addition, optical measurements on glass substrates were evaluated with UV-vis spectroscopy. The effect of the synthesis parameters on the corrosion behavior of WPU⁻CeO2/AA7075 systems was investigated with Eocp and electrochemical impedance spectroscopy (EIS) in a 3 wt % NaCl solution. In addition, the films were subjected to 180 h of accelerated weathering. The results show that the combination of specific nanoceria addition with the optimal synthesis parameters enhances optical transparence of WPU as well as barrier properties. From these, the coated specimens prepared with 3 wt % of ceria content and sonicated for 30 min showed a highly dispersed system, which results in a high charge transfer resistance. The observed properties in clear coats deposited on metallic substrates suggested an improvement in the appearance and less deterioration in UV exposure in comparison with pure WPU, enhancing the protective properties of the AA7075 aluminum alloy when exposed to a corrosive medium.