Uncovering Temperature-Insensitive Feature of Phase Change Thermal Storage Electrolyte for Safe Lithium Battery.

Lithium-ion batteries (LIBs) have emerged as highly promising energy storage devices due to their high energy density and long cycle life. However, their safety concern, particularly under thermal shock, hinders their widespread applications. Herein, a temperature-insensitive electrolyte (TI-electrolyte) with exceptional resistance to thermal stimuli is presented to address the safety issues arising from the lack of thermal abuse tolerance in LIBs. The TI-electrolyte is composed of two phase-change polymers with differentiation melting points (60 and 35°C for polycaprolactone and polyethylene glycol respectively), delivering a wide temperature-resistant range. It is demonstrated that the TI-electrolyte possesses a heat capacity of 27.3 J g-1. The crystalline region in the TI-electrolyte shrinks when confronted with above-ambient temperature, absorbing heat to unlock molecular chains fixed in the crystal lattice, becoming amorphous. Notably, the Li||LFP pouch cell delays 3 valuable minutes to achieve the same temperature as conventional liquid electrolytes (LE) when subjected to thermal shocks, paralleling with the simulation results. Moreover, symmetrical Li||Li cell cycles stably for over 600 h at 0.1 mA cm-2, and Li||LFP full cell demonstrates excellent electrochemical performance, with a capacity of 142.7 mAh g-1 at 0.5 C, thus representing a critical approach to enhancing the safety of LIBs.

Design of Power Amplifiers for BDS-3 Terminal Based on InGaP/GaAs HBT MMIC and LGA Technology.

With the development and popularization of the Beidou-3 navigation satellite system (BDS-3), to ensure its unique short message function, it is necessary to integrate a radio frequency (RF) transmitting circuit with high performance in the BDS-3 terminal. As the key device in an RF transmitting circuit, the RF power amplifier (PA) largely determines the comprehensive performance of the circuit with its transmission power, efficiency, linearity, and integration. Therefore, in this paper, an L-band highly integrated PA chip compatible with 3 W and 5 W output power is designed in InGaP/GaAs heterojunction bipolar transistor (HBT) technology combined with temperature-insensitive adaptive bias technology, class-F harmonic suppression technology, analog pre-distortion technology, temperature-insensitive adaptive power detection technology, and land grid array (LGA) packaging technology. Additionally, three auxiliary platforms are proposed, dedicated to the simulation and optimization of the same type of PA designs. The simulation results show that at the supply voltage of 5 V and 3.5 V, the linear gain of the PA chip reaches 39.4 dB and 38.7 dB, respectively; the output power at 1 dB compression point (P1dB) reaches 37.5 dBm and 35.1 dBm, respectively; the saturated output power (Psat) reaches 38.2 dBm and 36.2 dBm, respectively; the power added efficiency (PAE) reaches 51.7% and 48.2%, respectively; and the higher harmonic suppression ratios are less than -62 dBc and -65 dBc, respectively. The size of the PA chip is only 6 × 4 × 1 mm3. The results also show that the PA chip has high gain, high efficiency, and high linearity under both output power conditions, which has obvious advantages over similar PA chip designs and can meet the short message function of the BDS-3 terminal in various application scenarios.

An All-Silicon Resonant Pressure Microsensor Based on Eutectic Bonding.

In this paper, an all-Si resonant pressure microsensor based on eutectic bonding was developed, which can eliminate thermal expansion coefficient mismatches and residual thermal stresses during the bonding process. More specifically, the resonant pressure microsensor included an SOI wafer with a pressure-sensitive film embedded with resonators, which was eutectically bonded with a silicon cap for vacuum encapsulation. The all-Si resonant pressure microsensor was carefully designed and simulated numerically, where the use of the silicon cap was shown to effectively address temperature disturbances of the microsensor. The microsensor was then fabricated based on MEMS processes where eutectic bonding was adopted to link the SOI wafer and the silicon cap. The characterization results showed that the temperature disturbances of the resonant pressure microsensor encapsulated with the silicon cap were quantified as -0.82 Hz/°C of the central resonator and -2.36 Hz/°C of the side resonator within a temperature range from -40 °C to 80 °C, which were at least eight times lower than that of the microsensor encapsulated with the glass cap. Compared with the microsensor using the glass cap, the all-silicon microsensor demonstrated an accuracy improvement from 0.03% FS to 0.01% FS and a reduction in short-term frequency fluctuations from 3.2 Hz to 1.5 Hz.

Two-Electron Redox Chemistry Enabled High-Performance Iodide-Ion Conversion Battery.

A single-electron transfer mode coupled with the shuttle behavior of organic iodine batteries results in insufficient capacity, a low redox potential, and poor cycle durability. Sluggish kinetics are well known in conventional lithium-iodine (Li-I) batteries, inferior to other conversion congeners. Herein, we demonstrate new two-electron redox chemistry of I- /I+ with inter-halogen cooperation based on a developed haloid cathode. The new iodide-ion conversion battery exhibits a state-of-art capacity of 408 mAh gI-1 with fast redox kinetics and superior cycle stability. Equipped with a newly emerged 3.42 V discharge voltage plateau, a recorded high energy density of 1324 Wh kgI-1 is achieved. Such robust redox chemistry is temperature-insensitive and operates efficiently at -30 °C. With systematic theoretical calculations and experimental characterizations, the formation of Cl-I+ species and their functions are clarified.

A Regulated Temperature-Insensitive High-Voltage Charge Pump in Standard CMOS Process for Micromachined Gyroscopes.

Micromachined gyroscopes require high voltage (HV) for actuation and detection to improve its precision, but the deviation of the HV caused by temperature fluctuations will degrade the sensor's performance. In this paper, a high-voltage temperature-insensitive charge pump is proposed. Without adopting BCD (bipolar-CMOS-DMOS) technology, the output voltage can be boosted over the breakdown voltage of n-well/substrate diode using triple-well NMOS (n-type metal-oxide-semiconductor) transistors. By controlling the pumping clock's amplitude continuously, closed-loop regulation is realized to reduce the output voltage's sensitivity to temperature changes. Besides, the output level is programmable linearly in a large range by changing the reference voltage. The whole circuit has been fabricated in a 0.18- µ m standard CMOS (complementary metal-oxide-semiconductor) process with a total area of 2.53 mm 2 . Measurements indicate that its output voltage has a linear adjustable range from around 13 V to 16.95 V, and temperature tests show that the maximum variations of the output voltage at - 40 ∼ 80 ∘ C are less than 1.1%.

A Temperature-Insensitive Resonant Pressure Micro Sensor Based on Silicon-on-Glass Vacuum Packaging.

This paper presents a temperature-insensitive resonant pressure sensor, which is mainly composed of a silicon-on-insulator (SOI) wafer for pressure measurements and a silicon-on-glass (SOG) cap for vacuum packaging. The variations of pressure under measurement bend the pressure sensitive diaphragm and regulate the intrinsic frequencies of the resonators in the device layer. While, variations of temperature cannot significantly change the intrinsic frequencies of the resonators, due to the SOG cap to offset generated thermal stress. Numerical simulations, based on finite element analysis, were conducted to calculate the residual thermal stress and optimize the sensing structures. Experimental results show that the Q-factors of the resonators are higher than 16,000, with a differential pressure sensitivity of 11.89 Hz/kPa, a nonlinearity of 0.01% F.S and a low fitting error of 0.01% F.S with the pressure varying from 100 kPa to 1000 kPa. In particular, a temperature sensitivity of ~1 Hz/°C was obtained in the range of -45 °C to 65 °C, which is one order of magnitude lower than the previously reported counterparts.

Microstructured Porous Pyramid-Based Ultrahigh Sensitive Pressure Sensor Insensitive to Strain and Temperature.

An ultrahigh sensitive capacitive pressure sensor based on a porous pyramid dielectric layer (PPDL) is reported. Compared to that of the conventional pyramid dielectric layer, the sensitivity was drastically increased to 44.5 kPa-1 in the pressure range <100 Pa, an unprecedented sensitivity for capacitive pressure sensors. The enhanced sensitivity is attributed to a lower compressive modulus and larger change in an effective dielectric constant under pressure. By placing the pressure sensors on islands of hard elastomer embedded in a soft elastomer substrate, the sensors exhibited insensitivity to strain. The pressure sensors were also nonresponsive to temperature. Finally, a contact resistance-based pressure sensor is also demonstrated by chemically grafting PPDL with a conductive polymer, which also showed drastically enhanced sensitivity.

Near-Infrared Diffuse Reflectance Measurement Method Based on Temperature-Insensitive Radial Distance.

The variation of temperature is one of the main interference factors that affect the detection accuracy of near-infrared (NIR) diffuse reflectance. In this paper, a measurement method based on temperature-insensitive radial distance was proposed, and its feasibility and effectiveness were verified in Intralipid solutions. First, the possibility of temperature-insensitive radial distance was deduced based on the analytic solution of the steady-state diffusion equation in an infinite media, and the temperature-insensitive radial distances of 3% Intralipid solution in the wavelength range of 1000-1600 nm was calculated. Second, a detection system was designed to measure the diffuse reflectance of 3% Intralipid solutions at multiple radial distances with different glucose concentration (0-100 mM) and different temperatures (35-40 ℃). Both theoretical calculations and experimental results demonstrated the existence of temperature-insensitive radial distances in the range of 1000-1340 nm and 1440-1600 nm, and the distances were hardly affected by glucose variations. Finally, the glucose information extracted from the diffuse reflectance of Intralipid solutions at different radial distances under random temperature variations and constant temperature were compared. The result showed that the correlation between the glucose concentration and the diffuse reflectance obtained at the temperature-insensitive radial distance was significantly better than that of other radial distances, which was almost close to the situation of constant temperature. Therefore, the measurement method based on temperature-insensitive radial distance can effectively reduce the influence of temperature variations on NIR diffuse reflectance, and it is expected to improve the accuracy of diffuse reflectance in human body components detection and industrial field analysis.

High Precision Temperature Insensitive Strain Sensor Based on Fiber-Optic Delay.

A fiber-optic delay based strain sensor with high precision and temperature insensitivity was reported, which works on detecting the delay induced by strain instead of spectrum. In order to analyze the working principle of this sensor, the elastic property of fiber-optic delay was theoretically researched and the elastic coefficient was measured as 3.78 ps/km·µÎµ. In this sensor, an extra reference path was introduced to simplify the measurement of delay and resist the cross-effect of environmental temperature. Utilizing an optical fiber stretcher driven by piezoelectric ceramics, the performance of this strain sensor was tested. The experimental results demonstrate that temperature fluctuations contribute little to the strain error and that the calculated strain sensitivity is as high as 4.75 µÎµ in the range of 350 µÎµ. As a result, this strain sensor is proved to be feasible and practical, which is appropriate for strain measurement in a simple and economical way. Furthermore, on basis of this sensor, the quasi-distributed measurement could be also easily realized by wavelength division multiplexing and wavelength addressing for long-distance structure health and security monitoring.

The evolutionary divergence of TRPA1 channel: heat-sensitive, cold-sensitive and temperature-insensitive.

The Transient Receptor Potential Ankyrin 1 ion channel is heat-sensitive in invertebrate and ancestral vertebrates, cold-sensitive in rodents, and temperature-insensitive in primates. This remarkable divergence in temperature sensitivity is in contrast to its role in sensing electrophilic compounds, which is conserved during animal evolution.

Physicochemical investigation of mixed surfactant microemulsions: water solubilization, thermodynamic properties, microstructure, and dynamics.

In this contribution, we report on a systematic investigation of phase behavior and solubilization of water in water-in-heptane or decane aggregates stabilized by mixtures of polyoxyethylene (20) cetyl ether (Brij-58) and cetyltrimethylammonium bromide (CTAB) surfactants with varying compositions in conjugation with 1-pentanol (Pn) at fixed surfactant(s)/Pn ratio and temperature. Synergism in water solubilization was evidenced by the addition of CTAB to Brij-58 stabilized system in close proximity of equimolar composition in both oils. An attempt has been made to correlate composition dependent water solubilization and volume induced conductivity studies to provide insight into the solubilization mechanism of these mixed systems. Conductivity studies reveal the ascending curve in water solubilization capacity-(Brij-58:CTAB, w/w) profile as the interdroplet interaction branch indicating percolation of conductance and the descending curve is a curvature branch due to the rigidity of the interface in these systems. The microstructure of these systems as a function of surfactant composition has been determined by dynamic light scattering (DLS) and Fourier transform infrared spectroscopy (FTIR) measurements. FTIR study reveals increase and decrease in relative population of bound and bulk-like water, respectively, with increase in Brij-58:CTAB (w/w). DLS measurements showed that the droplet hydrodynamic diameter (Dh) decreases significantly with the increase in Brij-58:CTAB (w/w). Further, the interfacial composition and energetic parameters for the transfer of Pn from bulk oil to the interface were evaluated by the dilution method. Formation of temperature-insensitive microemulsions and temperature invariant droplet sizes are evidenced in the vicinity of the equimolar composition. The results are interpreted in terms of a proposed mechanism.

A temperature-insensitive cladding-etched Fiber Bragg grating using a liquid mixture with a negative thermo-optic coefficient.

To compensate for the temperature dependency of a standard FBG, a cladding-etched FBG immersed with a liquid mixture having a negative thermo-optic coefficient is presented, and its characteristics are investigated. The Bragg wavelength of the cladding-etched FBG is shifted counter to the direction of the Bragg wavelength shift of a conventional FBG according to the mixing ratio of glycerin to water; thus, the temperature-dependent Bragg wavelength shift was almost compensated by using a liquid mixture of water (50%) and glycerin (50%) having the negative thermo-optic coefficient of -5 × 10(-4) °C(-1).