Effect of monocultures and polycultures of Typha latifolia and Heliconia psittacorum on the treatment of river waters contaminated with landfill leachate/domestic wastewater in partially saturated vertical constructed wetlands.

Partially Saturated Vertical Constructed Wetlands (PSV-CWs) are novel wastewater treatment systems that work through aerobic and anaerobic conditions that favor the removal of pollutants found in high concentrations, such as rivers contaminated with domestic wastewater and landfill leachate. The objective of the study was to evaluate the efficiency of PSV-CWs using monocultures and polycultures of Typha latifolia and Heliconia psittacorum to treat river waters contaminated with leachates from open dumps and domestic wastewater. Six experimental units of PSV-CWs were used; two were planted with Typha latifolia monoculture, two with Heliconia psittacorum monoculture and two with polycultures of both plants. The results indicated better organic matter and nitrogen removal efficiencies (p < 0.05) in systems with polycultures (TSS:95%, BOD5:83%, COD:89%, TN:82% and NH4+:99%). In general, the whole system showed high average removal efficiencies (TSS:93%, BOD5:79%, COD:85%, TN:79%, NH4+:98% and TP:85%). Regarding vegetation, both species developed better in units with monocultures, being Typha latifolia the one that reached a more remarkable development. However, both species showed high resistance to the contaminated environment. These results showed higher removals than those reported in the literature with conventional Free Flow Vertical Constructed Wetlands (FFV-CWs), so PSV-CWs could be a suitable option to treat this type of effluent.

The research addresses the contamination of water resources in developing countries by landfill leachate and domestic wastewater discharges. It proposes treatment through Partially Saturated Vertical Constructed Wetlands (PSV-CWs), which, despite the limited information available, have been shown to be effective in removing pollutants in effluents with high concentrations. In addition to evaluating PSV-CWs, the study examines the impact of different types of vegetation on pollutant removal efficiency, concluding that PSV-CWs are a promising and viable option for the treatment of these effluents.

Landfill leachates as a significant source for emerging pollutants of phthalic acid esters: Identification, occurrence, characteristics, fate, and transport.

Phthalic acid esters (PAEs) are byproducts released from various sources, including microplastics, cosmetics, personal care products, pharmaceuticals, waxes, inks, detergents, and insecticides. This review article provides an overview of the literature on PAEs in landfill leachates, exploring their identification, occurrence, characteristics, fate, and transport in landfills across different countries. The study emphasizes the influence of these substances on the environment, especially on water and soil. Various analytical techniques, such as GC-MS, GC-FID, and HPLC, are commonly employed to quantify concentrations of PAEs. Studies show significant variations in levels of PAEs among different countries, with the highest concentration observed in landfill leachates in Brazil, followed by Iran. Among the different types of PAE, the survey highlights DEHP as the most concentrated PAE in the leachate, with a concentration of 89.6 µg/L. The review also discusses the levels of other types of PAEs. The data shows that DBP has the highest concentration at 6.8 mg/kg, while DOP has the lowest concentration (0.04 mg/kg). The concentration of PAEs typically decreases as the depth in the soil profile increases. In older landfills, concentrations of PAE decrease significantly, possibly due to long-term degradation and conversion of PAE into other chemical compounds. Future research should prioritize evaluating the effectiveness of landfill liners and waste management practices in preventing the release of PAE and other pollutants into the environment. It is also possible to focus on developing efficient physical, biological, and chemical methods for removing PAEs from landfill leachates. Additionally, the effectiveness of existing treatment processes in removing PAEs from landfill leachates and the necessity for new treatment processes can be considered.

Black Vulture (Coragyps atratus) feathers as bioindicators of exposure to metals and metalloids contamination in urban, semi-urban, and rural areas from Campeche state, Mexico.

Landfills are sources of soil, water, and air pollution due to the release of toxic compounds such as metals and metalloids. In both tropical and temperate environments, scavenger birds such as the Black Vulture (Coragyps atratus) that have learned to use these sites as a feeding area are probably exposed to metals, metalloids and other "persistent bioaccumulative toxic substances (PBTs)" released in open dumpsite (OD) and sanitary landfill (SL). The objective of this study is to evaluate the presence and distribution of toxic metals (Al, Sn, Hg, Cu, Pb, Cd, Cr) and As in OD and SL from urban, semi-urban and rural localities in Campeche, México, using molting feathers of C. atratus as bioindicators. A total of 125 Black Vulture primary and secondary wing feathers were collected from OD and SL. Metals were determined by voltammetry through acid digestion. The highest levels of metals occurred in landfills in urban, semi-urban, and rural localities. The elements with the highest concentrations were Al, with an average of 35.67 ± 33.51 µg g-1 from rural environments, and As, with 16.20 ± 30.06 µg g-1 from the urban localities. Mercury was the only element that had a very homogeneous distribution between the three environments we studied. In general, Pb, Hg, Cu and Cd were the elements that presented the lowest concentrations with 0.32 ± 0.35, 0.16 ± 0.22, 0.14 ± 0.31 and 0.06 ± 0.10 µg g-1, respectively regardless of any particular location or environment. Black Vultures from dumpsites are good bioindicators of what humans consume in urban, semi-urban, and rural environments. However, the conservation of vultures is of great importance since these scavenger birds perform ecosystem services by feeding on decomposing organic material.

Use of tritium in characterizing the leachate migration from a landfill - Central de tratamento de resíduos sólidos (CTRS) BR040 (Belo Horizonte, Minas Gerais, Brazil).

Landfills often become a source of environmental impact due to the percolation of the leachate (liquid resulting from the decomposition of buried waste), which can eventually disperse and contaminate the soil and water bodies. This study aimed to evaluate quantitatively and spatially the leachate plume from the former Belo Horizonte landfill in the Coqueiros and Taiobas watersheds by using tritium (3H) concentration in nineteen (19) sampling points: 14 groundwater, 4 surface water and 1 leachate. Among the methodologies applied to determine the 3H content in the leachate, pre-filtration proved to be the most effective due to the ease treating of the sample, as well as the identical results obtained compared to the traditional method. The 3H contents resulted in concentrations up to thirty times higher in the leachate (=96,19 to 111,87 TU) and ten times in groundwater (PM23/3 = 45,06 TU), compared to the calculated threshold (TS) of rainfall tritium (TS_3Hrain = 3,41 TU). Temporal series results indicate no trend and no influence of seasonality regarding the entry of pluvial tritium, leachate liquid level and wells water level. The 3H contour maps shows a transport of the mixture (water and leachate) towards the Coqueiros stream, with a higher concentration of leachate in wells closer to the landfill slope (PM13, PM14, PM15, and PM23) and in the southwest margin of the Coqueiros stream (PM17). In the furthest portion of the landfill, 3H levels are higher than the base threshold only at the deepest level of PM20 (=3,90 TU), possibly due to factors such as: i) denser character of the leachate compared to groundwater; ii) greater influence of recharge for regions further away from the landfill slope; and iii) the presence of the rock about 50 m from the surface. Based on the hydrogeological conceptual model, the transport of the leachate water mixture in the groundwater water compartment of the Coqueiros watershed basin seems to follow a piston or dispersion flow, with a small Peclet number (Pd = 0,05, as an example), as indicated by the high correlation coefficient values (R2 ≈ 0,85 to 0,99) from graphic interpolation. The mixture of water and leachate results in a transient time (tt) ≈ 30 years and linear velocity (Vl) ≈ 3-14 m/year in the interpolated sections. These indicate a coherent correlation with the mean hydraulic conductivity (K ≈ 29,34 m/year), as they result in effective porosity values between (Ne) ≈ 0.16 to 0.36, which corresponds to Ne range for unconsolidated sediments, similar to the wells lithotype profiles. Time series evaluation combined with lumped parameter approach suggest to be an interesting way to better understanding the HCM, and, therefore, to determine hydrodynamic parameters using tritium as a tracer.

Physical and chemical characterization and pollution index applied in the assessment of the polluting potential of leachate from urban landfills.

During the operation of the landfills, leachate should be managed with caution to avoid possible negative environmental impacts. Considering this, the present study aims to evaluate the relationship between different variables in the leachate composition and elucidate the transformation processes through which this effluent passes during the landfill's period of operation. The study was conducted with eight sanitary landfills from the state of Minas Gerais, in southeastern Brazil, and used descriptive statistical analysis, principal component analysis (PCA), correlation analysis, and calculation of the leachate pollution index (LPI). The biochemical oxygen demand (BOD5)/chemical oxygen demand (COD) ratio was between 0.20 and 0.60. We also observed a significant correlation of 0.45 between Cl- and N-NH4+, which reflects the biological degradation processes that contribute to the presence of both variables. The PCA showed that inorganic variables and organic matter dominated the first component, with coefficients above 0.65, indicating the importance of those variables in determining the general data variability. The LPI values were between 15.26 and 25.97, with BOD5, COD, and N-NH4+ having sub-indexes above 35, being the main variables that increase the pollution potential of the leachate. On the other hand, trace metals present sub-indexes below 7 due to precipitation caused by increased pH and the characteristics of the waste discarded in landfills. The study provides essential information regarding the landfill leachate characteristics and its variation over time, which can contribute to the definition of treatment technologies for this affluent in different scenarios.

Nitrate prediction in groundwater of data scarce regions: The futuristic fresh-water management outlook.

Nitrate contamination in groundwater poses a significant threat to water quality and public health, especially in regions with limited data availability. This study addresses this challenge by employing machine learning (ML) techniques to predict nitrate (NO3--N) concentrations in Mexico's groundwater. Four ML algorithms-Extreme Gradient Boosting (XGB), Boosted Regression Trees (BRT), Random Forest (RF), and Support Vector Machines (SVM)-were executed to model NO3--N concentrations across the country. Despite data limitations, the ML models achieved robust predictive performances. XGB and BRT algorithms demonstrated superior accuracy (0.80 and 0.78, respectively). Notably, this was achieved using ∼10 times less information than previous large-scale assessments. The novelty lies in the first-ever implementation of the 'Support Points-based Split Approach' during data pre-processing. The models considered initially 68 covariates and identified 13-19 significant predictors of NO3--N concentration spanning from climate, geomorphology, soil, hydrogeology, and human factors. Rainfall, elevation, and slope emerged as key predictors. A validation incorporated nationwide waste disposal sites, yielding an encouraging correlation. Spatial risk mapping unveiled significant pollution hotspots across Mexico. Regions with elevated NO3--N concentrations (>10 mg/L) were identified, particularly in the north-central and northeast parts of the country, associated with agricultural and industrial activities. Approximately 21 million people, accounting for 10 % of Mexico's population, are potentially exposed to elevated NO3--N levels in groundwater. Moreover, the NO3--N hotspots align with reported NO3--N health implications such as gastric and colorectal cancer. This study not only demonstrates the potential of ML in data-scarce regions but also offers actionable insights for policy and management strategies. Our research underscores the urgency of implementing sustainable agricultural practices and comprehensive domestic waste management measures to mitigate NO3--N contamination. Moreover, it advocates for the establishment of effective policies based on real-time monitoring and collaboration among stakeholders.

Organophosphate esters in inert landfill soil: A case study.

Organophosphate esters (OPEs) used as flame retardants and plasticizers are additives in building and construction materials, decorations, furniture, electronic equipment, among other applications. The presence of materials containing these substances in construction and demolition waste (CDW) from weak waste management practices can result in environmental contamination. In this study, OPEs' presence in soil samples collected from a CDW landfill in Brazil was evaluated. Soil samples were collected in areas adjacent to CDW from an inert landfill, and the samples were analysed by gas chromatography coupled to mass spectrometry. The OPEs were detected in all soil samples at quantifiable concentrations ranging from 21 to 251 ng g-1, and detected compounds were tris(phenyl) phosphate, tris(2-butoxyethyl) phosphate, tris(1,3-dichloroisopropyl) phosphate, tris(2-chloroisopropyl) phosphate and 2-ethylhexyl diphenyl phosphate. The presence of these compounds in a CDW landfill is probably due to the lack of control of the materials sent to and deposited in the landfill, which, results in part from the lack of sampling and screening systems that can help identify the presence of contaminants in the CDW waste stream. This is partially due to OPEs not being considered controlled compounds under current regulations, thus screening or separation for handling of OPEs at construction and demolition work sites is rare to non-existent. The data generated in this study reveals the need for improving CDW management to minimize, if not eliminate, environmental contamination by OPEs.

Quantification and molecular characterization of intact rotavirus species A (RVA) in municipal solid waste leachate.

AIMS: Leachate comprises a solid waste decomposition product found fresh in collection trucks or as an effluent in landfills. This study aimed to assess the occurrence, concentrations, and genetic diversity of intact rotavirus species A (RVA) in solid waste leachate. METHODS AND RESULTS: Leachate samples were concentrated by ultracentrifugation, treated with propidium monoazide (PMA), and exposed to LED photolysis. Treated and untread samples were extracted using the QIAamp Fast DNA Stool mini kit, and nucleic acids were screened for RVA employing a Taqman® Real-time PCR. The PMA RT-qPCR method detected RVA in eight out of nine truck samples and in 15.40% (2/13) of the landfill leachate samples. The RVA concentrations in the PMA-treated samples ranged from 4.57 × 103 to 2.15 × 107 genomic copies (GC) 100 mL-1 in truck leachate and from 7.83 × 103 to 1.42 × 104 GC 100 mL-1 in landfill samples. Six truck leachate samples were characterized as RVA VP6 genogroup I2 by partial nucleotide sequencing. CONCLUSIONS: The high intact RVA detection rates and concentrations in truck leachate samples indicate potential infectivity and comprise a warning for solid waste collectors concerning hand-to-mouth contact and the splash route.

Effects of capping on microbial populations and contaminant immobilization in an old unlined landfill.

This research aimed at evaluating the effects of capping on the mitigation of impacts generated by a closed unlined landfill in São Carlos, SP, Brazil. Physicochemical and microbiological analyses (16S rRNA sequencing) of buried solid waste samples were performed, in capped and uncapped areas. Even though leachate pockets could still be encountered in capped areas, the capping construction reduced oxygen availability and created more reducing conditions, propitiating the development of sulfate-reducing bacteria and possibly contributing to the precipitation of the metals Pb, Cd, Ni, Co, As, and Zn as metal sulfides, causing their immobilization. The microbial populations adapted to the anaerobic conditions created under capped zones belonged to the phyla Firmicutes, Chloroflexi, and Euryarchaeota and the genera Methanosaeta, Hydrogenispora, Smithella, and Gelria. Differently, the phyla Acidobacteria, Proteobacteria, Bacteroidetes, and Actinobacteria were more abundant in samples from the uncapped zones, in which the abundance of different genera varied homogeneously. Methanogenic activity was not impaired by the intervention measure, as assessed by the specific methanogenic activity (SMA). Capping of old unlined landfills brings benefits to the immobilization of metals and does not impair microbial degradation, being effective for the mitigation of impacts on soils and water resources.

On the correlation between thermal imagery and fugitive CH4 emissions from MSW landfills.

Landfill gas (LFG) is related to the biochemical processes generating heat and releasing CH4, CO2, and other gases in lower concentrations, which result in environmental impacts and risk of local explosion. Thermal infrared imagery (TIR) is employed to detect CH4 leakage as a risk control approach. However, the challenge for LFG leakage detection using TIR is establishing a relation between the gas flux and the ground temperature. This study evaluates the problem of a heated gas flowing through a porous medium column where the upward surface exchanges heat by radiation and convection to the environment. A heat transfer model that considers the upward LFG flow is proposed, and a sensibility analysis is developed to relate the flux to the ground temperature level in the condition of non-income solar radiation. An explicit equation to predict CH4 fugitive flow as a function of temperature anomalies of the ground was presented for the first time. The results show that the predicted ground surface temperatures are consistent with the literature's experimental observations. Moreover, the model was complementarily applied to a Brazilian landfill, with in situ TIR measurements in an area with a slightly fractured cover. In this field observation, the predicted CH4 flux was around 9025 g m-2 d-1. Model limitations concerning the soil homogeneity, the transient variation of atmospheric conditions or local pressure, and soil temperature difference in low-flux conditions (related to TIR-cameras accuracy) require further validation. Results could help landfill monitoring in conditions of a high-temperature ground anomaly in dry seasons.

Global Situation of Bioremediation of Leachate-Contaminated Soils by Treatment with Microorganisms: A Systematic Review.

This systematic review presents the current state of research in the last five years on contaminants in soils, especially in leachates from solid waste landfills, with emphasis on biological remediation. In this work, the pollutants that can be treated by microorganisms and the results obtained worldwide were studied. All the data obtained were compiled, integrated, and analyzed by soil type, pollutant type, bacterial type, and the countries where these studies were carried out. This review provides reliable data on the contamination of soils worldwide, especially soils contaminated by leachate from municipal landfills. The extent of contamination, treatment objectives, site characteristics, cost, type of microorganisms to be used, and time must be considered when selecting a viable remediation strategy. The results of this study can help develop innovative and applicable methods for evaluating the overall contamination of soil with different contaminants and soil types. These findings can help develop innovative, applicable, and economically feasible methods for the sustainable management of contaminated soils, whether from landfill leachate or other soil types, to reduce or eliminate risk to the environment and human health, and to achieve greater greenery and functionality on the planet.

An overview of in situ testing and geophysical methods to investigate municipal solid waste landfills.

Municipal solid waste (MSW) management is challenging as a whole. Global waste generation is expected to continue to increase in the coming years, and landfills are currently the primary destination. Therefore, the stability of these structures must be carefully evaluated to prevent failures and associated health and pollution risks, which implies the determination of waste properties using more reliable approaches. This paper presents a scoping review of field data from MSW landfills and outlines suggestions for future work. Studies published in the past twenty years were selected following a systematic search process in databases. Aspects discussed include (1) strength parameters and soil behavior type from in situ testing, (2) elastic moduli from seismic wave propagation, and (3) moisture content from geoelectrical measurements. Although the values of geotechnical parameters have varied due to waste heterogeneity and applied methods, the trends observed with depth and age could be compared. Research opportunities involve the spatial analysis of mechanical properties at a given site, seismic response of landfills with high organic content and saturation degree, interpretation of long-term resistivity monitoring, and combination of electrical properties to assess the degradation stages within the waste mass.

Application of a sustainable location index approach to landfill site selection in Monterrey, Mexico.

Landfilling is the main method to manage municipal solid waste (MSW) in Latin America due to the economic, technological and political characteristics of the region. The disposal of MSW in landfill sites may affect the quality of the environment and compromise a considerable share of the municipal budgets. The selection of suitable sites reduces the environmental and economic impact of landfills. In the present study the sustainable location index (SLI) is proposed as a methodology to assess environmentally, and economically, sanitary landfill site selection in the Metropolitan Area of Monterrey, a representative large-size city of Latin America. EVIAVE methodology was modified to include administrative and economic dimensions, which are assessed as a sustainable approach using together the SLI integrated with geospatial and multicriteria analysis tools. The assessment showed that the zones with the lowest SLI changes drastically when the importance of the economic or environmental factor varies. This result suggest that the inclusion of sustainability in landfill site selection decision-making is complex and it may requires the inclusion of local particularities such as municipal budgets, policies of MSW management and public perception about environmental deterioration.

A review on membrane concentrate management from landfill leachate treatment plants: The relevance of resource recovery to close the leachate treatment loop.

Membrane filtration processes have been used to treat landfill leachate. On the other hand, closing the leachate treatment loop and finding a final destination for landfill leachate membrane concentrate (LLMC) - residual stream of membrane systems - is challenging for landfill operators. The re-introduction of LLMC into the landfill is typical; however, this approach is critical as concentrate pollutants may accumulate in the leachate treatment facility. From that, leachate concentrate management based on resource recovery rather than conventional treatment and disposal is recommended. This work comprehensively reviews the state-of-the-art of current research on LLMC management from leachate treatment plants towards a resource recovery approach. A general recovery train based on the main LLMC characteristics for implementing the best recovery scheme is presented in this context. LLMCs could be handled by producing clean water and add-value materials. This paper offers critical insights into LLMC management and highlights future research trends.

Scaling-up of the adsorption process of ammonia nitrogen onto expanded vermiculite using fixed-bed columns.

Expanded vermiculite was used as an adsorbent to remove ammonia nitrogen from landfill leachate. Bench and pilot-scale adsorption experiments were performed with leachate collected from a closed sanitary landfill located in Curitiba, southern Brazil. At the bench-scale, two different heights of vermiculite and three different flow rates were tested using a fixed-bed column. These tests produced an average uptake capacity of 33.4 mg g-1 for the ammonia nitrogen concentration of 2,560 mg L-1. The Yan model was used to determine the breakthrough and the exhaustion times due to the best fit of the data to this model. At the pilot-scale, the flow rate was determined from the shortest length of the mass transfer zone obtained from bench-scale experiments. Tests were performed using one stainless-steel column filled with 26.2 kg of expanded vermiculite, which resulted in a bed height of 1.6 m. A leachate flow rate of approximately 350 L d-1 was applied to achieve the required contact time of 8.3 h. At this scale, an average uptake capacity of 18.1 mg g-1 was obtained for the ammonia nitrogen concentration of 1,193 mg L-1. It is worth mentioning that the flow rate and the concentration of the adsorbate in the feeding solution are fundamental to improve the operational time of the fixed-bed column. The main goal of this research was the determination of operating conditions to scale-up the adsorption process of ammonia nitrogen onto expanded vermiculite. The contact time was a key parameter to reach this goal.

A comprehensive assessment of leachate contamination at a non-operational open dumpsite: mycoflora screening, metal soil pollution indices, and ecotoxicological risks.

The final disposal of municipal solid waste (MSW) in dumpsites is still a reality worldwide, especially in low- and middle-income countries, leading to leachate-contaminated zones. Therefore, the aim of this study was to carry out soil and leachate physicochemical, microbiological, and toxicological characterizations from a non-operational dumpsite. The L-01 pond samples presented the highest physicochemical parameters, especially chloride (Cl; 4101 ± 44.8 mg L-1), electrical conductivity (EC; 10,452 ± 0.1 mS cm-1), and chemical oxygen demand (COD; 760 ± 6.6 mg L-1) indicating the presence of leachate, explained by its close proximity to the landfill cell. Pond L-03 presented higher parameters compared to pond L-02, except for N-ammoniacal and phosphorus levels, explained by the local geological configuration, configured as a slope from the landfill cell towards L-03. Seven filamentous and/or yeast fungi genera were identified, including the opportunistic pathogenic fungi Candida krusei (4 CFU) in an outcrop sample. Regarding soil samples, Br, Se, and I were present at high concentrations leading to high soil contamination (CF ≤ 6). Pond L-02 presented the highest CF for Br (18.14 ± 18.41 mg kg-1) and I (10.63 ± 3.66 mg kg-1), while pond L-03 presented the highest CF for Se (7.60 ± 1.33 mg kg-1). The most severe lethal effect for Artemia salina was observed for L-03 samples (LC50: 79.91%), while only samples from L-01 were toxic to Danio rerio (LC50: 32.99%). The highest lethality for Eisenia andrei was observed for L-02 samples (LC50: 50.30%). The applied risk characterization indicates high risk of all proposed scenarios for both aquatic (RQ 375-909) and terrestrial environments (RQ > 1.4 × 105). These findings indicate that the investigated dumpsite is contaminated by both leachate and metals, high risks to living organisms and adjacent water resources, also potentially affecting human health.

Beta-Lactam-Resistant Enterobacterales Isolated from Landfill Leachates.

Antibiotic resistance is one of the main challenges worldwide due to the high morbidity and mortality caused by infections produced by resistant bacteria. In Colombia, this problem has been studied mainly from the clinical perspective; however, it is scarcely studied in the leachates produced in landfills. The objective of this study was to detect, identify and determine the antibiotic sensitivity profile of Enterobacterales isolated from a leachate treatment plant located in Cali, Colombia. Detection was performed using selective culture media, bacterial identification using Matrix-Assisted Laser Desorption/Ionization-Time-Of-Flight (MALDI-TOF, bioMérieux) and by sequencing the gene coding for the 16S ribosomal RNA subunit when discrepancies were observed between phenotypic characteristics and MALDI-TOF. Antibiotic sensitivity profiling was determined using the automated VITEK®2 system (bioMérieux). Twenty-one isolates were obtained, of which Klebsiella pneumoniae was the most frequent (23.8%), and 34% of the isolates showed decreased sensitivity to beta-lactam antibiotics such as cefoxitin, ampicillin/sulbactam and piperacillin/tazobactam. These findings suggest that leachates from landfills could be a reservoir of pathogenic bacteria carrying antibiotic resistance determinants, so periodic microbiological characterization of these effluents should be performed, promoting the One Health approach.

Ecotoxicological responses of Daphnia magna and Eisenia andrei in landfill leachate.

Leachate toxicity using bioindicators such as microcrustaceans and earthworms has not been fully elucidated. These bioindicators are traditionally determined through physicochemical and microbiological analyses. The ecotoxicological assessment of leachate using indicator organisms from different environments is a technique to ensure the treatment and safe disposal of this effluent with minimum impact on human health and the environment. The current study aimed to evaluate the ecotoxicological responses of Daphnia magna and Eisenia andrei in landfill leachate, identifying which organism was more sensitive to this effluent. The leachate used in ecotoxicological tests was collected at the Campina Grande Sanitary Landfill (ASCG), Paraíba, Brazil. The leachate sample contained a high content of organic matter in the form of chemical oxygen demand (19496.86 mg.L-1) and ammoniacal nitrogen (2198.00 mg.NL-1), in addition to metals with carcinogenic potential, such as Cr (0.64 mg.L-1) and Fe (1.16 mg.L-1). The exposure of Daphnia magna to the leachate showed that the effluent is harmful to aquatic organisms, obtaining an EC 50, 48 h = 1.22%, FT of 128 and a TU of 81.96%. Among the contaminant concentrations tested in Eisenia andrei, 57% (59.28 mL.kg-1) caused the highest lethality, causing the death of 21 earthworms within 72 hours of exposure. The avoidance test showed that exposure to leachate concentrations between 10.38 and 39.86 mL.kg-1 led to the leakage of earthworms, and habitat loss was observed at a concentration of 55.80 mL.kg-1, in which leak response (LR) ≥80% was obtained. This study demonstrates that the mentioned organisms are suitable for ecotoxicological tests in landfill leachate. Moreover, the microcrustacean Daphnia magna showed the most significant sensitivity, presenting a rapid ecotoxicological response to the leachate.

A comparison assessment of landfill waste incineration and methane capture in the central region of Mexico.

This article aims to conduct a techno-economic feasibility assessment of producing energy by waste incineration and methane capture in the central region of Mexico. Three scenarios at different efficiency rates were considered: 50, 80 and 100%. For the methane project, yields and power capacity were determined using the potential generation rate and the degradable organic carbon content through the LandGEM model. For incineration, the waste calorific potential and the average moisture content were used to estimate the achievable electrical performance. The estimated annual energy was 35,018 GWh for methane, compared to 537.71 GWh for incineration. Both projects reported financial economic feasibilities when evaluated at a discount rate of 12%. Incineration reported an net present value of US$49,942,534 and an internal rate of return of 26% in contrast to US$4,054,109 and 17% for the methane project. Although the payback period for incineration was lower than for methane, its levelized cost of energy was significantly higher. These results are intended to assist the decision-making process when planning and developing waste management strategies under principles of circular economy in Mexico and similar regions worldwide.

Technical and economic aspects of a sequential MF + NF + zeolite system treating landfill leachate.

This work explores the techno-economic aspects of landfill leachate treatment by an integrated scheme composed of microfiltration (MF), nanofiltration (NF), and zeolite application for carbon and nitrogen removal. In bench-scale experiments, MF and NF were investigated, and zeolite batch tests were carried out to determine optimum conditions. A preliminary economic analysis is presented for a 200 m3 d-1 full-scale treatment facility based on the data obtained from experimental tests and literature surveys. The maximum removals of 92%, 94%, and 79% for chemical oxygen demand (COD), absorbance at 254 nm, and ammonium nitrogen (NH4+-N) were achieved in bench experiments, respectively. It was possible to reach the local discharge standard for COD (200 mg L-1), but it was not possible to reach the Brazilian disposal requirement for NH4+-N (20 mg L-1). The total cost of the integrated MF + NF + zeolite system was estimated at 19.89 US$m-3. In this study, the costs of the zeolite application account for around 70% of the total costs of the integrated scheme. Membrane process integration was an adequate strategy for removing organic compounds at low operating costs; However, further NH4+-N depuration is needed to meet discharge requirements.