Utilization of Secondary Raw Materials from Rice and Buckwheat Processing for the Production of Enriched Bread: Optimization of Formulation, Physicochemical and Organoleptic Properties, Structural and Mechanical Properties, and Microbiological Safety.

Pursuing enhanced nutritional value in bakery products through technological advancements and new recipes is a promising facet of the food industry. This study focuses on incorporating rice and buckwheat brans, additional raw materials rich in biologically active substances, into bakery products. Utilizing a second-order rotatable plan, optimal ratios were determined-5% rice bran and 10% buckwheat bran. The application of these brans influenced dough and bread quality, reducing sugar content by 5% in dry form and 29% in the fermented brew, potentially aiding in diabetes prevention and cholesterol control. Introducing brans, especially in fermented brew, positively impacted microbiological stability, reducing the risk of mold and potato disease. The developed bread technology using rice and buckwheat brans in fermented brew significantly increased nutritional value, satisfying adult daily protein needs by 31.2%, fats by 15%, and dietary fibers by 18.4%. This innovative approach ensures a sufficient intake of essential vitamins and minerals, showcasing a promising avenue for creating healthier and more nutritious bakery products.

Assessing the Potential of Rare Earth Elements in Bottom Ash from Coal Combustion in Poland.

The aim of the research was to assess the potential of bottom ash from Polish coal-fired power plants as an alternative source of rare earth elements (REY). The potential of these ashes was compared with fly ash from the same coal combustion cycle. The phase and chemical composition, as well as REY, were determined using: X-ray diffraction and inductively coupled plasma mass spectrometry. The tested ashes were classified as inert-low pozzolanic and inert-medium pozzolanic, as well as sialic and ferrosialic, with enrichment in detrital material. The phase and chemical composition of bottom ash was similar to fly ash from the same fuel combustion cycle. The REY content in the ash was 199-286 ppm and was lower than the average for global deposits, and the threshold value was considered profitable for recovery from coal. Bottom ash's importance as a potential source of REY will increase by recovering these metals from separated amorphous glass and mullite and grains rich in Al, Mg, K, and P. The industrial value of bottom ash as an alternative source of REY was similar to fly ash from the same fuel combustion cycle.

Distribution of Rare Earth Elements in Ash from Lignite Combustion in Polish Power Plants.

Rare earth elements are an essential critical raw material in the development of modern technologies and are highly sensitive to both supply chain disruptions and market turbulence. The presented study examines the characteristics of fuel, fly ash, and bottom ash from lignite combustion in power plant units. Also, we attempted to determine the amount of amorphous glass in the ashes and whether and to what extent the glass from the ash samples is bound to REY. The suitability of the ash was assessed as an alternative source of REY. The fuel and ash samples were acquired from power plants in Poland. The tests determined the fuel quality parameters, including the chemical and phase composition, of amorphous glass using ICP-MS and XRD methods, respectively. The study showed that all ash samples dissolved in 4% HF were enriched in REY. The efficiency of REY enrichment varied, and its presence in the residue samples was found to be in similar proportions compared to the raw sample. All ash residue samples were enriched in critical elements. The obtained values of the Coutl prospective coefficient allowed for the classification of some of the analyzed ashes and their residues after dissolution in 4% HF as prospective REY raw materials.

Case Studies on Changes and Proposed Process Development Approaches reflecting applicability of PDA Technical Report No. 89 Strategies for Vaccine Development and Lifecycle Management.

Vaccines are complex and a very diverse group of products with relatively long product lifecycles. The manufacturing programs for these vaccines need to be continually updated to comply with evolving regulatory expectations. Members of the Parenteral Drug Association (PDA) Vaccines Interest Group (VIG) authored and published PDA Technical Report No. 89 Strategies for Vaccine Development and Lifecycle Management (TR 89) which seeks to provide context to vaccine developers and manufacturers regarding key aspects of new or legacy vaccines such as control strategy from process development to vaccine lifecycle management, comparability and lifecycle management including technical, validation, quality and regulatory perspectives. To further explain and illustrate the concepts and topics discussed, seven relevant situations were selected as either case studies associated with changes implemented or proposed process development strategies, which are discussed in this article. The situations described are: working cell bank, modification or update of externally supplied product contact components for vaccine manufacturing, raw material change, new product at an existing site, vaccine development acceleration by leveraging existing platforms, selection and implementation of potency method, and modeling for stability forecast prediction. For each situation, the applicable key concepts from TR#89 are discussed as follows: Control Strategy, Prior Knowledge, Relying on PQS, Classification of Parameters, Validation Approach, Use of a Risk-based Approach, Comparability, Use of ICHQ12 and Additional Regulatory Considerations.

Marine microfossils: Tiny archives of ocean changes through deep time.

Microorganisms have inhabited the oceans since the dawn of Earth. Some of them have organic walls and some produce mineral tests that are usually composed of carbonate minerals or silica. They can therefore be preserved with original parts during sedimentary deposition or fossilized through permineralization or carbonization processes. The most common marine fossil groups studied by micropaleontologists are cyanobacteria, coccolithophores, dinoflagellates, diatoms, silicoflagellates, radiolarians, foraminifers, red and green algae, ostracods, and pteropods. Dormant or reproductive cysts can also be used for determinations of the fossil microbiota. Microfossils can be studied in petrographic slides prepared from rocks or separated from loosely consolidated rocks by disaggregation or dissolution and wet sieving. Their presence is sometimes recognized by biomarkers. Transmitted light microscopy and reflected light stereomicroscopy are necessary for micropaleontological studies whereas scanning electronic microscopy (SEM) aids research on the tiniest fossils and reveals fine skeletal details. Microorganisms have influenced the oxygenation of water and the atmosphere, as well as Earth's carbon cycle and have contributed to the formation of sedimentary rocks. By studying microfossils, paleontologists depict the age of the rock and identify depositional environments. Such studies help us recognize periods of stress in Earth's history and understand their influence on living organisms. Biogenic rocks, made of microfossils, can be used as raw materials, such as fossil fuels, building stone, or additives for the food industry, agricultural, or cosmetic purposes.

Trace Elements Anomalous Concentrations in Building Materials-The Impact of Secondary Mineralisation Processes.

The Pb, Cr, Cd, Ni, Zn, Cu, Co, As, Sr, Ba, and Zr content has been determined in the tested rock raw materials. The concentration of cadmium (Cd) was found to be elevated in all types of rock materials and was found on average to be: 1.39 mg/kg in limestones, 0.86 mg/kg-sandstones, 0.44 mg/kg-diatomites, 0.55 mg/kg-opoka rocks, 0.89 mg/kg-marls, 0.21 mg/kg-gaizes 0.42 mg/kg-kaolin clays, and 2.13 mg/kg-decalcified opoka rocks. Higher concentrations of arsenic (As) have also been recorded in sandstones and diatomites, as well as lead (Pb) in limestones and sandstones. The results obtained indicate that the anomalous level of elements is of natural origin and the results of identified secondary mineralisation processes that have affected the tested materials. Pyritization and sulfatization processes have been detected. Mineralogical research has shown that these processes can be associated with the activity of biochemical processes caused by the decomposition of the soft tissues of animal organisms and the organic substances of plant origin that fill the stylolites. It has been shown that the content of strontium (Sr) increases in geologically older Jurassic formations compared to younger Cretaceous formations, which can be used in the monitoring of building materials.

Surface Characteristics of Activated Carbon Sorbents Obtained from Biomass for Cleaning Oil-Contaminated Soils.

This study explores the sorption capacity and field application of activated carbons (ACs) derived from plant residues for the remediation of oil-contaminated soils. ACs were prepared from rice husks, reed stalks, pine sawdust and wheat straw using two-stage pyrolysis and chemical activation with potassium hydroxide. The structural and physicochemical properties of these ACs were analyzed using BET surface area measurements, SEM analysis, Raman spectroscopy and FTIR spectroscopy. Sorption experiments at room temperature demonstrated that AC from rice husks (OSL) exhibited the highest sorption capacities for gasoline, kerosene and diesel fuel, with values of 9.3 g/g, 9.0 g/g and 10.1 g/g, respectively. These results are attributed to the well-developed microporous and mesoporous structures of OSL, as confirmed by SEM images and a BET surface area of 2790 m2/g. Field tests conducted at the "Zhanatalap" oil deposit showed that the ACs effectively reduced the oil content in contaminated soils from 79.2 g/kg to as low as 2.6 g/kg, achieving a purification degree of up to 67% within 16 days. This study highlights the critical role of structural properties, such as porosity and graphitization degree, in enhancing the sorption efficiency of ACs.

Selective recovery of antimony from Sb-bearing copper concentrates by integration of alkaline sulphide leaching solutions and microwave-assisted heating: A new sustainable processing route.

The technical feasibility of leaching antimony from an antimony-bearing copper sulphide concentrate, using alkaline sulphide solutions and microwave-assisted and non-assisted heating technology, is investigated at a laboratory scale. The leaching test examines the influence of selective leaching reagent (Na2S and NaOH) concentrations, solid/liquid ratio, and temperature. The results indicate that antimony dissolution is highly selective (e.g. only Sb and As are leached), depending on the concentrations of leaching reagents and the leaching temperature. The influence of temperature on the mineral's dissolution, in the range 25-140 °C, is analysed from a thermochemical point of view using equilibrium databases. Under the optimal conditions: leaching agent: 250 g/L Na2S, 60 g/L NaOH, 2 h, 140 °C, with microwave assisted, the leaching efficiency of Sb reached 95.7 %. The antimony content in the copper concentrate is successfully reduced from 1.1 wt% to <0.2 wt% Sb, making it suitable for copper concentrate metallurgical processing. The study demonstrates that increasing temperature and NaOH/Na2S concentrations collectively enhance leaching efficiency, with a statistical significance, reducing both leaching time and the required temperature, compared to non-microwave-assisted leaching. Furthermore, it is established that excess free hydrogen sulphide ions ensure the efficient dissolution of the main impurities associated with penalties, such as antimony and arsenic, with limited copper and iron dissolution from the copper concentrate, predominantly chalcopyrite. Finally, an integrated hydrometallurgical process flowsheet for antimony removal and recovery from a sulphide copper concentrate is proposed.

Transfer and bioaccumulation of chemical and biological contaminants in the marine polychaete Hediste diversicolor (OF müller 1776) when reared on salmon aquaculture sludge.

Side streams from aquaculture production such as fish sludge poses ample opportunities for biological upcycling, as the sludge contains high amounts of nutrients, energy and valuable biochemicals, making it an ideal food for extractive species. Sludge has been proposed as a feed stock for polychaete production, which in turn can be utilized live in shrimp aquaculture or as an aquafeed ingredient. However, the biosafety of such value chains has not yet been addressed. We conducted an experiment exposing the polychaete Hediste diversicolor to aquaculture sludge spiked with four different fish pathogens (Mycobacterium salmoniphilum, Yersinia ruckeri, Infectious Pancreatic Necrosis (IPN) and Infectious Salmon Anaemia (ISA)) known to cause diseases in Atlantic salmon (Salmo salar L.). Moreover, we assessed whether heavy metals and other potentially hazardous elements present in fish sludge bioaccumulates in the polychaetes. Neither of the bacteria nor viruses could be detected in the polychaetes after 14 days of continuous exposure. Seven of the 15 elements we analysed showed bioaccumulation factors significantly below one, meaning biodilution, while the other eight did not differ from one, meaning no bioaccumulation. None of the elements showed a significant bioaccumulation. Further on, none of the heavy metals found in the polychaetes at the end of our experiment exceeded the EU regulatory maximum levels for fish feed ingredients. The current results suggest that a H. diversicolor can reared on aquaculture sludge, and aquaculture sludge may serve as feed stock for polychaete production without the product exceeding EU regulations for contaminants in animal feed.

Valorisation of salmon backbones: Extraction of gelatine and its applicability in biodegradable films.

Salmon backbones make up about 10 % of the total fish weight and contain valuable proteins, collagen and lipids that can be used for marine ingredients production. Gelatine is derived from the collagen fraction and this study evaluated how different fractionation and extraction procedures can affect the yield and composition of extracted gelatine. Fractionation by mild thermal treatment of backbones (10 min in 40-42 °C) leads to structural changes of muscle, which improves separation of meat from bones and gives better yield of de-muscled backbone fractionation compared to mechanical meat removal. The highest yield of the gelatine (9.3 ± 0.3g dry gelatine from 100g de-muscled backbone dry material) was obtained from mechanically de-muscled backbones. De-muscled backbones were pre-treated with alkaline (0.04 N NaOH) followed by EDTA and 10 % ethanol for de-calcification and lipid extraction, respectively. Gelatine from pretreated backbones was extracted with 60 °C water. The amount of gelatine amino acids (sum of hydroxyproline, proline and glycine) was 43.4 ± 0.2 % of all amino acids in the gelatine. Extracted backbone gelatines showed film-forming ability. Gelatine films were obtained by casting procedure. Resulted salmon backbone 6 % gelatine and 30 % sorbitol films showed properties (e.g. water vapour permeability, colour difference, transparency value) similar to films obtained with commercial gelatine, indicating the capability of the extracted gelatines for its valorisation as edible coatings or bio-based film layers in packaging.

Converting biomass waste into valuable biomaterials and bioactive compounds: an overview of antimicrobial activities in the pursuit of global sustainability and health.

The escalating global population poses formidable challenges to addressing pressing environmental concerns, hindering progress towards sustainable development goals. Unregulated human activities, particularly the excessive reliance on fossil fuels and unsustainable agricultural practices, contribute to pollution, climate change, and resource depletion. Inadequate waste management systems exacerbate environmental degradation and pose risks to public health. Leveraging biological resources and urban/industrial waste emerges as a promising solution. Various waste materials, such as food waste and agro-industrial by-products, have been efficiently repurposed into valuable bio-based products. This review explores the diverse applications of agricultural and food waste repurposing, including microbial production of biopolymers and biosurfactants, as well as the extraction of biologically active compounds for potential antimicrobial drugs.

Valorization of fish processing by-products for protein hydrolysate recovery: Opportunities, challenges and regulatory issues.

Protein-rich fish processing by-products, often called rest raw materials (RRM), account for approximately 60% of the total fish biomass. However, a considerable amount of these RRM is utilized for low-value products such as fish meal and silage. A promising and valuable approach for maximizing the utilization of RRM involves the extraction of bioactive fish protein hydrolysate (FPH). This review assesses and compares different hydrolyzation methods to produce FPH. Furthermore, the review highlights the purification strategy, nutritional compositions, and bioactive properties of FPH. Finally, it concludes by outlining the application of FPH in food products together with various safety and regulatory issues related to the commercialization of FPH as a protein ingredient in food. This review paves the way for future applications by highlighting efficient biotechnological methods for valorizing RRM into FPH and addressing safety concerns, enabling the widespread utilization of FPH as a valuable and sustainable source of protein.

Earliest evidence of human occupations and technological complexity above the 45th North parallel in Western Europe. The site of Lunery-Rosieres la-Terre-des-Sablons (France, 1.1 Ma).

The site of LuneryRosieres la-Terre-des-Sablons (Lunery, Cher, France) comprises early evidence of human occupation in mid-latitudes in Western Europe. It demonstrates hominin presence in the Loire River Basin during the Early Pleistocene at the transition between an interglacial stage and the beginning of the following glacial stage. Three archaeological levels sandwiched and associated with two diamicton levels deposited on the downcutting river floor indicate repeated temporary occupations. Lithic material yields evidence of simple and more complex core technologies on local Jurassic siliceous rocks and Oligocene millstone. Hominins availed of natural stone morphologies to produce flakes with limited preparation. Some cores show centripetal management and a partially prepared striking platform. The mean ESR age of 1175 ka ± 98 ka obtained on fluvial sediments overlying the archaeological levels could correspond to the transition between marine isotopic stages (MIS) 37 and 36, during the normal Cobb Mountain subchron, and in particular at the beginning of MIS 36. The Lunery site shows that hominins were capable of adapting to early glacial environmental conditions and adopting appropriate strategies for settling in mid-latitude zones. These areas cannot be considered as inhospitable at that time as Lunery lies at some distance from the forming ice cap.

Application of ion-exchange dynamic conditions in the recovery of precious metals from refining waste.

The objective of this study was to assess the potential for recovering precious metals from technological solutions using an ion-exchange dynamic method. Precious metals like platinum, palladium, rhodium, and gold are essential materials in various industries such as: automotive, electronics, pharmaceuticals, and jewellery. Due to their limited occurrence in primary sources, there is a growing trend in the market to extract these metals from secondary sources. The research involved conducting sorption and elution tests under different parameters to investigate their impact on the process in dynamic conditions. Additionally, an attempt was made to calculate the operational and total capacity of the resins, which has not been done previously for industrial solutions. The results showed that using Puromet MTS9200, Puromet MTS9850, and Lewatit MonoPlus MP600 resins, the sorption process could be effectively carried out in dynamic conditions with a contact time of 5 min between the technological solution and the resin bed. For optimal elution, the contact time between the eluent solution and the bed should range between 10 and 30 min. To improve rhodium sorption efficiency, it was found that neutralizing the technological solution to a pH of approximately 7 and using Lewatit MonoPlus MP600 resin could be beneficial.

Facile synthesis of eco-friendly alginate-chitosan bio-adsorbent for critical raw materials adsorption: A comprehensive study.

Sustainable management of critical raw materials is of paramount importance to ensure a steady supply and reduce environmental impact. The application of newly synthesized and environmentally friendly ALG@CS material as a bio-adsorbent for the effective rare earth elements removal from aqueous solution has been presented. The synthesized material underwent FTIR, XPS, EDX, and SEM analysis to determine its suitability for metal uptake. To evaluate the adsorption capacity of ALG@CS for rare earth elements several factors were taken into consideration. These factors included alginate:chitosan ratios, bead size, pH level, composite mass, interaction time, metal ion concentration, and temperature, being all varied during the batch mode evaluation process. Under the optimal conditions, the maximum adsorption capacities were found to be 145.90 mg La(III)/g, 168.44 mg Ce(III)/g, 132.51 mg Pr(III)/g, 128.40 mg Nd(III)/g, 154.36 mg Sm(III)/g, and 165.10 mg Ho(III)/g. The equilibrium data fits well with non-linear three-parameter Sips and Redlich-Peterson isotherm models. The PSO model finds the highest process suitability. The synthesized ALG@CS bio-adsorbent showed excellent regenerative capacity in ten cycles, making it a suitable adsorbent for rare earth elements uptake. The unique bio-adsorbents combination allows for efficient critical raw materials adsorption providing a promising solution for their recovery and recycling.

The Influence of the Grinding Media Diameter on Grinding Efficiency in a Vibratory Ball Mill.

The grinding process plays a crucial role in industry, allowing for the reduction of particle sizes of raw materials and substances to the required fineness-either as a finished product or for further technological processes. The high demand for micro- and nanopowders or suspensions is associated with the high energy consumption of the milling process. Therefore, optimizing the milling process, including correctly selecting grinding media, is essential to reduce energy consumption. This article presents experimental studies of the grinding process of a model material (quartz sand) in a laboratory vibratory mill. Five sets of grinding media with different diameters were used in the research, and grinding was conducted for various durations. The studies showed that the vibratory grinding process is efficient for each set of grinding media and grinding durations. The research has shown that conducting studies on the proper selection of mills is beneficial, especially regarding very fine grinding of various materials. The study confirmed that properly selecting grinding media sets can significantly accelerate the grinding process. For the selected technological variant, it was demonstrated that using 15 mm grinding media, compared to 12 mm, resulted in a 22.5% reduction in grinding time to achieve a specified particle size class of 0-10 µm.

Alkali Extraction of Arsenic from Groundwater Treatment Sludge: An Essential Initial Step for Arsenic Recovery.

Arsenic (As)-bearing Fe(III) precipitate groundwater treatment sludge has traditionally been viewed by the water sector as a disposal issue rather than a resource opportunity, partly due to assumptions of the low value of As. However, As has now been classified as a Critical Raw Material (CRM) in many regions, providing new incentives to recover As and other useful components of the sludge, such as phosphate (P) and the reactive hydrous ferric oxide (HFO) sorbent. Here, we investigate alkali extraction to separate As from a variety of field and synthetic As-bearing HFO sludges, which is a critical first step to enable sludge upcycling. We found that As extraction was most effective using NaOH, with the As extraction efficiency increasing up to >99% with increasing NaOH concentrations (0.01, 0.1, and 1 M). Extraction with Na2CO3 and Ca(OH)2 was ineffective (<5%). Extraction time (hour, day, week) played a secondary role in As release but tended to be important at lower NaOH concentrations. Little difference in As extraction efficiency was observed for several key variables, including sludge aging time (50 days) and cosorbed oxyanions (e.g., Si, P). However, the presence of ∼10 mass% calcite decreased As release from field and synthetic sludges considerably (<70% As extracted). Concomitant with As release, alkali extraction promoted crystallization of poorly ordered HFO and decreased particle specific surface area, with structural modifications increasing with NaOH concentration and extraction time. Taken together, these results provide essential information to inform and optimize the design of resource recovery methods for As-bearing treatment sludge.

Understanding How Chemical Pollutants Arise and Evolve in the Brewing Supply Chain: A Scoping Review.

In this study, a critical review was carried out using the Web of ScienceTM Core Collection database to analyse the scientific literature published to date to identify lines of research and future perspectives on the presence of chemical pollutants in beer brewing. Beer is one of the world's most popular drinks and the most consumed alcoholic beverage. However, a widespread challenge with potential implications for human and animal health is the presence of physical, chemical, and/or microbiological contaminants in beer. Biogenic amines, heavy metals, mycotoxins, nitrosamines, pesticides, acrylamide, phthalates, bisphenols, microplastics, and, to a lesser extent, hydrocarbons (aliphatic chlorinated and polycyclic aromatic), carbonyls, furan-derivatives, polychlorinated biphenyls, and trihalomethanes are the main chemical pollutants found during the beer brewing process. Pollution sources include raw materials, technological process steps, the brewery environment, and packaging materials. Different chemical pollutants have been found during the beer brewing process, from barley to beer. Brewing steps such as steeping, kilning, mashing, boiling, fermentation, and clarification are critical in reducing the levels of many of these pollutants. As a result, their residual levels are usually below the maximum levels allowed by international regulations. Therefore, this work was aimed at assessing how chemical pollutants appear and evolve in the brewing process, according to research developed in the last few decades.

Quality- and Health-Promoting Compounds of Whole Wheat Bread with the Addition of Stale Bread, Cornmeal, and Apple Pomace.

The aim of this study was to evaluate the effect of extruded preparations on the bioactive and nutritional properties, vitamin B content, volatile compound profile, and quality of whole wheat bread. Extruded preparations based on stale bread (secondary raw materials) and apple pomace (byproducts) were used as bread additives. It was found that the preparations did not enrich the bread in protein but in health-promoting compounds, especially gallic acid, protocatechuic acid, caffeic acid, p-coumaric acid, rutin, quercetin, and B vitamins. Extruded preparations had a positive effect on the quality of the bread produced, such as yield and cohesiveness, and gave it a pleasant aroma. It was shown that among all the examined bread samples with added extruded preparations of stale bread, the cornmeal and apple pomace bread samples with 15% extruded preparation (containing 55% cornmeal, 30% stale bread, and 15% apple pomace) had sufficient nutritional value, the highest amounts of gallic acid, protocatechuic acid, p-coumaric acid, caffeic acid, rutin, and quercetin; medium amounts of ellagic acid; high antioxidant activity determined in vitro using four methods (by DPPH, ABTS, power (FRAP), and Fe(II) chelating assays); adequate quality; and significant amounts of vitamins, especially B1, B2, and B3. This type of extruded preparation should utilize apple pomace, which is a byproduct, and stale bread, which is a secondary waste. Such a combination is an excellent low-cost, easy, and prospective solution for the baking industry that could be applied to obtain bread with elevated nutritional value and enhanced health potential, as proven in this publication.

Perspectives on Using Alder, Larch, and Birch Wood Species to Maintain the Increasing Particleboard Production Flow.

Particleboard, engineered wood products as part of a large family of wood composite materials, developed in use mainly in the 1950s and 1960s to utilize inferior wood and wood waste when good-quality wood was in short supply; the annual production capacity worldwide is over 100 million m3. It is also necessary to have a lot of wood raw material for its production, although raw material resources are limited on our planet. In addition to the main wood species, it is therefore possible to think about the wider use of alternative, lesser-known European species of alder, larch, and birch in particleboard production. These three wood species represent an eco-friendly and sustainable wood alternative to the conventional wood raw materials used. This review confirms the diversity of the use of these three species in different fields and proves their suitability in relation to particleboard production. Fundamental research is ongoing in certain universities to determine the proportional shares of use of these tree species in particleboard (in a certain weight proportion in their core layers) for the purpose of formulating the correct technology shares and rules for their application in the wood-based panel industry.