RESUMO
Metal halide perovskites (MHPs) have undergone rapid development in the fields of solar cells, light diodes, lasing, photodetectors, etc. However, the MHPs still face significant challenges, such as poor stability and heterocompositing with other functional materials at the single nanoparticle level. Herein, the successful synthesis of well-dispersed CsPbBr3@TiO2 heterostructure nanocrystals (NCs) is reported, in which each heterostructure NC has only one CsPbBr3 with a precise anatase TiO2 coating ranging from asymmetric to symmetric. Due to the protection of anatase TiO2, CsPbBr3 shows dramatically improved chemical stability and photostability. More significantly, the synthesized CsPbBr3@TiO2 heterostructure NCs form a type II heterojunction, which strongly promoted efficient photogenerated carrier separation between anatase TiO2 and CsPbBr3, hence leading to improved optoelectronic activity. This study provides a robust avenue for synthesizing stable and highly efficient MHPs@metal oxide heterostructure NCs, paving the way for the practical application of all inorganic perovskites.
RESUMO
BACKGROUND: This study was designed to perform isokinetic knee testing of male judokas competing in the under 73 kg category. The main aims were: to establish the concentric (CON) and eccentric (ECC) strength profile of hamstrings (H) and CON profile of quadriceps (Q) muscles; to evaluate the differences in CON and ECC peak torques (PT) with various strength ratios and their bilateral asymmetries; the calculation of the dynamic control ratio (DCR) and H ECC to CON ratio (HEC); Methods: 12 judokas competing on a national and international levels with a mean age of 19 ± 4 years, a weight of 75 ± 2 kg and with a height of 176 ± 5 cm were tested. All the subjects were right-hand dominant. Isokinetic testing was performed on iMOMENT, SMM isokinetic machine (SMM, Maribor, Slovenia). The paired t-test was used to determine the difference between paired variables. The level of significance was set at p ≤ 0.05; Results: Statistical differences between left (L) and right (R) Q PT (L 266; R 241 Nm), H ECC PT (L 145; R 169 Nm), HQR (L 0.54; R 0.63), DCR (L 0.55; R 0.70), HEC (L 1.02; R 1.14) and PTQ/BW (L 3.57; R 3.23 Nm/kg) were shown. Bilateral strength asymmetries in CON contraction of 13.52% ± 10.04 % for Q, 10.86% ± 7.67 % for H and 22.04% ± 12.13% for H ECC contraction were shown. CONCLUSIONS: This study reports the isokinetic strength values of judokas in the under 73 kg category, emphasising eccentric hamstring strength and eccentric derived strength ratios DCR and HEC. It was shown that asymmetries are better detected using eccentric testing and that the dominant leg in judokas had stronger eccentric hamstring strength resulting in higher DCR and HEC.